Optical filter, camera module, and electronic device
A technology for optical filters and cameras, applied in the fields of optical filters, camera modules and electronic equipment, can solve the problems of image degradation, inability to improve color and shadow, and insufficient absorption intensity.
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[0352] Hereinafter, although an Example demonstrates this invention more concretely, this invention is not limited to these Examples at all. In addition, "parts" mean "parts by mass" unless otherwise specified. In addition, the measurement method of each physical property value and the evaluation method of a physical property are as follows.
[0353]
[0354] The molecular weight of the resin is measured by the following method (a) or (b) in consideration of the solubility of each resin in a solvent and the like.
[0355] (a) Gel Permeation Chromatography (GPC) device (150C type, column: H type column produced by Tosoh (Tosoh) Company, developing solvent: o-dichlorobenzene) manufactured by Waters (WATERS) Company, The mass average molecular weight (Mw) and number average molecular weight (Mn) in terms of standard polystyrene were measured.
[0356] (b) Using a GPC device manufactured by Tosoh (HLC-8220, column: TSKgel α-M, developing solvent: tetrahydrofuran (THF)), measur...
Synthetic example
[0380] The compound (A) and the near-infrared absorbing dye (X) used in the following examples were synthesized by a generally known method. As a common synthesis method, for example, Japanese Patent Laid-Open No. 60-228448, Japanese Patent Laid-Open No. 1-146846, Japanese Patent Laid-Open No. 1-228960, Japanese Patent No. 4081149, Japanese Patent Laid-Open No. Publication No. 63-124054, "Phthalocyanine-Chemistry and Function-" (IPC, 1997), Japanese Patent Laid-Open No. 2007-169315, Japanese Patent Laid-Open No. 2009-108267, Japanese Patent Laid-Open No. 2010- The method described in Publication No. 241873 etc.
Synthetic example 1
[0382] The 8-methyl-8-methoxycarbonyltetracyclo[4.4.0.1 represented by the following formula (a) 2,5 .1 7,10 ] 100 parts of dodec-3-ene (hereinafter, also referred to as "DNM"), 18 parts of 1-hexene (molecular weight modifier) and 300 parts of toluene (ring-opening polymerization reaction solvent) were put into the reaction by nitrogen substitution In a vessel, the solution was heated to 80°C. Then, 0.2 parts of a toluene solution (0.6 mol / liter) of triethylaluminum as a polymerization catalyst, 0.9 parts of a toluene solution (concentration 0.025mol / liter) of tungsten hexachloride modified with methanol were added to the solution in the reaction vessel. parts, the solution was heated and stirred at 80° C. for 3 hours, thereby performing ring-opening polymerization to obtain a ring-opening polymer solution. The polymerization conversion rate in the polymerization reaction was 97%.
[0383] [chemical 19]
[0384]
[0385] 1,000 parts of the thus obtained ring-opened po...
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