Rare earth complex agricultural light conversion film and preparation method thereof

A rare earth complex and light-converting film technology, applied in the field of agricultural film materials, can solve the problems of unstable quality and low luminous efficiency of the light-converting film.

Pending Publication Date: 2022-04-19
苏州睿尔思科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0009] In order to solve the above technical problems, the present invention provides a new type of rare earth complex agricultural light conversion film, and a stable and reliable agricultural film processing and preparation method, which solves the problem of the luminous efficiency of the existing light conversion film prepared based on naphthyridine rare earth complexes. low-quality, unstable technical problems, and finally obtain a light-converting film product with high luminous efficiency and long service life

Method used

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  • Rare earth complex agricultural light conversion film and preparation method thereof
  • Rare earth complex agricultural light conversion film and preparation method thereof
  • Rare earth complex agricultural light conversion film and preparation method thereof

Examples

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Embodiment 1

[0041] A three-layer co-extruded coating type light conversion film, including an inner layer (mechanical structure layer), a middle layer (light conversion layer), and an outer layer (coating carrier layer), each layer has a thickness of 30 microns, a total of 90 microns. The inner and outer layers contain 10 parts of long-life aging masterbatch and 90 parts of base material; the middle light conversion layer contains 15 parts of alkaline light conversion masterbatch, 10 parts of single anti-aging masterbatch and 75 parts of base material.

[0042] The base material is one, two or three mixtures of low-density polyethylene (LDPE), metallocene linear low-density polyethylene (MLLDPE), and ethylene-vinyl acetate copolymer (EVA).

[0043] Longevity aging masterbatch is made by mixing and granulating 5% light stabilizer 944, 1.5% antioxidant 1010, 1% antioxidant 168, 1% erucamide slip agent and 91.5% polyethylene of. Longevity aging masterbatch is granulated by twin-screw proces...

Embodiment 2

[0052] A five-layer co-extruded coating type light conversion film, comprising an inner layer (mechanical structure layer), a second inner layer (mechanical structure layer), a middle layer (light conversion layer), a second outer layer (insulation layer), an outer layer (coating layer) Covering the carrier layer), the thickness of each layer is 18 microns, a total of 90 microns. The inner and outer layers contain 10 parts of longevity aging masterbatch and 90 parts of base material; the sub-inner layer and sub-outer layer contain 10 parts of single anti-aging masterbatch, 5 parts of thermal insulation masterbatch, and 85 parts of base material; the middle layer contains 25 parts of alkaline light conversion masterbatch, 10 parts of single anti-aging masterbatch, 65 parts of base material.

[0053] The base material is one, two or three mixtures of low-density polyethylene (LDPE), metallocene linear low-density polyethylene (MLLDPE), and ethylene-vinyl acetate copolymer (EVA)....

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Abstract

The invention discloses a rare earth complex agricultural light conversion film which is composed of at least one layer of co-extrusion blown film, naphthyridine light conversion agents are added into one or more layers of the co-extrusion blown film, the co-extrusion blown film layer containing the naphthyridine light conversion agents is a light conversion layer, and the addition mass percentage of the naphthyridine light conversion agents in the light conversion layer is 0.2-2%; an alkaline additive is also added into the light conversion layer containing the naphthyridine light conversion agent, and the adding mass percent of the alkaline additive is 0.2-5%. The naphthyridine rare earth complex light conversion film prepared by the invention can obtain high photoluminescence quantum yield and excellent light stability, and solves the technical problems of low luminous efficiency and unstable quality of the existing light conversion film prepared based on naphthyridine rare earth complexes.

Description

technical field [0001] The invention belongs to the field of agricultural film materials, and relates to a rare earth complex agricultural light conversion film with high luminous efficiency and long service life and a preparation method thereof. Background technique [0002] Agricultural plastic film (abbreviated as agricultural film) is one of the three major agricultural production materials in my country. The area of ​​greenhouse film in China accounts for more than 85% of the world's total area. It is widely used and has a very broad market prospect. Agricultural plastic film is mainly composed of additives such as resin, heat stabilizer, light stabilizer, heat preservation agent, and dripping agent. Among them, heat stabilizer and light stabilizer are mainly used to improve the processability, mechanical strength and anti-aging properties of plastics. The thermal insulation agent and dripping agent are functional additives, which can improve the thermal insulation perf...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/32B32B27/30B32B27/08C07F5/00C09K11/06B29D7/01
CPCB32B27/32B32B27/306B32B27/08C07F5/003C09K11/06B29D7/01C09K2211/182B32B2250/246B32B2410/00
Inventor 卫慧波缪倩倩俞贵萍
Owner 苏州睿尔思科技有限公司
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