Negative electrode composite for fluoride ion secondary battery, negative electrode and secondary battery for fluoride ion secondary battery using said composite, and method for producing said composite
A technology of fluoride ion and secondary battery, which is applied in the direction of secondary battery, battery electrode, non-aqueous electrolyte storage battery, etc. It can solve the problem that the defluorination/refluorination reaction cannot be carried out, and achieve the effect of high charge and discharge efficiency
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[0160] In Example 1, as the negative electrode active material, aluminum and aluminum fluoride (AlF) were used with lithium (Li) metal. 3 ) modified aluminum fluoride obtained by modification. In addition, CeBaF is used as the fluoride ion-conductive fluoride. 2.95 , The conductive assistant uses acetylene black to make a composite of negative electrode composite materials for fluoride ion secondary batteries.
[0161] In Example 1, the first complex obtained by the first mixing step and the first complexing step, and the second complex obtained by the second mixing step and the second complexing step were used in the third mixing step. After mixing and passing through the third composite step, finally, the negative electrode composite material composite for a fluoride ion secondary battery of Example 1 was obtained. In addition, in Example 1, in the second mixing step, the production of modified aluminum fluoride was carried out.
[0162] [1st mixing step]
[0163] Weigh ...
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