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Natural gas hydrogen production and biomass liquefaction combined treatment system and process

A treatment system and treatment process technology, applied in the field of biomass catalytic liquefaction and natural gas reforming hydrogen production combined treatment system and treatment process, can solve the problems of high economic cost, unfavorable large-scale industrial application, etc.

Active Publication Date: 2021-02-02
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The above problems lead to the high economic cost of the existing biomass liquefaction process, which is not conducive to the realization of large-scale industrial application

Method used

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  • Natural gas hydrogen production and biomass liquefaction combined treatment system and process
  • Natural gas hydrogen production and biomass liquefaction combined treatment system and process
  • Natural gas hydrogen production and biomass liquefaction combined treatment system and process

Examples

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Embodiment 1

[0071] In this example, lignocellulose is used as the raw material (the raw material is in the state of granular powder, with a particle size of 0.1-0.3 mm), and cyclohexane and diesel oil are used as solvents, wherein the mass ratio of the solvent to the biomass raw material is 0.3, and the cyclohexane in the solvent is The mass ratio of alkane to diesel oil is 0.1; in the biomass raw material pretreatment unit 12, it is fully mixed and fed with steam, and the molar flow ratio of the steam molar flow to the synthesis gas entering the biomass liquefaction reactor is 2:1; where The operating temperature of the natural gas reforming hydrogen production unit is 622~1335°C, the operating pressure is 2.7MPag, and the space velocity is 20000h -1 ; 20% of the synthesis gas from the natural gas steam reforming reaction product enters the synthesis gas ratio adjustment membrane separator; the membrane area of ​​the synthesis gas ratio adjustment membrane separator is 260m 2 , the cutti...

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Abstract

The invention discloses a natural gas hydrogen production and biomass liquefaction combined treatment system and process. The treatment system comprises a natural gas reforming hydrogen production unit, a synthesis gas proportion adjusting membrane separator, a synthesis gas compression unit, a biomass raw material pretreatment unit, a biomass liquefaction reactor, a carbon dioxide separation unit, a light hydrocarbon concentration membrane separator and a light hydrocarbon recovery unit. The invention further provides a treatment process adopting the treatment system. According to the combined treatment system, the biomass liquefaction reaction unit and the natural gas reforming hydrogen production unit are organically combined, the natural gas reforming hydrogen production unit can adjust the property of hydrogen required by liquefaction at any time according to different biomass raw materials, a water gas shift reaction unit and a hydrogen purification unit in the natural gas reforming hydrogen production unit are omitted, synthesis gas generated by the natural gas reforming hydrogen production unit is directly used in the biomass catalytic liquefaction process, the hydrogen cost is greatly reduced, and the hydrogen utilization rate is high.

Description

technical field [0001] The invention belongs to the technical field of chemical industry, and in particular relates to a combined treatment system and treatment process of biomass catalytic liquefaction and natural gas reforming hydrogen production. Background technique [0002] Biomass is an important renewable resource. At present, the fuel produced from biomass has accounted for more than 5% of the total energy demand, of which about 41% comes from woody biomass raw materials. After the biomass is liquefied, high-value products such as diesel, aromatics, tar and light hydrocarbons can be obtained, and the utilization value is greatly improved. However, due to the high oxygen content in the biomass raw material, the properties of the liquefied oil are poor, and further hydrogenation treatment is required to obtain qualified products. [0003] Biomass catalytic liquefaction reaction is to introduce hydrogen in situ on the basis of liquefaction reaction, and carry out hydro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G1/00C10G1/06C10G1/08C01B3/34
CPCC01B3/34C01B2203/0205C01B2203/06C10G1/00C10G1/065C10G1/083C10G2300/1011
Inventor 陈博孟兆会刘玲乔凯葛海龙杨涛
Owner CHINA PETROLEUM & CHEM CORP
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