Polymer microsphere with high refractive index and preparation method thereof

A high refractive index, polymer technology, applied in the field of biomedicine, can solve the problems of inconvenient preparation, poor refractive index properties of latex microspheres, etc., and achieve the effects of low production cost, excellent hand feel and elongation, and improved mechanical properties.

Inactive Publication Date: 2022-07-29
江苏简芯生物技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Aiming at the deficiencies of the prior art, the present invention provides a high-refractive-index polymer microsphere and its preparation method, which has the advantages of better refraction properties of latex microspheres and easier preparation, and solves the problems in the preparation of current latex microspheres. However, due to the influence of formula and process, the refractive index properties of latex microspheres are poor, and the preparation is also very inconvenient.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Embodiment 1, a high-refractive-index polymer microsphere, including the following raw materials in parts by weight: 100 parts of aliphatic conjugated diene monomers, 10 parts of ethylenically unsaturated carboxylic acid monomers, and 100 parts of acrylonitrile monomers. 20 parts of body, 10 parts of medium chain fatty acid glycerides and 5-15 parts of aluminum compound aqueous solution.

Embodiment 2

[0030] Embodiment 2, a high-refractive-index polymer microsphere, comprising the following raw materials in parts by weight: 150 parts of aliphatic conjugated diene monomers, 50 parts of ethylenically unsaturated carboxylic acid monomers, acrylonitrile monomers 30 parts of body, 20 parts of medium chain fatty acid glycerides and 10 parts of aluminum compound aqueous solution.

Embodiment 3

[0031] Embodiment 3, a high-refractive-index polymer microsphere, comprising the following raw materials in parts by weight: 200 parts of aliphatic conjugated diene monomers, 100 parts of ethylenically unsaturated carboxylic acid monomers, and acrylonitrile monomers. 40 parts of body, 30 parts of medium chain fatty acid glycerides and 15 parts of aluminum compound aqueous solution.

[0032] A preparation method of high refractive index polymer microspheres, comprising the following steps:

[0033] 1) Preparation of solution: water phase solution: send the metered emulsifier and water to the water phase solution preparation tank respectively, and the water phase solution prepared after stirring and fully mixing; oil phase solution: place styrene in an organic solvent Dissolve in the solution, feed nitrogen into the solution to remove oxygen to obtain an oil phase solution;

[0034] 2) Preparation of latex: put an appropriate amount of initiator, aliphatic conjugated diene mono...

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PUM

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Abstract

The invention relates to the technical field of biological medicines, and discloses a high-refractive-index polymer microsphere, which is prepared from the following raw materials in parts by weight: 100 to 200 parts of aliphatic conjugated diene monomers, 10 to 100 parts of ethylene unsaturated carboxylic acid monomers, 20 to 40 parts of acrylonitrile monomers, 10 to 30 parts of medium-chain fatty glyceride and 5 to 15 parts of aluminum compound aqueous solution. According to the high-refractive-index polymer microsphere and the preparation method thereof, the latex prepared by the method is more stable in structure, lower in production cost, higher in safety and stability in the production process, and capable of effectively inhibiting generation of cracks, various characteristics such as waterproofness, chemical resistance and the like obtained by forming the rubber layer are sufficient, and the high-refractive-index polymer microsphere can be used for preparing the high-refractive-index polymer microsphere. According to the present invention, the prepared latex has the advantages of high tensile strength, sufficient tensile strength of the obtained film molding body such as the dipping molding body, excellent hand feeling and excellent elongation, the controllable production cost can be ensured while the adhesion strength of the latex is ensured, and the product has advantages of high reflectivity and good application effect.

Description

technical field [0001] The invention relates to the technical field of biomedicine, in particular to a high refractive index polymer microsphere and a preparation method thereof. Background technique [0002] Synthetic latexes are used in coatings (e.g., latex paints) and glues because they cure through the agglomeration of polymer particles as the water evaporates and thus can form films without releasing potentially toxic organic compounds into the environment solvent. Other uses include cement additives, and hiding information on scratch cards. Latex (usually styrene-based latex) is also used in immunoassays. [0003] Due to the unique properties of latex, latex is now widely used in the field of biomedicine. However, the current latex microspheres are affected by formulation and process during preparation, resulting in poor latex microspheres with poor refractive index properties, and the preparation is also very inconvenient. SUMMARY OF THE INVENTION [0004] (1) ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F236/12C08F220/04C08F220/46C08F2/24
CPCC08F236/12C08F2/24C08F220/04C08F220/46
Inventor 许亮
Owner 江苏简芯生物技术有限公司
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