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Preparation method of super-hydrophobic oleophylic material

A hydrophilic and super-hydrophobic technology, which is applied in the field of preparation of super-hydrophobic and lipophilic materials, can solve problems such as uncontrollable infiltration uniformity, complex raw materials and ratios, and uncontrollable graphene growth and lamellae. , to achieve the effect of improving hydrophobicity and lipophilicity and durability

Active Publication Date: 2020-02-07
UNIV OF JINAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The invented material has long-lasting hydrophobic and lipophilic properties, and the established oil-water separation system has a large processing capacity and high separation efficiency, but the overall service life and mechanical strength of the material are relatively poor, the raw materials and proportioning are complex, and the infiltration is uniform sex is not controllable
CN201610937856.0 invented a green method for preparing silver-zinc oxide nanosheet-graphene-nickel foam composite material, which solves the problem that metal particles may be exposed to the application environment during the application of graphene-based active metal particle composite materials without falling off problem, realize the comprehensive performance of graphene, zinc oxide and silver particles, and exert the synergistic effect of their respective excellent electrical, catalytic and sensing performances. Although this invention coats graphene on the nickel foam skeleton, the The growth and sheets of graphene are uncontrollable, and the reaction environment is at high temperature, which poses a safety hazard; and this invention is mainly used in the fields of catalysis and sensors

Method used

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  • Preparation method of super-hydrophobic oleophylic material
  • Preparation method of super-hydrophobic oleophylic material
  • Preparation method of super-hydrophobic oleophylic material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] (1) Select a foamed nickel material with a void density of 110PPI and cut it into a sample of 5cm*5cm*0.3cm, wash it with anhydrous ethanol for 3 times, then with deionized water for 3 times, and ultrasonic vibration cleaning, 10 minutes each time, 50°C Dry down for later use;

[0033] (2) Weigh 0.25g of dopamine in 95ml of water, adjust the solution to pH 8.5 with 0.1M / L hydrochloric acid solution and Tris solution, add 5ml of graphene oxide aqueous solution with a concentration of 0.5mg / mL, and ultrasonically vibrate for 10min , under the condition of 25° C., magnetic stirring for 12 hours, vacuum filtration and drying at 75° C. to obtain polydopamine-graphene oxide.

[0034] (3) Weigh 0.20g of dopamine in 100ml of water, adjust the solution to pH 8.5 with 0.1M / L hydrochloric acid solution and Tris solution, and add the polydopamine-graphene oxide obtained in step (2) into the prepared Dopamine solution, ultrasonic 20min, immerse the prepared nickel foam into the mix...

Embodiment 2

[0040] (1) Select a foam nickel material with a void density of 125PPI and cut it into a sample of 5cm*5cm*0.3cm, wash it 3 times with absolute ethanol, then wash it with deionized water 3 times, and clean it with ultrasonic vibration, each time for 10 minutes, at 50°C drying spare;

[0041] (2) Weigh 0.25g of dopamine in 93ml of water, adjust the solution to pH=8.5 with 0.1M / L hydrochloric acid solution and Tris solution, add 7ml of graphene oxide aqueous solution with a concentration of 0.5mg / mL, and ultrasonically vibrate for 15min , under the condition of 25° C., magnetic stirring for 11 h, vacuum filtration and drying at 65° C. to obtain polydopamine-graphene oxide.

[0042] (3) Weigh 0.20g of dopamine in 100ml of water, adjust the solution to pH=8.5 with 0.1M / L hydrochloric acid solution and Tris solution, and add the polydopamine-graphene oxide obtained in step (2) into the prepared In the dopamine solution, ultrasonically for 20 minutes, the prepared matrix material w...

Embodiment 3

[0048] (1) Select a titanium foam material with a void density of 130PPI and cut it into a sample of 5cm*5cm*0.3cm, wash it twice with anhydrous ethanol, then wash it twice with deionized water, and clean it with ultrasonic vibration, each time for 6 minutes, at 50°C drying spare;

[0049] (2) Weigh 0.18g of dopamine in 90ml of water, adjust the solution to pH=8.5 with 0.1M / L hydrochloric acid solution and Tris solution, add 10ml of graphene oxide aqueous solution with a concentration of 0.1mg / mL, and ultrasonically vibrate for 15min , under the condition of 25° C., magnetic stirring for 14 h, vacuum filtration and drying at 65° C. to obtain polydopamine-graphene oxide.

[0050] (3) Weigh 0.15g of dopamine in 100ml of water, adjust the solution to pH=8.5 with 0.1M / L hydrochloric acid solution and Tris solution, and add the polydopamine-graphene oxide obtained in step (2) into the prepared In the dopamine solution, ultrasonically for 15 minutes, the prepared matrix material wa...

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Abstract

The invention discloses a super-hydrophobic oleophylic material which comprises a matrix, a reinforcing body, a coupling agent and a nano coating attached to the surface of the matrix, the matrix material is one of a stainless steel mesh, foamed nickel, foamed copper or foamed titanium, the coupling agent is dopamine, and the nano coating on the surface is one or two of hexadecylamine and octadecylamine; and the reinforcing body is graphene. The invention also discloses a preparation method thereof. According to the design thought, a layer of reduced graphene oxide coats a metal wire mesh framework such as foamed nickel and the like, the graphene serving as the reinforcing body plays a role in improving the strength of the matrix material, graphene oxide with a small particle size is adopted for coating of the graphene, and after reduction, the sheet layer of the graphene is thin, so that the excellent performance of the graphene can be played. In addition, the graphene has hydrophobicity, the surface of the graphene is modified with nanoscale low-surface-energy substances, performance integration of the graphene and the low-surface-energy substances is achieved, and hydrophobicity, lipophilicity and use durability are improved.

Description

technical field [0001] The invention belongs to the field of material preparation, and in particular relates to a preparation method of superhydrophobic and lipophilic materials. Background technique [0002] Superhydrophobic and lipophilic materials have always been a hot topic of theoretical research by researchers. At the same time, their huge potential market prospects are also an important reason why social workers are extremely concerned. With the introduction and emphasis of scientific development theories such as the new century, new energy, and low-carbon environmental protection, the deep improvement and optimization of high-quality, high-efficiency superhydrophobic and lipophilic materials has become an important part of environmental protection. In the process of global industrialization, human beings are very dependent on oil and its derivative products. However, oil spills will inevitably occur during oil extraction and transportation, thereby polluting the env...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D17/022
CPCB01D17/0202
Inventor 冷金凤夏昌鹏王康王建荣
Owner UNIV OF JINAN
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