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Method for preparing waterborne silicate zinc-enriched antirust and antiseptic paint from surface-activated and grafted glass flakes

A glass flake and surface activation technology, applied in anti-corrosion coatings, coatings, etc., can solve problems such as poor compatibility and affect the anti-corrosion performance of coatings, and achieve the effects of good compatibility, improved compatibility, and improved performance.

Inactive Publication Date: 2019-03-08
ANHUI TENGLONG PUMP VALVE MFG CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the significant differences in the chemical structure and physical form of glass flakes and polymers, the compatibility between the two is poor, which seriously affects the anti-corrosion performance of coatings.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A method for preparing water-based silicate zinc-rich anti-rust and anti-corrosion paint with surface-activated grafted glass flakes is characterized in that it comprises the following steps:

[0022] (1) Preparation of surface-activated grafted glass flakes:

[0023] Add xylene to 16 parts of glass flakes at a ratio of 1:15, stir and disperse at high speed for 20 minutes, then add KH560 hydrolyzate dropwise at 60-65°C under nitrogen protection, raise the temperature to 80-85°C for 2 hours, then raise the temperature to 105-115°C React at ℃ for 50 minutes, wash with xylene for 3 times, wash with tetrahydrofuran for 2 times, Soxhlet purification for 10 hours, then vacuum dry at 110-113℃ to obtain glass flakes with surface-activated grafted KH560;

[0024] (2) Modification of mica iron oxide filler:

[0025] Add anhydrous toluene to 5 parts of micaceous iron oxide at 1:20, stir for 30 minutes and then ultrasonically treat for 20 minutes. Under nitrogen protection, add 3 ...

Embodiment 2

[0031] A method for preparing water-based silicate zinc-rich anti-rust and anti-corrosion paint with surface-activated grafted glass flakes is characterized in that it comprises the following steps:

[0032] (1) Preparation of surface-activated grafted glass flakes:

[0033] Add xylene to 20 parts of glass flakes at a ratio of 1:15, stir and disperse at high speed for 30 minutes, then add KH560 hydrolyzate dropwise at 60-65°C under nitrogen protection, heat up to 80-85°C for 3 hours, then raise the temperature to 105-115°C Reaction at ℃ for 70 minutes, washing with xylene 4 times and tetrahydrofuran 3 times, after Soxhlet purification for 12 hours, vacuum drying at 110-113 ℃ to obtain glass flakes with surface-activated grafted KH560;

[0034] (2) Modification of mica iron oxide filler:

[0035] Add anhydrous toluene to 10 parts of micaceous iron oxide at 1:20, stir for 40 minutes and then ultrasonically treat for 30 minutes. Under nitrogen protection, add 6 parts of toluene ...

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Abstract

The invention discloses a method for preparing a waterborne silicate zinc-enriched antirust and antiseptic paint from surface-activated and grafted glass flakes. The method comprises adding and mixingxylene into the glass flakes for dispersion, under nitrogen protection, dropwise adding in KH560 hydrolysate, increasing the temperature for reaction, washing reaction products with xylene and tetrahydrofuran, performing Soxhlet extraction and vacuum drying to obtain surface-activated and grafted KH560 glass flakes, adding and mixing mica iron oxide into absolute methylbenzene, performing ultrasonic treatment, under nitrogen protection, dropwise adding in a mixture of toluene diisocyanate, dibutyltin dilaurate and absolute methylbenzene for reaction, increasing the temperature for further reaction, filtering and repeatedly washing reaction products with absolute methylbenzene to obtain a toluene diisocyanate-modified mica iron oxide filler; mixing film forming materials into a sanding anddispersing mixer, then mixing in deionized water and zinc powder, and then continuing to mixing in the toluene diisocyanate-modified mica iron oxide filler to obtain the waterborne silicate zinc-enriched antirust and antiseptic paint.

Description

technical field [0001] The invention belongs to the technical field of chemical pumps, and in particular relates to a method for preparing water-based silicate zinc-rich antirust and anticorrosion paint by using surface-activated grafted glass flakes. Background technique [0002] In chemical or petrochemical production, chemical pumps need to work in high temperature, low temperature, high pressure, flammable, explosive, toxic and strong corrosive media, and have high performance requirements. Chemical pumps can also work under high inlet pressure, high viscosity, Working under the conditions of small flow and high cavitation, the performance requirements of chemical pumps are high. When manufacturing chemical pumps, a layer of corrosion-resistant paint is usually coated on the pump body to protect the pump body. The impellers of chemical pumps also need to be in contact with a large amount of corrosive substances, and also require high surface corrosion resistance. [000...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D201/00C09D1/00C09D5/10C09D7/62
CPCC09D7/62C09D201/00C09D1/00C09D5/106C08K2003/0893C08K7/00C08K3/40C08K9/06C08K9/04C08K3/22C08K3/08
Inventor 徐向远
Owner ANHUI TENGLONG PUMP VALVE MFG CO LTD
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