Negative electrode mixture composite for fluoride ion secondary battery, negative electrode and secondary battery for fluoride ion secondary battery using composite, and method for producing composite
A fluoride ion, secondary battery technology, used in secondary batteries, battery electrodes, non-aqueous electrolyte batteries, etc., can solve the problem of inability to provide negative electrode active material defluorination/refluorination reactions, etc., to improve energy density Effect
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[0124] Next, examples and the like of the present invention will be described, but the present invention is not limited to these examples and the like.
[0125]
[0126] In Examples 1 to 4, aluminum as the negative electrode active material, CeBaF as the fluoride ion-conducting fluoride 2.95 , Acetylene black as a conductive auxiliary agent, and a negative electrode compound composite body for a fluoride ion secondary battery is produced.
[0127] [mixing process]
[0128] Weigh the nanoparticle-shaped aluminum and Ce shown in Table 1 as shown in Table 1 0.95 Ba 0.05 f 2.95 , and acetylene black. After weighing, put aluminum into a ball mill container made of silicon nitride (manufactured by Fritsh, Germany, PL-7 special container, internal volume: 45cc), and then put Ce 0.95 Ba 0.05 f 2.95 , and acetylene black. Furthermore, 40 grams of silicon nitride balls with a diameter of 2 mm were put in, and the container of the ball mill was sealed.
[0129] [Composite Part...
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