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A kind of high temperature resistant foamed ceramics prepared by FCC waste catalyst and preparation method thereof

A foamed ceramic and waste catalyst technology, which is applied to ceramic products, other household appliances, household appliances, etc., can solve the problem of not being able to fundamentally solve the problem of waste catalyst disposal, reducing the output of FCC waste catalyst, and the limited recovery and reuse effect. Achieve the effect of improving mechanical stability, low ceramic density, and good thermal insulation performance

Active Publication Date: 2021-12-28
JIANGSU HIGH TECHNO THERMAL EQUIP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The more catalyst particles contaminated with heavy metals, the stronger their magnetic susceptibility, which makes it possible to separate and recycle spent catalysts by magnetic separation; Catalysts that are light (low magnetic agent), good performance, and can still be used can only be treated by traditional methods for those catalysts that have been significantly deactivated, so the problem of disposal of spent catalysts cannot be fundamentally solved, and only reduced Production of spent FCC catalysts, no recycling of spent catalysts
The chemical method is mainly the chemical revival method of spent FCC catalysts. The spent catalysts are mixed and soaked with specific chemical reagents to remove heavy metals such as Ni and V on the spent catalysts, restore part of the specific surface area and pore volume of the catalysts, and then reuse them. to the catalytic cracking unit; however, the chemical method requires the use of a large amount of chemical reagents, and causes a certain amount of chemical pollution, and can only restore part of the catalytic performance of the catalyst, and the recovery and reuse effect is limited

Method used

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  • A kind of high temperature resistant foamed ceramics prepared by FCC waste catalyst and preparation method thereof
  • A kind of high temperature resistant foamed ceramics prepared by FCC waste catalyst and preparation method thereof
  • A kind of high temperature resistant foamed ceramics prepared by FCC waste catalyst and preparation method thereof

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preparation example Construction

[0048] The present invention also provides a method for preparing the high-temperature-resistant foamed ceramic described in the above-mentioned technical solution, comprising the following steps:

[0049] (1) FCC waste catalyst, Al 2 o 3 Powder, SiO 2 mixing the powder and coagulant to obtain a first mixture; mixing the binder, dispersant and water to obtain a second mixture; mixing the first mixture with the second mixture to obtain a first ceramic slurry;

[0050] (2) Adding a foaming agent, a foam stabilizer and a pH regulator to the first ceramic slurry in sequence to obtain a second ceramic slurry;

[0051] (3) adding a reinforcing body to the second ceramic slurry, and then foaming to obtain a foamed ceramic slurry;

[0052] (4) performing vibration treatment after injecting the foamed ceramic slurry until no more air bubbles with a diameter of 10 mm or more escape in the ceramic slurry to obtain an injection molded ceramic slurry;

[0053] (5) Demoulding the inject...

Embodiment 1

[0065] In parts by mass, the preparation raw materials used are: 30 parts of FCC waste catalyst, Al 2 o 3 Powder 25 parts, SiO 2 5 parts of powder, 7 parts of coagulant, 10 parts of binder, 1 part of dispersant, 1 part of foaming agent, 2 parts of foam stabilizer, 10 parts of reinforcement, 20 parts of deionized water and to adjust the waste containing FCC Catalyst, Al 2 o 3 Powder, SiO 2 Powder, coagulant, binder, dispersant, foaming agent, foam stabilizer and water mixed system pH value to 8-11 based on the pH value regulator.

[0066] The preparation method is as follows: 3kg FCC waste catalyst, 2.5kgAl 2 o 3 Powder, 0.5kg SiO 2 Flour and 0.7kg starch are stirred and mixed to obtain the first mixture, then add the second mixture composed of 2kg deionized water, 1kg silica sol and 0.1kg ammonium polyacrylate to the first mixture, and use an electric mixer at 900r / min Stir rapidly for 30 minutes at a certain stirring speed to form the first ceramic slurry with stable ...

Embodiment 2

[0072] In terms of parts by mass, the preparation raw materials used are: 36 parts of FCC spent catalyst, Al 2 o 3 24 parts powder, SiO 2 10 parts of powder, 6 parts of coagulant, 10 parts of binder, 1 part of dispersant, 2 parts of foaming agent, 3 parts of foam stabilizer, 10 parts of reinforcement, 20 parts of deionized water and to adjust the waste containing FCC Catalyst, Al 2 o 3 Powder, SiO 2 Powder, coagulant, binder, dispersant, foaming agent, foam stabilizer and water mixed system pH value to 8-11 based on the pH value regulator.

[0073] The preparation method is as follows: 180g FCC waste catalyst, 120g Al 2 o 3 powder, 50g SiO 2 Powder and 30g starch are stirred and mixed to obtain the first mixture, and then the second mixture composed of 100g deionized water, 50g silica sol and 5g ammonium polyacrylate is added to the first mixture, and stirred at 2000r / min by an electric mixer Stir rapidly at a high speed for 10 minutes to form the first ceramic slurry ...

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Abstract

The invention belongs to the technical field of inorganic fire-resistant and heat-insulating materials, and in particular relates to a high-temperature-resistant foamed ceramic prepared from FCC waste catalyst, which is prepared from the following raw materials in parts by mass: 18-50 parts of FCC waste catalyst; Al 2 o 3 Powder 22~40 parts; SiO 2 0-10 parts of powder; 5-8 parts of coagulant; 9-12 parts of binder; 0.8-1.2 parts of dispersant; 5-15 parts of reinforcement; 1-2 parts of foaming agent; 2-3 parts of foam stabilizer ; 15-20 parts of water and a pH regulator. The present invention uses FCC waste catalyst, Al 2 o 3 Powder and SiO 2 The powder is the ceramic base material, and the ratio is optimized. The high-temperature-resistant foam ceramics obtained have a higher service temperature and a lower thermal conductivity, and realize efficient recycling and reuse of FCC spent catalysts.

Description

technical field [0001] The invention belongs to the technical field of inorganic fire-resistant and heat-insulating materials, and in particular relates to a high-temperature-resistant foamed ceramic prepared from FCC waste catalyst and a preparation method thereof. Background technique [0002] Catalytic cracking (FCC) is an important part of modern petroleum refining process. The FCC process is a process of cracking heavy raw materials at a certain temperature and under the action of a catalyst. It is the main method of lightening heavy oil. During the operation of the FCC unit, the high temperature and the poisoning effect of heavy metals lead to the reduction of catalyst activity and cannot meet the requirements of catalytic cracking reaction. In order to maintain a certain activity of the catalyst in the FCC unit, it is necessary to regularly replenish fresh catalyst and remove some deactivated catalyst from the regenerator, so waste FCC catalyst will continue to be pro...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/10C04B35/622C04B35/80C04B38/02
CPCC04B35/10C04B35/622C04B38/02C04B35/62204C04B2235/3418C04B2235/3227C04B2235/3229C04B2235/3272C04B2235/3201C04B2235/3206C04B2235/3208C04B2235/3232C04B2235/3239C04B2235/3275C04B2235/3279C04B2235/3284C04B2235/3286C04B2235/3213C04B2235/3244C04B2235/3294C04B2235/5228C04B2235/526C04B2235/77C04B2235/9607C04B2235/9615C04B38/0074
Inventor 刘和义崔宏亮刘涛张敏
Owner JIANGSU HIGH TECHNO THERMAL EQUIP CO LTD
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