Soluble temporary blocking material for well fracturing and preparation method of soluble temporary blocking material for well fracturing
An oil and gas well, soluble technology, applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve the problems of increased construction period, poor solubility of cross-linked polymers, formation damage, etc., to achieve increased production, good temporary The effect of blocking the steering and the effect of low ground damage
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Embodiment 1
[0024] Nitrogen was passed through the reaction system to replace the air, and then fumaric acid (fumaric acid) and pentaerythritol monomers were added into a four-necked round-bottomed flask according to the mass ratio and stirred, wherein 98.5 g of fumaric acid was added into 100 g of distilled water to fully dissolve , add 110 g of pentaerythritol; then add 0.32 g of initiator and gradually heat the system to 100 ° C, after 25 min of heat preservation, add AMPS solution neutralized with sodium hydroxide to the system (dissolve with distilled water, add 25 g of AMPS to 25 g of distilled water, then add 4 g sodium hydroxide). Then the temperature of the system was raised to 140°C and kept for 0.5h. Then, 15 g of phenoxyethanol was added to the reaction system for reaction, and 0.08 g of initiator was added and the temperature was raised to 165° C., and the temperature was lowered after 2 hours of reaction. After the reaction is completed, the obtained product is purified and...
Embodiment 2
[0028] Nitrogen was passed through the reaction system to replace the air, and then itaconic acid and trimethylolpropane monomers were added into a four-necked round-bottomed flask according to the mass ratio and stirred, wherein 105g of itaconic acid was fully dissolved in 100g of distilled water, and trimethylolpropane was added Methylpropane 97g; then add 0.30g initiator and gradually heat up the system to 105°C, keep warm for 30min and add AMPS solution neutralized with sodium hydroxide to the system (dissolve with distilled water, add 21g AMPS to 30g distilled water, then add 4g sodium hydroxide). Then raise the temperature of the system
[0029] The molecular weight is 16500-18500.
[0030] In order to ensure that the obtained temporary plugging material has good hydrophilicity, the embodiment of the present invention adopts a synthetic main chain with a linear structure, and uses itaconic acid and trimethylolpropane containing three hydroxyl groups as the synthetic u...
Embodiment 3
[0032] The soluble temporary plugging material obtained in Example 1 was heated, melted and extruded by a screw extruder, cut and granulated by a granulator, and shaped into particles with a particle size of 5-8 mm to obtain temporary plugging particles. After crushing and sieving, a 20-120 mesh powder is obtained.
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