Preparation method of super-hydrophobic oleophylic material
A hydrophilic and super-hydrophobic technology, which is applied in the field of preparation of super-hydrophobic and lipophilic materials, can solve problems such as uncontrollable infiltration uniformity, complex raw materials and ratios, and uncontrollable graphene growth and lamellae. , to achieve the effect of improving hydrophobicity and lipophilicity and durability
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Embodiment 1
[0032] (1) Select a foamed nickel material with a void density of 110PPI and cut it into a sample of 5cm*5cm*0.3cm, wash it with anhydrous ethanol for 3 times, then with deionized water for 3 times, and ultrasonic vibration cleaning, 10 minutes each time, 50°C Dry down for later use;
[0033] (2) Weigh 0.25g of dopamine in 95ml of water, adjust the solution to pH 8.5 with 0.1M / L hydrochloric acid solution and Tris solution, add 5ml of graphene oxide aqueous solution with a concentration of 0.5mg / mL, and ultrasonically vibrate for 10min , under the condition of 25° C., magnetic stirring for 12 hours, vacuum filtration and drying at 75° C. to obtain polydopamine-graphene oxide.
[0034] (3) Weigh 0.20g of dopamine in 100ml of water, adjust the solution to pH 8.5 with 0.1M / L hydrochloric acid solution and Tris solution, and add the polydopamine-graphene oxide obtained in step (2) into the prepared Dopamine solution, ultrasonic 20min, immerse the prepared nickel foam into the mix...
Embodiment 2
[0040] (1) Select a foam nickel material with a void density of 125PPI and cut it into a sample of 5cm*5cm*0.3cm, wash it 3 times with absolute ethanol, then wash it with deionized water 3 times, and clean it with ultrasonic vibration, each time for 10 minutes, at 50°C drying spare;
[0041] (2) Weigh 0.25g of dopamine in 93ml of water, adjust the solution to pH=8.5 with 0.1M / L hydrochloric acid solution and Tris solution, add 7ml of graphene oxide aqueous solution with a concentration of 0.5mg / mL, and ultrasonically vibrate for 15min , under the condition of 25° C., magnetic stirring for 11 h, vacuum filtration and drying at 65° C. to obtain polydopamine-graphene oxide.
[0042] (3) Weigh 0.20g of dopamine in 100ml of water, adjust the solution to pH=8.5 with 0.1M / L hydrochloric acid solution and Tris solution, and add the polydopamine-graphene oxide obtained in step (2) into the prepared In the dopamine solution, ultrasonically for 20 minutes, the prepared matrix material w...
Embodiment 3
[0048] (1) Select a titanium foam material with a void density of 130PPI and cut it into a sample of 5cm*5cm*0.3cm, wash it twice with anhydrous ethanol, then wash it twice with deionized water, and clean it with ultrasonic vibration, each time for 6 minutes, at 50°C drying spare;
[0049] (2) Weigh 0.18g of dopamine in 90ml of water, adjust the solution to pH=8.5 with 0.1M / L hydrochloric acid solution and Tris solution, add 10ml of graphene oxide aqueous solution with a concentration of 0.1mg / mL, and ultrasonically vibrate for 15min , under the condition of 25° C., magnetic stirring for 14 h, vacuum filtration and drying at 65° C. to obtain polydopamine-graphene oxide.
[0050] (3) Weigh 0.15g of dopamine in 100ml of water, adjust the solution to pH=8.5 with 0.1M / L hydrochloric acid solution and Tris solution, and add the polydopamine-graphene oxide obtained in step (2) into the prepared In the dopamine solution, ultrasonically for 15 minutes, the prepared matrix material wa...
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