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Humidity-regulating controlled-release type gas phase corrosion inhibitor

A gas-phase corrosion inhibitor and humidity control technology, which is applied in the field of metal corrosion and protection, can solve the problems of environmental humidity control, VCI loss, long anti-rust period, etc., and achieve the effect of wide application range, convenient use and long anti-rust period

Inactive Publication Date: 2020-05-01
STATE GRID ZHEJIANG PINGHU POWER SUPPLY +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] (4) Low cost and long anti-rust period. The cost of gas-phase anti-rust storage is 20% to 50% of anti-rust grease storage, and 7% to 17% of oil-coated anti-rust storage, but the storage protection period is as long as 5 years above
However, after a large number of practical application results, it seems that this is not entirely the case
When the ambient humidity is too high, the corrosion tendency of the metal increases, and the corrosion inhibition effect of VCI will become worse. However, when the ambient humidity is too low, the corrosion tendency of the metal weakens, but the corrosion inhibition effect of VCI also weakens, especially When the ambient humidity is too low when using VCI for the first time, the metal corrosion inhibition effect will be significantly weakened
This is mainly because VCI forms a protective film on the metal surface on the premise that there is a water film on the metal surface. VCI dissolves in the water film on the metal surface and dissociates a characteristic ion group, which is adsorbed on the metal surface to form a protective film. When the humidity in the environment is too low, it is difficult to form a complete water film on the metal surface, so it is also difficult to form a complete protective film, so the corrosion inhibition effect of VCI on the metal is weakened.
[0012] Because the gas phase corrosion inhibition technology developed at present does not consider the influence of the humidity in the environment on the corrosion inhibition effect, so the environmental humidity is not regulated, so that when the environmental humidity is too high or too low, it cannot achieve sufficient mitigation. corrosion protection
On the other hand, the existing gas-phase corrosion inhibition technology all utilizes the natural volatilization process of VCI, and does not control its volatilization rate. This results in that when the temperature is low, the amount of VCI volatilization is not enough to inhibit corrosion. The effect is affected, and when the temperature is high, the volatilization amount of VCI is too much, exceeding the amount required for metal corrosion inhibition, resulting in unnecessary loss of VCI and reducing the protection period of VCI

Method used

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  • Humidity-regulating controlled-release type gas phase corrosion inhibitor
  • Humidity-regulating controlled-release type gas phase corrosion inhibitor
  • Humidity-regulating controlled-release type gas phase corrosion inhibitor

Examples

Experimental program
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Effect test

Embodiment 1

[0033] A humidity-adjusting and controlled-release gas-phase corrosion inhibitor, which consists of 20%-80% by mass of porous hygroscopic material, 5%-20% by mass of pure gas-phase corrosion inhibitor and 10-60% by mass of deionized water.

[0034] Wherein, the porous hygroscopic material is one of silica gel powder, bentonite, montmorillonite, zeolite, and white carbon black. These porous supports have a rich pore structure with an extremely large surface area for the adsorption of water molecules. There is an equilibrium relationship between the moisture content of the carrier and the humidity of the environment. According to this equilibrium relationship, these carriers can be used to adjust the humidity in the environment. Porous hygroscopic materials not only have well-developed pores and a large specific surface area, but also have many hydroxyl groups on the surface, which can be adsorbed together with the functional groups of the gas phase corrosion inhibitor by hydro...

specific example 1

[0037] Specific example 1: the mass percentage of each component is: porous hygroscopic material 70%, gas phase corrosion inhibitor pure product 10%, deionized water 20%.

specific example 2

[0038] Specific example 2: the mass percentage of each component is: porous hygroscopic material 50%, gas phase corrosion inhibitor pure product 15%, deionized water 35%.

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PUM

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Abstract

The invention discloses a humidity-regulating controlled-release type gas phase corrosion inhibitor. The humidity-regulating controlled-release type gas phase corrosion inhibitor is composed of the following components of, in percentage by mass, 20%-80% of a porous moisture-absorbing material, 5%-20% of a gas phase corrosion inhibitor pure product and 10%-60% of deionized water. The composite vapor phase inhibitor has an air humidity adjusting function, can select a humidity-adjusting controlled-release type vapor phase inhibitor with proper water content according to the environment humidityof different application occasions, and can ensure that the environment humidity can quickly form a protective film at the initial stage of feeding, and the effect of slowly releasing VCI can be achieved through rich pore structures of the hygroscopic porous material and the physicochemical effect of surface hydroxyl groups.

Description

technical field [0001] The invention relates to the technical field of metal corrosion and protection, in particular to a gas phase corrosion inhibitor. Background technique [0002] The phenomenon of metal corrosion is extremely common. The metal loss due to metal corrosion in the world is more than 100 million tons per year. Among them, atmospheric corrosion is the most widespread form of corrosion, and the loss caused by it accounts for more than half of the total metal corrosion loss. Since the total amount of mineable metals in the ground is limited, it is very important to effectively reduce metal corrosion to reduce economic losses and alleviate resource crises. [0003] In order to reduce the corrosion loss of metals, many metal corrosion protection technologies have been developed, such as electroplating, coating, plastic spraying, and corrosion inhibition. received continuous attention. [0004] Vapor phase corrosion inhibition technology is a technology that use...

Claims

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Application Information

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IPC IPC(8): C23F11/02
CPCC23F11/02
Inventor 潘建乔吴迪余方召王征陈超冯跃亮庾峰徐克左滕潘白浪栾伊斌朱晓晨张晓忠
Owner STATE GRID ZHEJIANG PINGHU POWER SUPPLY
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