Lignin nanoparticle/polyvinyl alcohol/chitosan ternary composite material as well as preparation method and application thereof
A technology of nano-particles and polyvinyl alcohol, which is applied in paper coating, textile and paper making, fiber raw material processing, etc.
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Embodiment 1
[0056] A kind of preparation method of lignin nanoparticle (LNP) of the present embodiment, described method specifically comprises the steps:
[0057] Dissolve 1.5 g of lignin in 10 mL of ethanol solvent to obtain a lignin ethanol solution; slowly add 10 mL of HCl solution with a concentration of 0.1 mol / L to the lignin ethanol solution at a rate of 1 drop / min , stand at room temperature for 2 hours; use Whatman 541 filter paper (pore size 0.22 μm) to filter; then use MD55 dialysis bag to dialyze in deionized water for 3 days, and dilute the solution in the dialysis bag to 400mL aqueous solution after dialysis; After a few days, when the lignin in the solution is deposited on the bottom, take out the lignin at the bottom, and bake the obtained lignin in an oven at 40-60°C for 24 hours by thermal evaporation, take it out, place it in a petri dish, put it in freezing the freezing layer of the refrigerator for half an hour to 1 hour, and finally putting the petri dish containing...
Embodiment 2-3
[0060] The preparation method of the lignin nanoparticles (LNP) in Example 2-3 is the same as that in Example 1, the only difference being that the dropping rate of the HCl solution in Example 2-3 is 2 drops / min and 10 drops / min.
Embodiment 4
[0062] The preparation method of the lignin nanoparticles (LNP) in Example 4 is the same as that in Example 1, except that the concentration of the HCl solution in Example 4 is 0.25 mol / L.
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