A kind of polyfunctionalized cross-linked polyarylene butanedione anion exchange membrane and preparation method thereof
A technology of polyarylene butanedione and anion exchange membrane, which is applied in electrochemical generators, fuel cells, electrical components, etc., and can solve problems such as attack, membrane mechanical properties and electrical conductivity decline
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Embodiment 1
[0030] Synthesis of dibromo-substituted polyarylene butanedione: Add 4.024g (16.5mmol) of 1,4-dibromo-2,3-butanedione and 2.313g (15mmol) of biphenyl into a 50mL single-necked flask, Add 22.5mL of dichloromethane and 5.3mL of trifluoromethanesulfonic acid, react at 0°C for 6h. After the reaction is completed, the product is slowly poured into methanol under stirring, and a filamentous polymer product is precipitated. The product is repeatedly washed and soaked with methanol, and then dried to obtain a polymer. Dissolve the polymer with N-methylpyrrolidone into a solution of a certain concentration. After the solution is completely dissolved, pour the solution into methanol to precipitate the polymer. After repeated washing several times, dry it in a vacuum oven for 6 hours at room temperature to obtain a polymer product.
[0031] Synthesis of combined polyarylene butanedione anion exchange membrane: Dissolve 0.16 g of dibromosubstituted polyarylene butanedione in 4.4 mL of N-m...
Embodiment 2
[0037] Synthesis of dibromo-substituted polyarylene butanedione: Add 4.024g (16.5mmol) of 1,4-dibromo-2,3-butanedione and 2.313g (15mmol) of biphenyl into a 50mL single-necked flask, Add 22.5mL of dichloromethane and 5.3mL of trifluoromethanesulfonic acid, react at 0°C for 6h. After the reaction is completed, the product is slowly poured into methanol under stirring, and a filamentous polymer product is precipitated. The product is repeatedly washed and soaked with methanol, and then dried to obtain a polymer. Dissolve the polymer with N-methylpyrrolidone into a solution of a certain concentration. After the solution is completely dissolved, pour the solution into methanol to precipitate the polymer. After repeated washing several times, dry it in a vacuum oven for 6 hours at room temperature to obtain a polymer product.
[0038] Synthesis of combined polyarylene butanedione anion exchange membrane: Dissolve 0.16 g of dibromosubstituted polyarylene butanedione in 4.4 mL of N-m...
Embodiment 3
[0044] Synthesis of dibromosubstituted polyarylene butanedione: same as Example 2
[0045]Synthesis of combined polyarylene butanedione anion exchange membrane: Dissolve 0.16 g of dibromosubstituted polyarylene butanedione in 4.4 mL of N-methylpyrrolidone in a 25 mL one-necked flask, add 4.4 μL of N,N, N',N'-tetramethyl-1,6-hexanediamine, stirred for 30 minutes, centrifuged the casting solution and cast it in a glass mold, dried at 30°C for 24 hours, and then heated to 60°C for 24 hours to obtain a polymer film .
[0046] Preparation of multifunctional cross-linked polyarylene butanedione anion exchange membrane: Soak the joint polyarylene butanedione anion exchange membrane in 10% N-methylpiperidine aqueous solution at 80°C for 48h, Then soak in deionized water for 24 hours, then soak in 1mol / L KOH solution at room temperature for 48 hours, then repeatedly wash with deionized water and soak for 48 hours until neutral, then the multi-functional cross-linked polyarylene Diace...
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