Coating composition with long-term antimicrobial properties
An evaporator and cleaning agent technology, used in antifouling/underwater coatings, coatings, and biocide-containing paints, etc., can solve the problem of lack of long-term antibacterial effect, achieve good stability and reduce odor problems. Effect
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[0043] There is no particular limitation on the type and source of the quaternary ammonium salt, which can be purchased commercially or prepared according to known synthesis methods, as long as it can provide good bactericidal effect and surface active effect. The commercially available products of the quaternary ammonium salt bactericide that can be adopted include: C8-C16 quaternary ammonium salt Bardac 208M produced by Lonza (China) Investment Co., Ltd.; and quaternary ammonium salt Tomamine Q-C-15 produced by Air Chemical Company; Bardac 208M is a mixture of didecyl / dioctyldimethylammonium chloride (number average molecular weight 522, CAS 68424-95-3) and benzalkonium chloride (number average molecular weight 354, CAS 68424-85-1), The average molecular weight is 460.
[0044] The inventors found that silica nanoparticles can provide good superhydrophilic effect in application. However, the surface tension of the aqueous solution of silica nanoparticles is very high, and i...
Embodiment 1
[0087] Nalco 8699 (15.5% by weight solid content and 2 nm average particle size) and Nalco 1050 (50% by weight solid content and 20 nm average particle size) in a weight ratio of 7:3 were mixed to obtain silica nano Aqueous dispersion of particles. The silica nanoparticle aqueous dispersion, quaternary ammonium salt Tomamine Q-C-15, fatty alcohol polyoxyethylene ether modified silicone surfactant 3259, ethanol and deionized water were mixed and fully stirred to obtain a coating composition , wherein based on the total weight of the coating composition, the silica nanoparticles in the aqueous dispersion of silica nanoparticles account for 0.1% by weight, and the quaternary ammonium salt Tomamine Q-C-15 accounts for 5.0% by weight, so The fatty alcohol polyoxyethylene ether modified silicone surfactant 3259 accounts for 2.0% by weight, the ethanol accounts for 20% by weight, and water accounts for 72.9% by weight (the water content includes the content of the deionized water and...
Embodiment 2-11 and comparative example 1-3
[0089] A coating composition was prepared in the same manner as in Example 1 except that the presence or absence and the content of each component were changed according to the data shown in Table 1 below.
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