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Biaxially oriented polypropylene heat-sealing film and preparation process thereof

A technology of biaxial stretching and preparation process, which is applied in the field of biaxially stretched polypropylene heat-sealing film and its preparation process, which can solve the problems of affecting the use effect and aesthetics, poor water vapor barrier permeability, and poor wear resistance of cigarette film. , to achieve the effect of improving transparency and gloss, improving aesthetics and improving surface strength

Pending Publication Date: 2021-03-16
JIANGYIN ZHONGDA FLEXIBLE PLASTIC NEW MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The tobacco manufacturing industry is a major tax source in China. For the outer surface film of its tobacco packaging, various materials including cellophane, PVC coating film, PVDC coating film, BOPP cigarette film, etc. have been used. BOPP cigarette film is also called two-way stretch film. Stretched polypropylene cigarette film, which is co-extruded and stretched by various polypropylene functional materials, has good optical properties, wide heat-sealing range, high heat-sealing strength, strong water vapor barrier ability, Uniform thickness, wide shrinkage control range, good stiffness and other incomparable characteristics are ideal materials for cigarette packaging, but some existing cigarette films have poor wear resistance and are prone to scratches, which affect the use effect and aesthetics, and the water vapor barrier permeability is poor, which is easy to cause tobacco deterioration. In an environment with high humidity, the humid air is easy to condense on the surface of the cigarette film, showing the appearance defect of "water mist". Therefore, we propose a A kind of biaxially stretched polypropylene heat-sealing film and its preparation process

Method used

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  • Biaxially oriented polypropylene heat-sealing film and preparation process thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] 1) Raw material preparation:

[0048] Take sodium hydroxide solution, add polysorbate-80 and vegetable oil, shear emulsification and ultrasonic treatment for 10 minutes, and obtain an emulsified solution; take 2.9 parts by weight of zinc nitrate and 7.5 parts by weight of aluminum nitrate dissolved in ethanol aqueous solution, add the emulsified solution and mix evenly, After standing still for 12 hours, washing and drying with water, zinc aluminate colloid was obtained; 18 parts by weight of ethyl orthosilicate and absolute ethanol were stirred and mixed, and hydrochloric acid aqueous solution was added to continue stirring for 1 hour, and silica gel was obtained after standing for 18 hours. ; Take 12.5 parts by weight of zinc carbonate, 7.8 parts by weight of aluminum hydroxide, 25 parts by weight of feldspar feldspar, and 0.8 parts by weight of titanium dioxide, mix and grind, sieve, mix with colloidal silica, place at a temperature of 1000 ° C for sintering, and sint...

Embodiment 2

[0057] 1) Raw material preparation:

[0058] Take sodium hydroxide solution, add polysorbate-80 and vegetable oil, shear emulsification and ultrasonic treatment for 12 minutes, and obtain an emulsified solution; take 4.5 parts by weight of zinc nitrate and 11 parts by weight of aluminum nitrate dissolved in ethanol aqueous solution, add the emulsified solution and mix evenly, After standing still for 15 hours, washing and drying with water, zinc aluminate colloid was obtained; 24 parts by weight of ethyl orthosilicate and absolute ethanol were stirred and mixed, and aqueous hydrochloric acid was added to continue stirring for 2 hours, and then stood for 21 hours to obtain silica colloid ; Take 25 parts by weight of zinc carbonate, 11 parts by weight of aluminum hydroxide, 26 parts by weight of feldspar feldspar, and 1.6 parts by weight of titanium dioxide, mix and grind, sieve, mix with colloidal silica, place at 1100 ° C for sintering, and sinter The time is 1.5h, take it out...

Embodiment 3

[0067] 1) Raw material preparation:

[0068] Add polysorbate-80 and vegetable oil to sodium hydroxide solution, shear emulsify and ultrasonically treat for 15 minutes to obtain an emulsified solution; take 6.0 parts by weight of zinc nitrate and 15.0 parts by weight of aluminum nitrate dissolved in aqueous ethanol, add the emulsified solution and mix evenly, Stand still for 18 hours, wash and dry to obtain zinc aluminate colloid; take 30 parts by weight of ethyl orthosilicate and absolute ethanol to stir and mix, add hydrochloric acid aqueous solution to continue stirring for 3 hours, and stand still for 24 hours to obtain silica colloid ; Take 37.6 parts by weight of zinc carbonate, 15 parts by weight of aluminum hydroxide, 27 parts by weight of feldspar feldspar, and 2.4 parts by weight of titanium dioxide, mix and grind them, mix them with colloidal silica after sieving, place them at a temperature of 1200°C for sintering, and sinter The time is 2 hours, take out the quick ...

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Abstract

The invention discloses a biaxially oriented polypropylene heat-sealing film and a preparation process thereof. The biaxially oriented polypropylene heat-sealing film comprises an outer surface layer,a core layer and an inner surface layer, and is prepared by co-extruding the outer surface layer, the core layer and the inner surface layer from top to bottom. The core layer is prepared from the following components in parts by weight: 87 to 92 parts of homo-polypropylene, 5 to 10 parts of hydrogenated petroleum resin, 0.8 to 1.2 parts of nano glass powder, 0.4 to 0.8 part of calcium carbonate,0.25 to 2.5 parts of nucleating agent, 0.2 to 0.5 part of stabilizer and 0.01 to 0.2 part of antioxidant. By arranging the biaxially oriented film layer structure, the components and the preparationprocess of the biaxially oriented film layer structure, the performance of a prepared tobacco film is improved, the strength, the mechanical performance, the glossiness and the humidity of the prepared tobacco film are improved, the wear resistance and the moisture barrier capacity of the prepared tobacco film are improved, moisture condensation and permeation can be effectively prevented, the existing tobacco quality and tobacco film appearance are kept, and the film is suitable for wide popularization and use.

Description

technical field [0001] The invention relates to the technical field of cigarette films, in particular to a biaxially stretched polypropylene heat-sealing film and a preparation process thereof. Background technique [0002] The tobacco manufacturing industry is a major tax source in China. For the outer surface film of its tobacco packaging, various materials including cellophane, PVC coating film, PVDC coating film, BOPP cigarette film, etc. have been used. BOPP cigarette film is also called two-way stretch film. Stretched polypropylene cigarette film, which is co-extruded and stretched by various polypropylene functional materials, has good optical properties, wide heat-sealing range, high heat-sealing strength, strong water vapor barrier ability, Uniform thickness, wide shrinkage control range, good stiffness and other incomparable characteristics are ideal materials for cigarette packaging, but some existing cigarette films have poor wear resistance and are prone to scra...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L57/02C08L23/14C08L23/08C08L83/12C08K9/12C08K3/40C08K13/06C08K3/26C08K3/36C08K5/134C08K5/11C08K5/103C08K9/04C08K9/00C08K3/24C08J5/18B32B27/06B32B27/32B32B27/18B29C48/00B29C48/08B29C48/18B29C48/88B29C48/92B29C55/14B29D7/01
CPCC08J5/18B32B27/08B32B27/32B32B27/18B29D7/01B29C48/0018B29C48/022B29C48/08B29C48/18B29C55/143B29C48/9135B29C48/92C08J2323/12C08J2457/02C08J2323/14C08J2423/08C08J2483/12C08K2201/011C08K9/12C08K13/06C08K3/40C08K3/26C08K2003/265C08K3/36C08K5/1345C08K5/11C08K5/103C08K9/04C08K9/00C08K3/24B32B2307/31B32B2307/406B32B2307/554B32B2307/7246B29C2948/9258
Inventor 王润霄薛银春王勇军季建军黄刚庄阿强高学平贾斌汤鑫伟杨刘邦赵毓阚建芬
Owner JIANGYIN ZHONGDA FLEXIBLE PLASTIC NEW MATERIALS CO LTD
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