Electrolyte and electrochemical device and electronic device containing electrolyte
An electrolyte and atom technology, applied in the field of electrochemistry, can solve the problems of accelerating the decomposition of electrolyte, affecting the service life and cycle performance of lithium-ion batteries, etc., to suppress continuous decomposition, improve high-temperature storage performance and cycle performance, and achieve good high-temperature storage. Effects of performance and cycle performance
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Embodiment 1
[0114]
[0115] Ethylene carbonate (EC), propylene carbonate (PC), diethyl carbonate (DEC), ethyl propionate (EP), propyl propionate (PP) were mixed in an argon atmosphere glove box with a water content of less than 10 ppm. ), mixed uniformly according to the mass ratio of 1:1:1:1:1 to form the base solvent. Then add the compound formula (I-1) represented by the formula (I), the compound formula (II-1) represented by the formula (II) and the fully dried lithium salt LiPF to the above-mentioned base solvent. 6 , and stir evenly to dissolve the lithium salt. Based on the total mass of the electrolyte, the mass percentage of formula (I-1) is 0.1%, the mass percentage of (II-1) is 0.001%, and the lithium salt LiPF 6 The mass percentage of 12.5%, and the remainder is the mass percentage of the base solvent.
[0116]
[0117] The cathode material lithium cobalt oxide (LiCoO 2 ), conductive agent conductive carbon black, conductive paste, and binder polyvinylidene fluoride (PV...
Embodiment 2 to Embodiment 17
[0125] The preparation steps of , , , and are the same as those in Example 1, and the relevant preparation parameters and The changes in performance parameters are shown in Table 1.
Embodiment 18 to Embodiment 47
[0127]
[0128] In addition to adding the compound represented by formula (I) and the compound represented by formula (II) to the base solvent, at least one of sulfur-oxygen double bond compounds, polynitrile compounds or boron-based lithium salt compounds is also added. The changes of parameters and performance parameters are shown in Table 2, and the rest are the same as in Example 1.
[0129] The preparation steps of , , and are the same as those in Example 1.
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