Treatment method of high-salt solid waste containing organic matters
A solid waste and treatment method technology, which is applied in the field of high-salt solid waste treatment and can solve problems such as unsatisfactory membrane performance
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Embodiment 1
[0111] Dissolve 5 parts of block polyether amide copolymer (Pebax2533 for the grade) in 40 parts of isopropanol, heat and stir, control the temperature at 80°C, and heat for 5 hours to form a sol solution. Weigh 5 parts of nanocrystalline SiO2 (particle size range 20-40nm) solid, dissolve it in 10 parts of isopropanol, stir and mix evenly, add it dropwise into the mixed sol, and stir for 30 minutes to obtain a nanocrystalline SiO2 polymer mixed solution. 30 parts of polyacrylonitrile carbon fibers were impregnated with the nanocrystalline SiO2 polymer mixed solution, and pulled out at a rate of 5 cm / min. The modified carbon fibers were dried at 80° C. for 12 hours. Then high temperature treatment at 1300°C for 3h in Ar atmosphere. The TEM picture of the carbon fiber that present embodiment obtains is as figure 1 shown.
Embodiment 2
[0113] Dissolve 20 parts of polyetheramide copolymer (Pebax3533 for the grade) in 20 parts of isopropanol, heat and stir, control the temperature at 80°C, and heat for 12 hours to form a sol solution. Weigh nanocrystalline SiO 2 (Particle size range 40-100nm) 20 parts, dissolved in 10 parts of isopropanol, stirred and mixed evenly, added dropwise to the mixed sol, stirred for 30 minutes to obtain nanocrystalline SiO 2 Polymer mixed solution. 10 parts of polyacrylonitrile carbon fibers were impregnated with the nanocrystalline SiO 2 The polymer mixed solution is pulled out afterward, and the extraction speed is 20cm / min. Dry the modified carbon fiber at 80°C for 12h. Then it was treated at 1500°C for 10h in an Ar atmosphere. The TEM picture of the carbon fiber that present embodiment obtains is as figure 2 shown.
Embodiment 3
[0115] Dissolve 5 parts of polyether amide copolymer (Pebax7233 for the grade) in 40 g of tetrahydrofuran, heat and stir, control the temperature at 80°C, and heat for 5 hours to form a sol solution. Weigh nanocrystalline SiO 2 (Particle size range 100-300nm) 5 parts, dissolved in 20 parts of tetrahydrofuran, stirred and mixed evenly, added dropwise into the mixed sol, stirred for 30 minutes, to obtain nanocrystalline SiO 2 Polymer mixed solution. 50 parts of polyacrylonitrile carbon fibers were impregnated with the nanocrystalline SiO 2 The polymer mixed solution is pulled out afterward, and the extraction speed is 5cm / min. Dry the modified carbon fiber at 80°C for 12h. Then high temperature treatment at 1300°C for 10h in Ar atmosphere. The TEM picture of the carbon fiber that present embodiment obtains is as image 3 As shown, the XRD pattern is as Figure 4 shown.
[0116] Table 1 uses different nanocrystalline SiO for carbon fibers 2 Comparison of mechanical proper...
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