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A method for separating oil and mud from oily sludge

A kind of technology of poly-oil sludge and system, which is applied in the direction of oxidation treatment sludge, mining wastewater treatment, etc., can solve the problems of poly-oil-containing sludge, polymer residue, and inclusion pollutants, etc., achieve low oil content and simplify subsequent steps.

Active Publication Date: 2022-01-18
CHINA NAT OFFSHORE OIL CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the main method of separating oily sludge is to use a certain concentration of a certain surfactant solution to mix and stir with oily sludge to achieve the purpose of oil and mud separation, but this method often leads to turbidity of the treatment liquid , mixed with a large amount of pollutants, resulting in a new problem of difficulty in subsequent sewage treatment
Especially for sludge containing polymers, the surfactants used are easy to interact with polymers to form difficult-to-handle gel complexes, which are difficult to handle later
[0004] In the actual oil recovery process, the use of polymers increases the oil recovery efficiency of crude oil, but it also leads to polymer residues in oily sludge, resulting in polymer-containing oil sludge.

Method used

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  • A method for separating oil and mud from oily sludge
  • A method for separating oil and mud from oily sludge

Examples

Experimental program
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Effect test

Embodiment 1

[0040] 24mL of thiourea / hydrogen peroxide (mass percentage ratio = 1:1) with a concentration of 1% in mass percentage was reacted with 8g of oily sludge (45°C, 800rpm), stirred for 15min, kept at a constant temperature of 45°C for 15min, and used 10mL Take out the water phase with a syringe and place it in a glass bottle, measure the water phase taken out three times with an oil meter and take the average value to obtain the oil content, which is 20836 mg / L.

Embodiment 2

[0042] 24mL of 3% thiourea / hydrogen peroxide (mass percentage ratio = 1:1) reacted with 8g of oily sludge (45°C, 800rpm), stirred for 15min, kept at a constant temperature of 45°C for 15min, and used 10mL Take out the water phase with a syringe and place it in a glass bottle, measure the water phase taken out three times with an oil meter and take the average value to obtain the oil content, which is 18768mg / L.

Embodiment 3

[0044] 24mL thiourea / hydrogen peroxide (mass percentage ratio = 1:1) with 4% concentration by mass percent was reacted with 8g oily sludge (45°C, 800rpm), stirred for 15min, kept at a constant temperature of 45°C for 15min, and used 10mL Take out the water phase with a syringe and place it in a glass bottle, measure the water phase taken out three times with an oil meter and take the average value to obtain the oil content, which is 28804 mg / L.

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Abstract

The invention discloses a method for separating oil and mud from oily sludge. It includes the following steps: using a redox system to carry out mixed reaction with oily sludge, standing still, and then removing the water phase to separate oil, mud and water in the oily sludge; the redox system is a reducing agent aqueous solution and an oxidizing agent aqueous solution. The method of the invention can decompose HPAM and release oil droplets or solid substances wrapped in polymers, and obtain oil-cement three-phase substances after standing still. The invention can obtain a clear water phase with low oil content, and can simplify the subsequent steps of oily sludge treatment, so as to achieve the purpose of recovering crude oil.

Description

technical field [0001] The invention relates to a method for separating oil and mud from oily sludge, which belongs to the field of petrochemical industry. Background technique [0002] Oily sludge with high oil content, high viscosity, and difficult dehydration will be produced in the process of crude oil extraction, transportation, and sewage treatment. The accumulation of these oily sludges leads to pollution of the atmosphere, water resources, and cultivated land, and its rich oil content will cause a large waste of resources. Therefore, it is of great significance to separate the oily sludge and extract the oil from the oily sludge. [0003] At present, the main method of separating oily sludge is to use a certain concentration of a certain surfactant solution to mix and stir with oily sludge to achieve the purpose of oil and mud separation, but this method often leads to turbidity of the treatment liquid , mixed with a large amount of pollutants, resulting in a new p...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F11/06C02F103/10
Inventor 张健华朝王秀军靖波康晓东陈文娟王大威陈晏如荆世尧谭业邦
Owner CHINA NAT OFFSHORE OIL CORP
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