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Production method of gasoline and low-sulfur marine fuel

A production method and technology for low-sulfur ships, which are mainly used in the field of gasoline and low-sulfur marine fuel production, can solve the problems of insufficient utilization of re-refined oil and oil slurry, difficult diesel processing, low gasoline yield, etc., and achieve reduction Difficulty of hydrogenation reaction and processing severity, improvement of logistics distribution and mass transfer, and the effect of improving oil properties

Active Publication Date: 2021-06-29
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantage of this route is that the hydrogen consumption is high during the hydrogenation process and the amount of hydrogenation is large. Usually, when the sulfur content meets the indicators, other indicators such as carbon residues are greatly reduced, viscosity is greatly reduced, and the processing cost is high.
Liquefied petroleum gas and catalytic cracking gasoline are ideal components, but catalytic cracking diesel is rich in aromatics and difficult to process
[0007] The existing residual oil hydrotreating and catalytic cracking combined process has problems such as low gasoline yield, difficult diesel processing, insufficient utilization of re-refined oil and oil slurry, and poor economic benefits.

Method used

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  • Production method of gasoline and low-sulfur marine fuel

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] This embodiment adopts the production method of gasoline and low-sulfur marine fuel provided by the present invention, and uses inferior residual oil raw material A. It can be seen that the sulfur content of residual oil is as high as 4.15wt%, residual carbon is 13.48wt%, and metal (Ni+V) is 92µg / g, with a total nitrogen content of 0.30%, belongs to the high-sulfur low-quality residual oil.

[0041] The device adopts four fixed-bed reactors connected in series, one of which is filled with three kinds of residue hydrogenation protection agents, and the filling volume is 18mL of FZC-12B catalyst, 20mL of FZC-103D catalyst, and 22mL of FZC-103E catalyst; One kind of residue hydrodemetallization catalyst, the loading volume is 85mL for FZC-28A catalyst, and 140mL for FZC-204 catalyst; one kind of residual oil hydrodesulfurization catalyst FZC-34A is loaded in three reverses, and the filling volume is 165mL; A residual oil hydrodenitrogenation and carbon removal catalyst FZ...

Embodiment 2

[0044] Embodiment 2 adopts the production method of gasoline and low-sulfur marine fuel provided by the present invention, and uses inferior residual oil raw material B, and the properties of the residual oil raw material are shown in Table 1. It can be seen that the residual oil has a sulfur content of 1.65wt%, a nitrogen content of 5200µg / g, a Kangxi residual carbon of 10.56wt%, and a metal (Ni+V) of 50µg / g, which belong to low-sulfur and high-nitrogen low-quality residual oil.

[0045] The hydrogenation unit adopts four fixed-bed reactors in series, one of which is filled with three kinds of residue hydrogenation protection agents, and the filling volume is 12mL of FZC-12B catalyst, 18mL of FZC-103D catalyst, and 30mL of FZC-103E catalyst; Two kinds of residual oil hydrogenation and demetallization are loaded, and the loading volumes are 74mL for FZC-28A catalyst and 132mL for FZC-204 catalyst; one kind of residual oil hydrodesulfurization catalyst FZC-34A is loaded for the ...

Embodiment 3

[0048] The same as in Example 1, the difference is that the catalyst loading method in the hydrogenation unit is as follows: one of them reversely loads two kinds of residue hydrogenation protection agents, and the loading volumes are respectively 8mL of FZC-12B catalyst and 17mL of FZC-103E catalyst; A residual oil hydrodemetallization catalyst, with a loading volume of 150mL for FZC-28A catalyst and 125mL for FZC-204 catalyst; and a residual oil hydrodesulfurization catalyst FZC-34A, with a loading volume of 200mL.

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Abstract

The invention discloses a production method of gasoline and low-sulfur marine fuel. The production method comprises the following steps: (1) carrying out hydrogenation reaction on a residual oil raw material in the presence of hydrogen and a hydrotreating catalyst; (2) carrying out gas-liquid separation on an effluent of the hydrogenation reaction, circulating a gas phase to the hydrogenation reaction in the step (1), taking a liquid phase as mixed hydrogenation generated oil, not fractionating the mixed hydrogenation generated oil, throwing a part of the mixed hydrogenation generated oil as low-sulfur marine fuel, feeding the rest of the mixed hydrogenation generated oil into a catalytic cracking device, and carrying out catalytic cracking reaction; and (3) mixing a catalytic cracking heavy fraction obtained after dry gas, liquefied gas and catalytic cracking gasoline are separated from the effluent of the catalytic cracking reaction, used as heavy cycle oil, with the residual oil raw material in the step (1) for hydrogenation reaction. The combined process provided by the invention can be used for producing high-octane catalytic cracking gasoline and low-sulfur marine fuel products to the maximum extent. Meanwhile, hydrogenation load is reduced, a catalytic cracking fractionation system is simplified, and equipment investment and operation energy consumption are reduced.

Description

technical field [0001] The invention relates to a method for lightening residual oil, in particular to a process for mainly producing gasoline and low-sulfur marine fuel by using low-quality high-sulfur residual oil as raw materials. Background technique [0002] With the increasingly stringent global environmental protection regulations, clean low-sulfur marine fuel oil will become one of the key oil products in the next few years after the upgrading of clean gasoline and diesel and other light oil products. The International Maritime Organization (IMO) "International Convention for the Prevention of Pollution from Ships" stipulates that from January 2020, the sulfur mass fraction of marine fuel oil used for navigation in general areas of the sea will be reduced from the current not more than 3.5% to not more than 0.5%; when sailing in emission control areas, the sulfur content of marine fuel should not exceed 0.1%. In the marine fuel oil demand market, high-sulfur residua...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G69/00
CPCC10G69/00C10G2300/202
Inventor 蒋立敬刘铁斌袁胜华金建辉韩坤鹏
Owner CHINA PETROLEUM & CHEM CORP
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