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Reforming hydrogen production reactor, hydrogen production conversion furnace and hydrogen production reaction method

A reforming hydrogen production and reactor technology, applied in chemical instruments and methods, hydrogen, inorganic chemistry, etc., can solve the problems of reducing the operation period of the device, biased flow of raw materials, and low conversion rate of raw materials, so as to improve the conversion efficiency and reduce the Mass transfer resistance, the effect of improving space-time yield

Active Publication Date: 2021-03-02
SINOPEC ENG +1
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The existing hydrogen production conversion furnace is filled with a nickel-based catalyst of a certain particle size and shape in the furnace tube, which often causes uneven loading, causing the raw material gas to drift, resulting in a low conversion rate of the raw material, and the catalyst is prone to carbon deposition and deactivation. operating cycle
In addition, the catalyst with smaller particle size is loaded in the furnace tube, although it can increase the loading amount of the catalyst, increase the number of catalyst active centers, and improve the processing capacity and conversion rate of raw materials to a certain extent, the disadvantage is that the smaller the catalyst size, the furnace The larger the pipe pressure drop, the higher the energy consumption of the feed gas compressor

Method used

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  • Reforming hydrogen production reactor, hydrogen production conversion furnace and hydrogen production reaction method
  • Reforming hydrogen production reactor, hydrogen production conversion furnace and hydrogen production reaction method
  • Reforming hydrogen production reactor, hydrogen production conversion furnace and hydrogen production reaction method

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Embodiment 1

[0085] Such as figure 1 , figure 2 As shown, the reforming hydrogen production reactor used in this embodiment includes a pressure-bearing shell 12 with a first straight pipe 11 at the upper end and a second straight pipe 14 at the lower end. A sleeve 15 and a sleeve 15 are arranged inside the shell. A radial catalytic reaction zone formed by a central cylinder 13; the upper part of the first straight pipe 11 is provided with an air inlet 1, and the lower part of the second straight pipe 14 is provided with an air outlet 2. The micro-catalysis reaction plate 10 and the micro-catalysis reaction plate 6 of the central cylinder extend axially respectively, and the micro-catalysis reaction plate 10 in the sleeve 15 is radially arranged around the central cylinder 13, and the angle between the flat plate and the horizontal direction is 90°, and the central cylinder 13 , the sleeve 15 and the housing 12 are coaxially arranged; the central cylinder micro-catalysis reaction plate 6 ...

Embodiment 2

[0096] Such as figure 1 , image 3 , Figure 9 As shown, the reforming hydrogen production reactor and the reforming furnace of the present embodiment are the same as the reactor size of the embodiment 1, the distance between two adjacent catalytic reaction plates, the distance between the annular gaps, the substrate material of the micro-reaction plate and the active component per unit area NiO The payload parameters are the same. The difference from Example 1 is that in this embodiment, the micro-catalytic reaction plate 10 and the central tube micro-catalytic reaction plate 6 are tooth-shaped micro-reaction plates, and the wave direction is along the radial direction of the reactor. For the tooth-shaped plate, the distance between the crest and the trough is 3mm, and the distance between two adjacent crests or adjacent troughs on the same micro-catalytic reaction plate 10 or central cylinder micro-catalytic reaction plate 6 is 5.5mm. The reforming hydrogen production rea...

Embodiment 3

[0101] Such as figure 1 , Figure 4 , Figure 11 As shown, the reforming hydrogen production reactor and the reforming furnace of the present embodiment are the same as the reactor size of the embodiment 1, the distance between two adjacent catalytic reaction plates, the distance between the annular gaps, the substrate material of the micro-reaction plate and the active component per unit area NiO The payload parameters are the same. The difference from Example 1 is that the micro-catalytic reaction plate in this example is a corrugated micro-reaction plate, and the wave direction is along the radial direction of the reactor. For the corrugated plate, the distance between the crest and the trough is 3mm, and the distance between two adjacent crests or adjacent troughs of the same microplate is 5.5mm.

[0102] Similarly, the reforming hydrogen production reactor and reformer of this embodiment are applied to the hydrogen production reaction by steam reforming of natural gas....

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Abstract

The disclosure relates to a reforming hydrogen production reactor, a hydrogen production conversion furnace and a hydrogen production reaction method. The reforming hydrogen production reactor and the conversion furnace adopt a micro-catalytic reaction plate, and the activity required for the hydrogen production reaction is loaded on the reaction plate Components, reducing the amount of catalytically active metals and the catalyst is not easy to be deactivated by carbon deposition, shortening the distance from the reaction gas to the catalytic active center, reducing the mass transfer resistance and reactor pressure drop, and improving the conversion rate of the hydrogen production reaction; the reaction gas Flowing from the center to the outside in the reactor, the flow channel area gradually increases, and the temperature of the reaction plate gradually increases, which is conducive to the improvement of the conversion rate of the hydrogen production reaction as a volume increase and endothermic reaction; the reforming hydrogen production reactor uses Wide range, as the furnace tube of the hydrogen production reformer, it can be applied to different types of reformer. The hydrogen production method using the reforming hydrogen production conversion furnace has a lower pressure of the furnace tube, a high time-space yield of the catalyst per unit volume in the furnace tube, and a high conversion rate of the raw material gas treatment capacity, which can meet the requirements of the hydrogen production reaction.

Description

technical field [0001] The present disclosure relates to the field of reforming hydrogen production, in particular, to a reforming hydrogen production reactor, a hydrogen production conversion furnace and a hydrogen production reaction method. Background technique [0002] Hydrogen is not only an important chemical raw material, but also a clean fuel. Hydrogen plays an increasingly important role in modern industry, especially petrochemical industry, fuel cell and other national economies. Under the multiple pressures of increasing crude oil quality and inferior quality in the world, increasing demand for clean oil products, continuously improving quality standards, and increasingly stringent environmental regulations, the demand for hydrogen is also increasing, and the demand for hydrogen production is also increasing. Devices also put forward higher requirements. [0003] Hydrogen production processes mainly include water electrolysis, light hydrocarbon steam reforming, ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B3/40C01B3/38
CPCC01B3/38C01B3/40C01B2203/0227C01B2203/0233C01B2203/1041C01B2203/1058C01B2203/1241C01B2203/141Y02P20/52
Inventor 张旭戴文松蒋荣兴
Owner SINOPEC ENG
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