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A kind of nylon masterbatch suitable for low-temperature nylon cable ties and its preparation method and application

A technology of nylon cable ties and nylon, which is applied in the field of polymer materials and processing, can solve the problems of reducing the release force of cable ties, reducing the viscosity of nylon, and easy yellowing of cable ties, so as to reduce injection molding time and excellent low temperature resistance , Improve the effect of dimensional stability

Active Publication Date: 2022-04-19
张家港绿洲新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantages of this technology are: the amount of elastomer used is large and the cost is high; moreover, the elastomer is prone to yellowing at the production temperature of the cable tie, and the product color is mainly black; the use of a large amount of elastomer reduces the release force of the cable tie
This patent achieves better fluidity and low temperature resistance of the overall material through the combination of a toughening agent and a surface brightener. However, the mechanical properties of this nylon cable tie are reduced, and the yellowness index increases (easy to yellow). Manufacturing Increased costs
The applicant found that the reason for the decline in the physical and mechanical properties of the nylon cable tie and the yellowing of the cable tie is that the nylon raw material contained in the cable tie needs to be melted and extruded for one thermal processing, and then injection molding is required when it is made into a product. The impact of the secondary thermal processing is that the nylon base material will undergo partial thermal degradation or hydrolytic degradation in the system after two thermal processings, which will not only reduce the viscosity of nylon, but also lead to the deterioration of the physical and mechanical properties of nylon products. The yellow index of the product increases, and the manufacturing cost increases

Method used

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  • A kind of nylon masterbatch suitable for low-temperature nylon cable ties and its preparation method and application
  • A kind of nylon masterbatch suitable for low-temperature nylon cable ties and its preparation method and application
  • A kind of nylon masterbatch suitable for low-temperature nylon cable ties and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-4

[0039] The raw material formula of the nylon masterbatch suitable for low-temperature nylon cable ties provided in these examples is shown in Table 1 below.

[0040] Table 1

[0041]

[0042]

[0043] The preparation method of the above-mentioned nylon masterbatch suitable for low-temperature nylon cable ties is: weighing each raw material according to the formula, mixing, extruding and granulating through a twin-screw extruder, drying at 80°C for 5 hours, and then it can be prepared; wherein, the The temperature settings of each zone of the twin-screw extruder from the main feed are: 120°C, 160°C, 180°C, 220°C, 250°C, 260°C, 230°C, 240°C, 240°C, 240°C, die temperature is 235°C.

Embodiment 5-8

[0045] These embodiments provide low-temperature nylon cable ties, the raw material formula of which is shown in Table 2 below.

[0046] Table 2

[0047]

[0048] The preparation method of the above-mentioned nylon cable tie is as follows: Weigh the raw materials according to the formula, mix them, and inject them to make them; the heating temperatures in zones 1 to 4 are 265°C, 305°C, 325°C, and 315°C in sequence, and the injection pressure is 80MPa.

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Abstract

The invention discloses a nylon masterbatch suitable for low-temperature nylon cable ties and its preparation method and application. In terms of weight percentage, its raw materials include: nylon 6 58-85%; toughening agent 10-30%; Oxidizing agent 0.1-2.5%; Lubricant 2-7.5%; Nucleating agent 0.1-2%; Relative sulfuric acid viscosity of nylon 6 is 2.3-3.2; Preparation method: Weigh each raw material according to the formula, mix, extrude and granulate, and dry , made; and low-temperature nylon cable ties made of the above-mentioned nylon masterbatch; the nylon masterbatch of the present invention has a fast molding speed, and a small amount of nylon masterbatch and nylon base material can be mixed and injected during injection molding to make nylon cable ties , to avoid the defect that most of the nylon base materials need to be heat-processed twice, which not only endows the nylon cable tie with excellent low temperature resistance, but also has excellent mechanical properties.

Description

technical field [0001] The invention belongs to the technical field of polymer materials and processing, and in particular relates to a nylon masterbatch suitable for low-temperature nylon cable ties, a preparation method and application thereof. Background technique [0002] Cable ties are a kind of wire and cable accessories. The low-temperature cable ties are very light and strong. They are mainly used to bundle items, and they can also withstand low temperatures during use. For many special places Very practical. At present, the popular low-temperature cable ties on the market are mainly nylon cable ties. Size, during use, customers do not need to measure the size again, and can use it directly, which can significantly reduce the workload during use; moreover, the service life of low-temperature cable ties is also very long, and many production companies Will choose to use cable ties. Especially in recent years, the application of nylon cable ties in construction and ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L77/02C08L77/06C08L51/06C08L51/04C08L23/08C08K5/20C08K5/134C08K5/526C08K9/04C08K3/34C08J3/22
CPCC08J3/226C08J2377/06C08J2477/02C08J2477/06C08J2451/06C08J2451/04C08J2423/08C08K5/20C08K5/1345C08K5/526C08K9/04C08K3/346C08K3/34
Inventor 张洪生贾翠丽张杨张磊
Owner 张家港绿洲新材料科技有限公司
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