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Continuous preparation and transfer method for meter-scale single-walled carbon nanotube film and special device

A technology of single-wall carbon nanotubes and transfer devices, applied in the direction of single-wall carbon nanotubes, nanotechnology, nanotechnology, etc., can solve the problems of discontinuous preparation process and small size of single-wall carbon nanotube films, and achieve continuous transfer , The effect of large film forming area and small film forming area

Pending Publication Date: 2020-11-10
INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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  • Abstract
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Problems solved by technology

[0006] The second object of the present invention is to provide a roll-to-roll continuous preparation and transfer method and a special device for large-area (wide meter-level, length unlimited) single-walled carbon nanotube films under normal temperature and normal pressure, which overcomes existing The single-walled carbon nanotube film prepared by the method is small in size and the problem of discontinuous preparation process

Method used

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  • Continuous preparation and transfer method for meter-scale single-walled carbon nanotube film and special device
  • Continuous preparation and transfer method for meter-scale single-walled carbon nanotube film and special device
  • Continuous preparation and transfer method for meter-scale single-walled carbon nanotube film and special device

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Embodiment

[0045] In this example, the continuous preparation and transfer process of single-walled carbon nanotube film is shown in figure 1 . Single-walled carbon nanotubes were prepared by floating catalyst chemical vapor deposition. The chemical vapor deposition reaction temperature was 1100 °C. Ferrocene, thiophene and toluene were prepared as a catalyst solution at a mass ratio of 6.7:1:222. The rate was 4 μL / min. The catalyst solution was injected into the tube furnace, and 8000 sccm hydrogen and 11 sccm ethylene were fed into the tube furnace at the same time, and the hydrogen and ethylene carried the catalyst into the constant temperature reaction zone of the tube furnace to synthesize single-walled carbon nanotubes. The synthesized single-wall carbon nanotubes flow into the gas-phase suction filter device from the end of the tube furnace with the carrier gas, and adjust the airflow rate at the gas-phase suction port so that all the about 8011sccm airflow flowing into the gas-ph...

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Abstract

The invention relates to a continuous preparation and transfer technology of a single-walled carbon nanotube film, in particular to a reel-to-reel continuous preparation and transfer method of a meter-scale single-walled carbon nanotube film and a special device. The method comprises the following steps: synthesizing a single-walled carbon nanotube by adopting a floating catalyst chemical vapor deposition method, and uniformly and continuously depositing a single-walled carbon nanotube film on the surface of a microporous filter membrane capable of continuously running by adopting a vapor suction filtration method; employing a roll-to-roll imprinting mode, wherein the carbon nanotube film can be transferred to the flexible plastic substrate from the surface of the microporous filter membrane, so the large-area uniform single-walled carbon nanotube film with the width reaching the meter level and the unlimited length is obtained. According to the roll-to-roll continuous preparation andtransfer technology of the single-walled carbon nanotube film, large-area and uniform macro preparation of the single-walled carbon nanotube film is achieved under the conditions of normal pressure and room temperature, and the roll-to-roll continuous preparation and transfer technology has important significance in promoting large-scale preparation and application of the single-walled carbon nanotube film in the field of transparent and flexible photoelectric devices in the future.

Description

technical field [0001] The invention relates to a continuous preparation and transfer technology of single-wall carbon nanotube films, in particular to a roll-to-roll continuous preparation and transfer method and a special device for meter-scale single-wall carbon nanotube films. Background technique [0002] Single-walled carbon nanotube films have excellent electrical, optical and mechanical properties. As a flexible and transparent electrical material with excellent performance, they have been widely used in electronic devices such as flexible thin film transistors, flexible circuits, flexible batteries, and flexible transparent displays in recent years. field, showing its broad application prospects in future transparent and flexible electronic devices. [0003] In the preparation process of the single-walled carbon nanotube film, according to whether it is processed by liquid phase dispersion or not, the preparation method of the film is divided into two types: dry pre...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B32/168C01B32/164B82Y30/00B82Y40/00
CPCC01B32/168C01B32/164B82Y30/00B82Y40/00C01B2202/02
Inventor 孙东明汪炳伟刘畅侯鹏翔孙陨栾健成会明
Owner INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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