Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Copper-aluminum film etching solution

An etchant, copper and aluminum technology, applied in the field of etchant, can solve the problems of boiling and explosive etching efficiency, reduction, etc.

Active Publication Date: 2021-06-01
TCL CHINA STAR OPTOELECTRONICS TECH CO LTD
View PDF9 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003]Most of the existing copper and aluminum film etching solutions use hydrogen peroxide system to oxidize copper and aluminum through hydrogen peroxide, and then generate copper ions and aluminum ions under the action of acid. Ultimately achieve the purpose of etching, but copper ions have a catalytic effect on the decomposition of hydrogen peroxide. When the concentration of copper ions dissolved in the etching solution exceeds 0.005 grams per milliliter (5000ppm, ppm is parts per million) during the etching process, the over Hydrogen oxide will be violently decomposed, resulting in boiling and explosion and reduced etching efficiency, prematurely reaching the service life of the etching solution, and requiring frequent replacement of new etching solution

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Copper-aluminum film etching solution
  • Copper-aluminum film etching solution
  • Copper-aluminum film etching solution

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] This embodiment provides a copper aluminum film etching solution, relative to the total weight of the etching solution, by weight, comprising: 6.3% hydrogen peroxide, 0.5% phenylurea (hydrogen peroxide stabilizer), 0.15% 5-amino-1H-tetrazolium monohydrate (etch inhibitor), 8% citric acid (organic acid), 7% 2-amino-2-methyl-1-propanol (alcoholamine ), 0.5% polyethylene glycol (surfactant), 1.8% ammonium dihydrogen phosphate (inorganic hydrogen phosphate), 1.2% phosphoric acid (inorganic acid) and deionized water of the remainder.

[0045] The preparation method of the copper-aluminum film etching solution described in this embodiment is: dissolving each component of the etching solution in deionized water, stirring and dissolving for 1.5 to 3 minutes at 15 to 30 degrees Celsius and 150 to 800 rpm hours until a clear and homogeneous mixed solution appears.

Embodiment 2

[0047] This embodiment provides a copper aluminum film etching solution, relative to the total weight of the etching solution, by weight, comprising: 6.3% hydrogen peroxide, 0.5% phenylurea (hydrogen peroxide stabilizer), 0.15% 5-amino-1H-tetrazolium monohydrate (etch inhibitor), 8% citric acid (organic acid), 7% 2-amino-2-methyl-1-propanol (alcoholamine ), 0.5% polyethylene glycol (surfactant), 1.8% ammonium dihydrogen phosphate (inorganic hydrogen phosphate), 1.2% phosphoric acid (inorganic acid), 0.05% ammonium fluoride (fluoride) and other amount of deionized water.

[0048] The preparation method of the copper-aluminum film etching solution described in this embodiment is: dissolving each component of the etching solution in deionized water, stirring and dissolving for 1.5 to 3 minutes at 15 to 30 degrees Celsius and 150 to 800 rpm hours until a clear and homogeneous mixed solution appears.

[0049] The effect of the etching solution described in the embodiment of the p...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The embodiment of the invention discloses a copper-aluminum film etching solution. The copper-aluminum film etching solution comprises the following components in percentage by weight relative to the total weight of the etching solution: 4%-10% of hydrogen peroxide, 0.1%-1% of a hydrogen peroxide stabilizer, 0.05%-0.5% of an etching inhibitor, 10%-30% of a chelating agent, 0.2%-2% of a surfactant, 0.2%-5% of inorganic phosphate or inorganic hydrophosphate, 0.1%-5% of inorganic acid, 0-0.05% of fluoride and the balance of deionized water. The etching solution provided by the invention has relatively long service life.

Description

technical field [0001] The present application relates to the technical field of etching solution, in particular to a copper-aluminum film etching solution. Background technique [0002] At present, amorphous silicon thin film transistor products are commonly used in the high-generation thin film transistor liquid crystal display (TFT-LCD) production process, and copper, aluminum and their alloys are developed and applied due to their low cost. The copper / aluminum film layer has become the main gate (Gate) and source / drain (Source / Drain) metal layer structure of TFT-LCD, and the development of related etching solutions is also particularly important. [0003] Most of the existing copper and aluminum film etching solutions use hydrogen peroxide system to oxidize copper and aluminum through hydrogen peroxide, and then generate copper ions and aluminum ions under the action of acid to finally achieve the purpose of etching, but the decomposition of copper ions to hydrogen perox...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C23F1/18C23F1/20
CPCC23F1/18C23F1/20Y02P70/50
Inventor 吴豪旭
Owner TCL CHINA STAR OPTOELECTRONICS TECH CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products