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Optical filter, camera module, and electronic device

A technology for optical filters and cameras, applied in the fields of optical filters, camera modules and electronic equipment, can solve the problems of image degradation, inability to improve color and shadow, and insufficient absorption intensity.

Active Publication Date: 2020-10-20
JSR CORPORATIOON
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In Patent Document 4, broad absorption in the near-infrared wavelength region is achieved by using a compound mainly having a dithiolene structure, but the absorption intensity around 700 nm is not sufficient
In particular, when used under high incident angle conditions (for example, 45-degree incident angles) that have been accompanied by lower profile camera modules in recent years, image degradation due to color shading may occur
[0007] In addition, Patent Document 5 discloses a near-infrared cut filter having a near-infrared-absorbing glass substrate and a layer containing a near-infrared-absorbing pigment. However, even in the structure described in Patent Document 5, color shading cannot be sufficiently improved. Case

Method used

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  • Optical filter, camera module, and electronic device
  • Optical filter, camera module, and electronic device
  • Optical filter, camera module, and electronic device

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0352] Hereinafter, although an Example demonstrates this invention more concretely, this invention is not limited to these Examples at all. In addition, "parts" mean "parts by mass" unless otherwise specified. In addition, the measurement method of each physical property value and the evaluation method of a physical property are as follows.

[0353]

[0354] The molecular weight of the resin is measured by the following method (a) or (b) in consideration of the solubility of each resin in a solvent and the like.

[0355] (a) Gel Permeation Chromatography (GPC) device (150C type, column: H type column produced by Tosoh (Tosoh) Company, developing solvent: o-dichlorobenzene) manufactured by Waters (WATERS) Company, The mass average molecular weight (Mw) and number average molecular weight (Mn) in terms of standard polystyrene were measured.

[0356] (b) Using a GPC device manufactured by Tosoh (HLC-8220, column: TSKgel α-M, developing solvent: tetrahydrofuran (THF)), measur...

Synthetic example

[0380] The compound (A) and the near-infrared absorbing dye (X) used in the following examples were synthesized by a generally known method. As a common synthesis method, for example, Japanese Patent Laid-Open No. 60-228448, Japanese Patent Laid-Open No. 1-146846, Japanese Patent Laid-Open No. 1-228960, Japanese Patent No. 4081149, Japanese Patent Laid-Open No. Publication No. 63-124054, "Phthalocyanine-Chemistry and Function-" (IPC, 1997), Japanese Patent Laid-Open No. 2007-169315, Japanese Patent Laid-Open No. 2009-108267, Japanese Patent Laid-Open No. 2010- The method described in Publication No. 241873 etc.

Synthetic example 1

[0382] The 8-methyl-8-methoxycarbonyltetracyclo[4.4.0.1 represented by the following formula (a) 2,5 .1 7,10 ] 100 parts of dodec-3-ene (hereinafter, also referred to as "DNM"), 18 parts of 1-hexene (molecular weight modifier) ​​and 300 parts of toluene (ring-opening polymerization reaction solvent) were put into the reaction by nitrogen substitution In a vessel, the solution was heated to 80°C. Then, 0.2 parts of a toluene solution (0.6 mol / liter) of triethylaluminum as a polymerization catalyst, 0.9 parts of a toluene solution (concentration 0.025mol / liter) of tungsten hexachloride modified with methanol were added to the solution in the reaction vessel. parts, the solution was heated and stirred at 80° C. for 3 hours, thereby performing ring-opening polymerization to obtain a ring-opening polymer solution. The polymerization conversion rate in the polymerization reaction was 97%.

[0383] [chemical 19]

[0384]

[0385] 1,000 parts of the thus obtained ring-opened po...

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Abstract

The present invention addresses the problem of providing an optical filter capable of achieving both color shading suppression and ghost suppression of a camera image at a high level. This optical filter fulfills requirements (a) and (b): (a) in a wavelength region of 430-580 nm, a minimum value T<b-0> of transmittance of light incident from a vertical direction, a minimum value T<b-30> of transmittance of light incident from a direction inclined at 30 degrees with respect to the vertical direction, and a minimum value T<b-60> of transmittance of light incident from a direction inclined at 60degrees with respect to the vertical direction are all 55% or more and less than 90%; and (b) in a wavelength region of 700-780 nm, a mean value OD<a-0> of optical density to the light incident from the vertical direction, a mean value OD<a-30> of optical density to the light incident from the direction inclined at 30 degrees with respect to the vertical direction, a mean value OD<a-60> of opticaldensity to the light incident from the direction inclined at 60 degrees with respect to the vertical direction are all 1.8 or more.

Description

technical field [0001] The invention relates to an optical filter, a camera module and electronic equipment. More specifically, it relates to an optical filter having specific optical characteristics, a camera module using the optical filter, and an electronic device including the camera module. Background technique [0002] In solid-state imaging devices such as video cameras, digital still cameras, and mobile phones with camera functions, charge coupled devices (CCDs) or complementary metal oxide semiconductors (CCDs) as solid-state imaging elements for color images are used. , CMOS) image sensor. These solid-state imaging devices use silicon photodiodes that are sensitive to near-infrared rays that cannot be sensed by human eyes in their light-receiving portions. In these solid-state imaging devices, it is necessary to correct the visual sensitivity to present natural colors seen by the human eye, and optical filters that selectively transmit or cut light in specific wa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G02B5/22G03B11/00H04N5/225
CPCG03B11/00G02B5/22H04N23/00G02B1/04C09D201/00C09D7/41C09B57/00G03B17/12H04N23/55
Inventor 田中幸恵长屋胜也岸田寛之
Owner JSR CORPORATIOON
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