Online measuring device for photo ionization efficiency curve of cigarette smoldering side-stream smoke gas phase composition

A technology for side-stream flue gas and gas phase composition is applied in the field of chemical composition analysis of cigarette smoke, which can solve the problems of differences in the combustion state of cigarette combustion cones, affecting the stability of side-stream flue gas, and unable to provide a stable flue gas injection flow, etc. Achieve the effect of real-time measurement, simple structure and convenient measurement

Pending Publication Date: 2019-08-30
CHINA TOBACCO ANHUI IND CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When the smoking machine periodically smokes cigarettes, the side stream smoke will be generated periodically, which cannot provide a stable smoke sampling flow
Even when the smoking machine does not smoke and let the cigarette smolder naturally, as the cigarette burns, the length of the cigarette gradually becomes shorter, and the cigarette burning cone gradually approaches the fishtail cover, which will cause more smoke. The gas is adsorbed on the side wall of the fishtail hood; on the other hand, due to the different air velocity in different parts of the fishtail hood, the combustion state of the cigarette combustion cone will be different, which will also affect the stability of the sidestream smoke injection flow. sex
Therefore, this type of analysis device is not suitable for online measurement of the photoionization efficiency curve of cigarette sidestream smoke, and there is no report on the measurement method and device of the photoionization efficiency curve of cigarette sidestream smoke components.

Method used

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  • Online measuring device for photo ionization efficiency curve of cigarette smoldering side-stream smoke gas phase composition
  • Online measuring device for photo ionization efficiency curve of cigarette smoldering side-stream smoke gas phase composition
  • Online measuring device for photo ionization efficiency curve of cigarette smoldering side-stream smoke gas phase composition

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A special research cigarette with a length of 15 cm, a circumference of 24.2 mm and no filter was used as the research object; the inner diameter and length of the smoke transmission quartz capillary were set to 100 μm and 25 cm, respectively, and the heating temperature was set to 200 ℃; the working flow rate of the flowmeter is set to 2000mL / min; the energy scanning step size of the photoionization time-of-flight mass spectrometer is set to 4 angstroms, the measurement time of each mass spectrogram is set to 10 seconds, and the photon energy scanning range is set to Set at 8.0-10.6eV. After the measurement, plot the photon energy value on the abscissa and the ion intensity on the ordinate to obtain the photoionization efficiency curves of flue gas components with different mass numbers.

[0036] The photoionization efficiency curves of several representative smoke components with mass numbers of 54, 78, 92 and 106 in the gas phase of cigarette smoldering sidestream sm...

Embodiment 2

[0038] Basically the same as in Example 1, the difference is that a conventional cigarette with a cigarette length of 84 mm, a tipping paper length of 32 mm, and a circumference of 24.2 mm is selected as the research object; The three energy ranges of 8.0-8.7eV, 8.7-9.6eV and 9.6-10.6eV are measured separately, that is, the first cigarette is measured in the energy range of 8.0-8.7eV, and then the second cigarette is measured in the energy range of 8.7-9.6eV. cigarette, and finally a third cigarette was measured in the energy range of 9.6-10.6eV. After the measurement is over, integrate the photon energy of each scanning energy segment and the corresponding mass spectrum peak ion intensity into the same file, and plot the photon energy value on the abscissa and the ion intensity value on the ordinate to obtain different mass-charge values. The photoionization efficiency curve of specific flue gas components in the photon energy range of 8.0-10.6eV.

[0039] The photoionizatio...

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Abstract

The invention discloses an online measuring device for a photo ionization efficiency curve of a cigarette smoldering side-stream smoke gas phase composition. The online measuring device is characterized in that a non-combustion end of a cigarette is inserted into a cigarette insertion seat of a stepping cigarette sampler capable of controlling the movement direction and speed of the cigarette; a combustion end extends into the internal center of a rough end part of a fishtail cover; the outlet of a fine end part of the fishtail cover is connected with a flowmeter and a membrane vacuum pump insequence through a Cambridge filter clamper and a smoke flow pipe; a smoke flow pipe between the Cambridge filter clamper and the flowmeter communicates with one port of a smoke transmission quartz capillary passing through the pipe wall; and the other port of the smoke transmission quartz capillary passes through a cavity wall of a photo ionization flight time mass spectrometer and enters a vacuum-ultraviolet photo ionization area. The online measuring device is simple in structure, and is suitable for online measurement of the photo ionization efficiency curve of the cigarette smoldering side-stream smoke gas phase composition, so that the online authentication function for a geometric isomer is realized.

Description

technical field [0001] The invention belongs to the technical field of analysis of chemical components of cigarette smoke, and in particular relates to an on-line measurement device for the photoionization efficiency curve of the gas phase components of smoldering sidestream smoke of cigarettes, so as to realize the homogeneity and differentiation of the gas phase components of smoldering sidestream smoke of cigarettes The function of online identification of conformation. Background technique [0002] Combustion of a cigarette usually includes two modes of smoking and smoldering, wherein smoking refers to the burning of a cigarette when it is sucked, and smoldering refers to the natural combustion of a cigarette during the smoking interval. Due to the different combustion modes of cigarette smoking and smoldering, two forms of cigarette smoke are produced, namely mainstream smoke and sidestream smoke. The smoke drawn from the filter end of the cigarette during smoking is c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N27/64
CPCG01N27/64
Inventor 胡永华郑丰潘洋王健孔俊胡立中
Owner CHINA TOBACCO ANHUI IND CO LTD
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