Wear-resistant antibacterial degradable polymer composite material and preparation method thereof
A composite material and polymer technology, which is applied in the field of wear-resistant and antibacterial degradable polymer composite materials and its preparation, can solve the problems of difficult degradation of waste, failure to achieve balance, insufficient environmental protection, etc., to achieve improved degradability, Increased elasticity, strength and hardness enhancement effects
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preparation example Construction
[0020] A method for preparing a wear-resistant and antibacterial degradable polymer composite material, characterized in that it comprises the following steps:
[0021] (1) ABS material, carbon fiber, ethylene pure fiber, polylactic acid, chitosan, plant fiber, tributyltin chloride, trichlorodiphenyl urea, polyaniline, ultra-high molecular weight wear-resistant agent, Coupling agent, curing agent, compatibilizer;
[0022] (2) Put the raw materials weighed in step (1) into a stirring tank and heat to 170-180° C., stir and mix evenly to obtain a blend, the stirring speed is 350-600r / min, and the stirring time is 20-30min. fully stir;
[0023] (3) Cool down the blend in step (2) to 55-65°C, continue to stir for 10-15 minutes, and then add it to a twin-screw extruder to melt and extrude to pelletize. The extrusion temperature is 350-410°C, and the extrusion rate The temperature is 160-170r / min, the granulation is naturally cooled, and the preparation is completed.
no. 1 example
[0026] A wear-resistant and antibacterial degradable polymer composite material, characterized in that it is composed of the following raw materials in parts by weight: 60 parts of ABS material, 10 parts of carbon fiber, 5 parts of ethylene pure fiber, 10 parts of polylactic acid, shell 20 parts of polysaccharide, 60 parts of sawdust fiber, kombu fiber and flax fiber, 5 parts of tributyltin chloride, 2 parts of trichlorodiphenyl urea, 2 parts of polyaniline, 2 parts of ultra-high molecular weight anti-wear agent, KH560 coupling agent 8 parts, curing agent 5 parts, styrene maleic anhydride graft 2 parts.
[0027] Preferably, the compatibilizer is a maleic anhydride grafted polyolefin or a styrene maleic anhydride graft.
[0028] Preferably, the plant fiber is one or more combinations of wood chip fiber, kombu fiber, flax fiber and kapok fiber.
[0029] Preferably, the coupling agent is one of aluminate coupling agent, γ-aminopropyltriethoxysilane or KH560.
no. 2 example
[0031] A wear-resistant and antibacterial degradable polymer composite material is characterized in that it is composed of the following raw materials in parts by weight: 35 parts of ABS material, 10 parts of carbon fiber, 3 parts of pure vinyl fiber, 5 parts of polylactic acid, shell 20 parts of polysaccharide, 20 parts of flax fiber, 3 parts of tributyltin chloride, 1 part of trichlorodiphenyl urea, 2 parts of polyaniline, 2 parts of ultra-high molecular weight wear-resistant agent, 2 parts of aluminate coupling agent, curing 3 parts of agent, 2 parts of maleic anhydride grafted polyolefin.
[0032] Preferably, the compatibilizer is a maleic anhydride grafted polyolefin or a styrene maleic anhydride graft.
[0033] Preferably, the plant fiber is one or more combinations of wood chip fiber, kombu fiber, flax fiber and kapok fiber.
[0034] Preferably, the coupling agent is one of aluminate coupling agent, γ-aminopropyltriethoxysilane or KH560.
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