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Mixture of fused-ring aromatic pigment and polymer material, its preparation method and its downstream products

A technology of polymer materials and aromatic compounds, applied in the field of pigments, can solve the problems of unavoidable waste liquid and achieve good compatibility

Active Publication Date: 2021-03-02
CAICAI TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Similarly, J.APPL.POLYM.SCI.2015, DOI: 10.1002 / APP.42172 also reported the synthesis of polymerizable naphthalimide fluorescent dyes to prepare polyethylene fluorescent polymers, but the polymerizable naphthalimide It also needs to be synthesized by traditional methods, and the waste liquid cannot be avoided.

Method used

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  • Mixture of fused-ring aromatic pigment and polymer material, its preparation method and its downstream products
  • Mixture of fused-ring aromatic pigment and polymer material, its preparation method and its downstream products
  • Mixture of fused-ring aromatic pigment and polymer material, its preparation method and its downstream products

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preparation example Construction

[0044] A method for preparing a mixture of fused-ring aromatic pigments and polymer materials, comprising the following steps:

[0045] The thermoplastic macromolecule material is mixed with reactants for forming condensed ring aromatic pigments, and kneaded or extruded to obtain a mixture of condensed ring aromatic pigments and polymer materials.

[0046] Wherein, the reactants for forming the condensed-ring aromatic pigments include acid anhydride functionalized condensed-ring aromatic compound derivatives, o-diamine compounds and catalysts.

[0047] It should be noted that during the kneading or extrusion process, the anhydride-functionalized condensed-ring aromatic compound derivative and the ortho-diamine compound can react under the action of a catalyst to obtain a condensed-ring aromatic pigment.

[0048] Further, the acid anhydride functionalized condensed ring aromatic compound derivative is selected from at least one of the following compounds:

[0049]

[0050] ...

Embodiment 1-6

[0085]

Embodiment 1~6

[0086] Embodiment 1~6 are all prepared according to the following method:

[0087] Mix 0.5kg of PMMA, (32g, 119mmol) compound (1-1), (25g, 231mmol) compound (1-2) and catalyst, extrude the reaction in a single-screw extruder, cool, dry and pelletize to obtain Crude color masterbatch containing compound (1-3).

[0088] Embodiments 1 to 6 are basically the same, except for the type and consumption of the catalyst, specifically as shown in Table 1:

[0089] Table 1

[0090]

[0091]

[0092] figure 1 The color masterbatch crude product prepared for embodiment 4 is mixed with ABS injection molding at a concentration of 1% to obtain the reflectance spectrum of a 1mm thick plastic sheet, which is obtained by figure 1 It can be seen that its absorption is mainly in the blue to orange light region, which is similar to the mixture of Pigment Orange 43 and Pigment Red 194.

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Abstract

This application relates to a mixture of condensed ring aromatic pigments and polymer materials, its preparation method and its downstream products. In this method, different thermoplastic polymer materials can be mixed with the reactants used to generate fused-ring aromatic pigments, and the reactants and polymer materials can The mixture can be extruded or kneaded to obtain a mixture of fused-ring aromatic pigments and polymer materials in one step. Compared with pigments, the raw material reactants of pigments have better dispersion in polymer materials, so extrusion or Kneading, the pigment can be directly generated and evenly dispersed in the polymer material, and there is no need to add any solvent during the extrusion or kneading process, and the ortho-diamine compound is almost completely consumed, and the obtained mixture does not need to be purified, avoiding the traditional process of pigment synthesis. The generation of three wastes greatly simplifies the technological process and reduces energy consumption.

Description

technical field [0001] The invention relates to the technical field of pigments, in particular to a mixture of condensed ring aromatic pigments and polymer materials, a preparation method and downstream products thereof. Background technique [0002] Fused-ring aromatic vat dyes (Vat Dyes) have bright color and excellent fastness, especially in light fastness and solvent resistance. However, due to the poor dispersion of fused-ring aromatic compounds in the production process, it is necessary to use high-boiling-point, difficult-to-remove solvents, resulting in a large amount of waste liquid, and because the purification of dye molecules is also very difficult, so that the reaction yield of such dyes is low and the price is low. High, and the processing technology is relatively more complicated, which greatly limits the application and development of this type of dye. [0003] US20080139813 uses metal catalysts such as ammonium molybdate, molybdenum oxide, molybdenum carbon...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J3/20C08J3/22C08K5/3447C08K5/3465C08L33/12C08L69/00C08L67/02C08L77/00C09B67/20C09B67/42C09B57/12C09B57/00
CPCC08J3/20C08J3/22C09B67/006C09B67/0071C09B57/12C09B57/00C08K5/3447C08K5/3465C08J2333/12C08J2369/00C08J2367/02C08J2377/00C08J2433/12C08J2469/00C08J2467/02C08J2477/00C08J3/226C09B67/0063C08J2353/02C09B67/0002C09B67/0097C08K5/0041C08L33/12
Inventor 李辰魏文山段若蒙赵雁飞刘志宏田禾
Owner CAICAI TECH CO LTD
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