Solid-phase OMS-2 molecular sieve catalyst for purifying formaldehyde at room temperature and preparation method thereof
An OMS-2, formaldehyde purification technology, applied in molecular sieve catalysts, physical/chemical process catalysts, separation methods, etc., can solve problems such as high price, and achieve low price, simple and easy preparation method, and excellent carbon dioxide generation selectivity. Effect
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Embodiment 1
[0025] Immerse the solid-phase OMS-2 molecular sieve as a carrier in an aqueous solution containing silver nitrate, ultrasonicate for 30 minutes, stir for 4 hours, and age overnight; stir the mixed solution with a glass rod at 80°C, evaporate the water in the mixed solution to dryness, The active components are uniformly loaded on the solid-phase OMS-2 molecular sieve, and then dried at 100°C for 5 hours; then moved to a muffle furnace under air conditions, and baked at 450°C for 5 hours; OMS- 2 After the molecular sieve is calcined, a catalyst with silver ions as active components is obtained. The mass content of active components in the catalyst is 0.1%, and the catalyst is sieved into particles with a size of 40-60 meshes for use.
Embodiment 14
[0026] Except for Example 14, the solid-phase OMS-2 provided in other examples of the present application are all cryptopotassium manganese oxide octahedral molecular sieves synthesized by a solvent-free method. Specific process example:
[0027] 9.489g (0.06mol) KMnO 4 and 22.059g (0.09mol) Mn(Ac) 2 4H 2 Mix O into a mortar, grind at room temperature for 0.5 hours; then transfer to a crystallization kettle, and crystallize at 80°C for 4 hours; filter, wash, and dry the solid obtained after crystallization, and bake at 400°C for 5 hours , finally get the solid phase OMS-2 molecular sieve as carrier.
Embodiment 2
[0029] The rest are the same as in Example 1, except that the percentage of silver ions is 0.5%, ultrasonic for 5 minutes, stirred for 1 hour, dried at 100° C. for 3 hours, and roasted at 450° C. for 1 hour under air conditions.
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