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Preparation method of auxiliary agent for improving compatibility of water reducing agent and retarder in cement mortar

A technology of cement mortar and water reducing agent, applied in the field of building materials, can solve the problems of early strength influence, reduced fluidity, shortened fluidity retention time, etc., so as to improve compatibility problems, increase fluidity, and maintain fluidity Performance-enhancing effects

Inactive Publication Date: 2021-11-23
SUZHOU XINGBANG CHEM BUILDING MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Cement-based self-leveling and repair mortars often encounter problems caused by the compatibility of retarders and polycarboxylate superplasticizers during the production process, such as reduced fluidity, resulting in poor construction performance and shortened fluidity retention time , resulting in shortened construction time and poor use effect
The general solution is to increase the amount of water reducing agent to increase its initial fluidity and fluidity retention time, but excessive water reducing agent has a great impact on the early strength, and it is easy to cause the slurry to lag and bleed.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] Provided is a preparation method of an auxiliary agent for improving the compatibility of a water reducing agent and a retarder in cement mortar, comprising the steps of:

[0016] (1) Using HPEG-2400 as the macromonomer and acrylic acid as the small monomer, the acid-ether ratio of the modified polyether and the acrylic acid is 4.5, based on the total mass of the modified polyether and acrylic acid, add the mass fraction 1% maleic anhydride and 1% vinyl phosphonic acid as comonomers, 0.4% hydrogen peroxide as initiator, 0.04% thioglycolic acid and 0.12 mass fraction The mercaptopropionic acid of % is transfer agent, and the vitamin C that massfraction is 0.05%% is reductant reaction synthesis and obtains auxiliary agent mother liquor;

[0017] (2) Remove water from the auxiliary agent mother liquor by vacuum distillation to obtain a high-purity water solution, then reduce the viscosity of the high-purity water solution mechanically to obtain a low-viscosity water soluti...

Embodiment 2

[0020] Provided is a preparation method of an auxiliary agent for improving the compatibility of a water reducing agent and a retarder in cement mortar, comprising the steps of:

[0021] (1) Using HPEG-2400 as the macromonomer and acrylic acid as the small monomer, the acid-ether ratio of the modified polyether and the acrylic acid is 5.0, based on the total mass of the modified polyether and acrylic acid, add the mass fraction 2% maleic anhydride and 2% vinyl phosphonic acid as comonomers, 0.6% hydrogen peroxide as initiator, 0.08% thioglycolic acid and 0.14 mass fraction % of mercaptopropionic acid is a transfer agent, and the vitamin C with a mass fraction of 0.5% is a reductant reaction synthesis to obtain an auxiliary agent mother liquor;

[0022] (2) Remove water from the auxiliary agent mother liquor by vacuum distillation to obtain a high-purity water solution, then reduce the viscosity of the high-purity water solution mechanically to obtain a low-viscosity water solu...

Embodiment 3

[0025] Provided is a preparation method of an auxiliary agent for improving the compatibility of a water reducing agent and a retarder in cement mortar, comprising the steps of:

[0026] (1) Using HPEG-2400 as the macromonomer and acrylic acid as the small monomer, the acid-ether ratio of the modified polyether and the acrylic acid is 4.5, based on the total mass of the modified polyether and acrylic acid, add the mass fraction 1.5% maleic anhydride and 1.5% vinyl phosphonic acid as comonomers, 0.5% hydrogen peroxide as initiator, 0.06% thioglycolic acid and 0.13% mass fraction Mercaptopropionic acid is a transfer agent, and vitamin C with a mass fraction of 0.3% is a reductant reaction synthesis to obtain an auxiliary agent mother liquor;

[0027] (2) Remove water from the auxiliary agent mother liquor by vacuum distillation to obtain a high-purity water solution, then reduce the viscosity of the high-purity water solution mechanically to obtain a low-viscosity water solution...

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PUM

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Abstract

The invention discloses a preparation method of an auxiliary agent for improving compatibility of a water reducing agent and a retarder in cement mortar, which comprises the following steps: taking modified polyether as a large monomer, taking acrylic acid as a small monomer, adding maleic anhydride and vinyl phosphonic acid as comonomers, taking hydrogen peroxide as an initiator, taking thioglycollic acid and thiohydracrylic acid as transfer agents, carrying out reaction synthesis by using vitamin C as a reducing agent to obtain auxiliary mother liquor; dehydrating the assistant mother liquor to obtain mother liquor powder; and mixing the mother liquor powder with calcium hydroxide and calcium formate, adding a suspension stabilizing aid, and stirring to obtain the aid for improving the compatibility of the water reducing agent and the retarder in the cement mortar. The additive is obtained by changing a synthesis process and performing physical compounding, the compatibility problem of a water reducing agent and a retarder can be remarkably improved, the dosage of the additive is 20-40% of the dosage of the water reducing agent, the initial fluidity is increased, the fluidity retention performance is enhanced, and the additive has certain early strength components and cannot cause adverse effects on the early strength of mortar.

Description

technical field [0001] The invention relates to the technical field of building materials, in particular to a preparation method of an auxiliary agent for improving the compatibility of a water reducing agent and a setting retarder in cement mortar. Background technique [0002] Cement-based self-leveling and repair mortars often encounter problems caused by the compatibility of retarders and polycarboxylate superplasticizers during the production process, such as reduced fluidity, resulting in poor construction performance and shortened fluidity retention time , resulting in shortened construction time and poor use effect. The general solution is to increase the amount of water reducing agent to increase its initial fluidity and fluidity retention time, but excessive water reducing agent has a great impact on the early strength, and it is easy to cause the slurry to lag and bleed to the bottom. Contents of the invention [0003] The technical problem mainly solved by the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/32
CPCC04B40/0039C04B24/32C04B24/04C04B24/003C04B22/068C04B24/16C04B24/06C04B22/064C04B2103/0068
Inventor 沈焱时磊钱佳佳刘凯
Owner SUZHOU XINGBANG CHEM BUILDING MATERIALS
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