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Preparation method of transparent fireproof gel and composite fireproof glass

A gel and transparent technology, applied in the direction of parallel glass structures, windows/doors, building components, etc., can solve the problems of low water glass modulus, poor dispersion stability, viscosity increase, etc., to avoid indirect losses and improve fire resistance , the effect of low overall cost

Active Publication Date: 2022-05-10
应急管理部天津消防研究所
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method has the following problems: firstly, the price of silica raw materials with a specific particle size is relatively high; secondly, silica needs to be modified in advance to make the dispersion more uniform and stable, so the operation is more complicated and further increases the cost, and the stability of the dispersion is poor; in addition, during the dispersion process, the overall viscosity of the solution will rise sharply, and problems such as difficulty in dispersion will occur. Even if the viscosity is reduced by adding an alkaline solution to adjust the pH, a higher viscosity cannot be obtained Silica dispersion with solid content, which limits the improvement of the fire resistance limit of composite fireproof glass
In addition, water glass is also commonly used as a raw material to prepare transparent gel for composite fireproof glass, but due to the low modulus and low solid content of water glass, the prepared transparent gel has poor strength and general fire resistance.
[0004] It can be seen from the current technical methods for preparing composite fireproof glass that there are still problems such as high cost, difficult dispersion, complicated operation, poor stability, low solid content, and poor fire resistance.

Method used

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  • Preparation method of transparent fireproof gel and composite fireproof glass
  • Preparation method of transparent fireproof gel and composite fireproof glass
  • Preparation method of transparent fireproof gel and composite fireproof glass

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] The raw materials were prepared according to the components and dosages of Example 1 shown in Table 1, and the thickness of the glass was 5mm. Follow the steps below to prepare composite fireproof glass.

[0046] 1) Add 15 parts by weight of a stabilizer to 100 parts of alkaline silica sol, mix at 1000 rpm for 30 minutes, continue stirring while raising the temperature to 80°C for evaporation and concentration, when the evaporation amount is alkaline silica sol 5% of the parts (ie 5 parts by weight), cooled to room temperature, and stirred at 1000 rpm for 2 hours to obtain an inorganic dispersion;

[0047] 2) Add 60 parts by weight of an aqueous solution of potassium hydroxide with a mass fraction of 50% to the inorganic dispersion prepared above, stir at room temperature at 1000 rpm for 10 min, heat up to 50° C. and stir for 30 min in a vacuum state, After cooling, the transparent fireproof gel precursor liquid is prepared, and it is used for subsequent use;

[0048]...

Embodiment 4

[0055] The dispersant in Example 4 and Example 5 is γ-aminopropyltriethoxysilane.

Embodiment 6

[0056] In Example 6 and Example 7, the dispersant is gamma-glycidyl etheroxypropyl trimethoxysilane, and the flame retardant is sodium phosphate. In Example 8-11, the dispersant is methyltrimethoxysilane, and the flame retardant is Guanidine phosphate, the carbon forming agent is pentaerythritol.

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Abstract

The invention discloses a transparent fireproof gel, which comprises the following components in parts by weight: 100 parts of alkaline silica sol, 30-60 parts of curing agent and 5-55 parts of auxiliary agent, the auxiliary agent consists of 5-5 parts 20 parts of stabilizer, 0-10 parts of dispersant, 0-15 parts of flame retardant and 0-10 parts of char-forming agent. The present invention also discloses a method for preparing composite fireproof glass using the transparent fireproof gel of the above formula, which uses alkaline silica sol as the base material, wherein a stable inorganic dispersion with high solid content is obtained by a concentration method, and a transparent fireproof glass is obtained. Gel; the fire resistance limit of the composite fireproof glass prepared by using the transparent fireproof gel can reach 25-143min; the preparation method solves the relatively high cost in the process of preparing transparent fireproof gel and composite fireproof glass with silica particles as the base material High, difficult to disperse, complex operation, poor stability, low solid content and other problems.

Description

technical field [0001] The invention relates to the field of composite fireproof glass, in particular to a composite fireproof glass and a transparent fireproof gel contained therein. Background technique [0002] With the rapid development of my country's economy, society and urban construction, a large number of large buildings and underground buildings have sprung up, and new products and materials have been put into use, and new fire safety issues have also been brought. Modern buildings have an increasing demand for glass and its products. Safety and fire prevention is a new functional requirement for glass in modern buildings, and fire-resistant glass has emerged as the times require. Fire-resistant glass is a type of special glass that can maintain its integrity and even heat insulation in the prescribed fire-resistant test. The composite fire-resistant glass is to add fire-resistant glue between two or more pieces of glass to make it solidify into a transparent gel. ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C27/12E06B3/67E06B3/677C04B28/24C04B111/28
CPCC03C27/10E06B3/67E06B3/677C04B28/24C04B2111/28C04B24/42C04B24/2623C04B24/06C04B24/02C04B24/124C04B24/00C04B22/062C04B24/005C04B22/16C04B24/003C04B24/125C04B24/126C04B22/0013
Inventor 商珂王俊胜赵璧吴颖捷韩伟平金星刘丹
Owner 应急管理部天津消防研究所
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