Method for treating acidic waste-water contg. nonferrous metals
A technology for acidic wastewater and non-ferrous metals, applied in chemical instruments and methods, multi-stage water/sewage treatment, water/sludge/sewage treatment, etc. To achieve the effect of reducing the amount of pollutants
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Embodiment 1
[0017] Non-ferrous metal acid wastewater flow rate 400M 3 / hour (continuous flow), wastewater composition (mg / l); Cu3.88, Pb14.63, Cd12.65, Zn139.29, pH value 5.0.
[0018] One-stage lime neutralization: add milk of lime with a concentration of 6% in the mixing tank until the pH value reaches 8.5, take a sample and test the neutralized components (mg / l): Cu0.26, Pb1.22, Cd0.45, Zn17 .86.
[0019] Two-stage polymerized ferric sulfate precipitation: put 200PPM (equivalent to 80kg / hour) of polymerized ferric sulfate with a concentration of 10% into the mixing tank, and take a sample to test the composition of the clarified liquid after the polymerized precipitation (mg / l): Cu0.20, Pb0.91 , Cd0.08, Zn1.43, pH 8.5.
example 2
[0021] Wastewater composition (mg / l): Cu1.82, Pb9.40, Cd7.12, Zn138.48, pH value 3.5.
[0022] The concentration of milk of lime is 6%, until the pH value reaches 7.5, the composition of the clarified liquid after neutralization (mg / l) is sampled and tested: Cu0.40, Pb1.04, Cd0.16, Zn2.14, and the pH value is 7.5.
[0023] Concentration of 5% polyferric sulfate 70PPM (equivalent to 28kg / hour), sampling and testing the clarified liquid composition (mg / l) after polymerization and precipitation: Cu0.28, Pb0.97, Cd0.07, Zn1.93, pH value 7.5, Feeding and sampling locations are the same as in Example 1.
example 3
[0025] Wastewater composition (mg / l): Cu5.65, Pb11.79, Cd6.89, Zn629.65, PH value 4.0.
[0026] The concentration of milk of lime is 10%, until the pH value reaches 9.0, the composition of the clarified liquid after neutralization (mg / l) is sampled and tested: Cu0.28, Pb1.31, Cd0.16, Zn9.55, and the pH value is 9.0.
[0027] Concentration of 20% polyferric sulfate 200PPM, sampling and testing the composition of the clarified liquid after polymerization precipitation (mg / l): Cu0.24, Pb1.20, Cd0.07, Zn3.23, pH value 9.0, feeding and sampling locations are the same as examples 1.
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