Uvioresistant and anti-static chemical fiber yarn and preparation method thereof
An anti-ultraviolet and anti-static technology, applied in the field of textile yarns, can solve the problems of poor adhesion of ultraviolet absorbers, poor air permeability, and inability to wash, and achieve excellent sterilization performance, not easy to agglomerate, and reduce the effect of loss.
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Embodiment 1
[0042] (1) Preparation of modified metal-organic framework: mix silver nitrate, isophthalic acid, and imidazole, add deionized water and stir for 25 minutes, add epoxy soybean oil monoacrylate, adjust the Ph value to 2, seal and place at 85°C Drying under conditions for 2 hours, taking it out, cooling with cooling water for 30 minutes, centrifuging, washing the separated solid with absolute ethanol 3 times to obtain a modified metal organic framework;
[0043] (2) Prepare modified microspheres;
[0044] A. Dissolve methyl methacrylate and azobisisoheptanonitrile in n-hexadecane, add essence, β-1,4-polyglucosamine, stir and mix to obtain solution A;
[0045] B. Sodium lauryl sulfate is dissolved in deionized water to obtain solution B;
[0046] C. Add solution A to solution B, stir at a high speed at 35-45°C, emulsify for 15 minutes, pass nitrogen gas, stir for 4 hours in a water bath at 55°C, add calcium chloride solution for 10 minutes, and age by suction filtration. Obtain...
Embodiment 2
[0061] (1) Preparation of modified metal-organic framework: mix silver nitrate, isophthalic acid, and imidazole, add deionized water and stir for 35 minutes, add epoxy soybean oil monoacrylate, adjust the Ph value to 3, seal and place at 90°C Dry under conditions for 2.5 hours, take it out, cool with cooling water for 35 minutes, centrifuge, wash the separated solid with absolute ethanol 3 times to obtain a modified metal organic framework;
[0062] (2) Prepare modified microspheres;
[0063] A. Dissolve methyl methacrylate and azobisisoheptanonitrile in n-hexadecane, add essence, β-1,4-polyglucosamine, stir and mix to obtain solution A;
[0064] B. Sodium lauryl sulfate is dissolved in deionized water to obtain solution B;
[0065] C. Add solution A to solution B, stir at a high speed at 40°C, emulsify for 20 minutes, pass nitrogen gas, stir for 5.5 hours in a water bath at 60°C, add calcium chloride solution for 15 minutes, filter and age to obtain Modified microspheres; ...
Embodiment 3
[0080] (1) Preparation of modified metal-organic framework: mix silver nitrate, isophthalic acid, and imidazole, add deionized water and stir for 45 minutes, add epoxy soybean oil monoacrylate, adjust the Ph value to 4, seal and place at 95°C Dry under the condition for 3 hours, take it out, cool with cooling water for 40 minutes, centrifuge, wash the separated solid with absolute ethanol 3 times to obtain the modified metal organic framework;
[0081] (2) Prepare modified microspheres;
[0082] A. Dissolve methyl methacrylate and azobisisoheptanonitrile in n-hexadecane, add essence, β-1,4-polyglucosamine, stir and mix to obtain solution A;
[0083] B. Sodium lauryl sulfate is dissolved in deionized water to obtain solution B;
[0084] C. Add solution A to solution B, stir at a high speed at 45°C, emulsify for 5 minutes, feed nitrogen, stir in a water bath at 65°C for 7 hours, add calcium chloride solution for 20 minutes, filter and age to obtain the improved sex microsphere...
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