Photocatalytic long-acting stain-resistant elastic acrylate emulsion and preparation method thereof

A technology of acrylate and alkyl acrylate, which is applied in the field of elastic acrylate emulsion and its preparation, can solve the problems of reduced coating film decoration effect, coating film pollution, easy dusting, etc., to reduce adhesion and suction, and reduce static electricity Adsorption, damage reduction effect

Inactive Publication Date: 2020-06-26
广东巴德富新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to its elasticity, the elastic coating film is soft. Especially in hot summer weather, the surface of the coating film is even sticky and easily stained with dust. In addition, the dust dissolved in rainwater can also enter into the water through the water absorption of the coating film. The capillary pores of the coating film will cause permanent pollution to the coating film and greatly reduce the decorative effect of the coating film

Method used

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  • Photocatalytic long-acting stain-resistant elastic acrylate emulsion and preparation method thereof

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Effect test

Embodiment 1

[0021] A preparation method of a photocatalyzed long-lasting stain-resistant elastic acrylate emulsion, comprising the following steps (the following raw materials are calculated in parts by weight):

[0022] a) Preparation of base liquid: Add 17.3 parts of deionized water, (propenyloxy)methyl nonylphenol polyoxyethylene ether sulfonic acid into a polymerization kettle equipped with a stirrer, condenser, and constant-flow pump feeding device 0.03 part of ammonium salt, the temperature in the kettle is raised to 80°C;

[0023] b) Preparation of pre-emulsion: Add 29.8 parts of deionized water, (propenyloxy) methyl nonylphenol polyoxyethylene ether into the pre-emulsification tank with monomer metering tank and agitator under normal temperature and pressure 0.05 parts of ammonium sulfonate, 0.39 parts of potassium lauryl phosphate, 0.1 parts of nonylphenol polyoxyethylene ether, 8.03 parts of methyl methacrylate, 39.75 parts of n-butyl acrylate, 2.06 parts of acrylonitrile, 0.26 ...

Embodiment 2

[0027] A method for preparing a photocatalytic long-lasting stain-resistant elastic acrylate emulsion, comprising the following steps (the following raw materials are calculated in parts by weight):

[0028] a) Preparation of base liquid: Add 17.3 parts of deionized water, (propenyloxy)methyl nonylphenol polyoxyethylene ether sulfonic acid into a polymerization kettle equipped with a stirrer, condenser, and constant-flow pump feeding device 0.03 part of ammonium salt, the temperature in the kettle is raised to 80°C;

[0029] b) Preparation of pre-emulsion: Add 29.8 parts of deionized water, (propenyloxy) methyl nonylphenol polyoxyethylene ether into the pre-emulsification tank with monomer metering tank and agitator under normal temperature and pressure 0.05 parts of ammonium sulfonate, 0.39 parts of potassium lauryl phosphate, 0.1 parts of nonylphenol polyoxyethylene ether, 8.72 parts of methyl methacrylate, 33.53 parts of n-butyl acrylate, 5.15 parts of 2-ethylhexyl acrylate...

Embodiment 3

[0033] A method for preparing a photocatalytic long-lasting stain-resistant elastic acrylate emulsion, comprising the following steps (the following raw materials are calculated in parts by weight):

[0034] a) Preparation of base liquid: Add 17.3 parts of deionized water, (propenyloxy)methyl nonylphenol polyoxyethylene ether sulfonic acid into a polymerization kettle equipped with a stirrer, condenser, and constant-flow pump feeding device 0.04 parts of ammonium salt, the temperature in the kettle is raised to 80°C;

[0035] b) Preparation of pre-emulsion: Add 29.8 parts of deionized water, (propenyloxy) methyl nonylphenol polyoxyethylene ether into the pre-emulsification tank with monomer metering tank and agitator under normal temperature and pressure 0.05 parts of ammonium sulfonate, 0.39 parts of potassium lauryl phosphate, 0.1 parts of nonylphenol polyoxyethylene ether, 8.27 parts of styrene, 39.43 parts of n-butyl acrylate, 1.54 parts of acrylonitrile, 0.59 parts of met...

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Abstract

The invention discloses a photocatalytic long-acting stain-resistant elastic acrylate emulsion and a preparation method thereof. The photocatalytic long-acting stain-resistant elastic acrylate emulsion comprises the following raw materials: styrene, alkyl methacrylate, alkyl acrylate, a functional monomer, an initiator, an emulsifier, deionized water and ammonia water. The preparation method comprises the following steps: step a, preparing a backing material liquid; step b, preparing pre-emulsified liquid; step c, dropwise adding the pre-emulsified liquid to react; and step d, after finishingof the reaction, preserving heat, adjusting the pH value, and performing discharging. According to the invention, the reactive emulsifier is compounded with the phosphate salt, such that emulsifier migration and surface charges are reduced, and coating film adhesion resistance is improved. The compactness of a coating film can be effectively enhanced by reasonably matching the functional monomer and the photoinitiator, permanent damage caused by dust permeation is reduced, and the decorative service life of the coating film is prolonged.

Description

technical field [0001] The invention relates to a photocatalyzed long-term anti-fouling elastic acrylate emulsion and a preparation method thereof, belonging to the field of elastic coatings. Background technique [0002] With rich colors, simple construction, easy maintenance and renewal, light dead weight, non-toxic and tasteless, and high quality latex paint that can meet the requirements of protection and decoration, latex paint is becoming the leading building decoration material. Elastic latex paint is becoming more and more popular among users because it can cover capillary cracks on the wall and prevent carbonization of concrete. However, the disadvantage of poor stain resistance of elastic latex paint greatly reduces the decorativeness of latex paint. Restricted the further popularization and use of elastic latex. [0003] The elastic coating can extend or retract with the change of stress, and has suitable modulus and tensile strength when stretched, mainly elasti...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/18C08F220/14C08F220/46C08F220/06C08F222/02C08F220/56C08F212/08C08F2/26C08F2/28C08F2/30C09D133/08C09D5/16
CPCC08F2/26C08F2/28C08F2/30C08F220/18C09D5/1662C09D5/1687C09D133/26
Inventor 莫广强刘燕杨文涛
Owner 广东巴德富新材料有限公司
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