Three-chamber electrodialysis hydrogen production fermentation reactor and hydrogen production method

An electrodialysis and reactor technology, which is applied in the field of fermentation reactors, can solve problems such as high energy consumption, and achieve the effects of increasing hydrogen production, realizing separation and recovery of by-products, and simple structure.

Active Publication Date: 2019-02-01
CHONGQING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the large amount of aeration required in the aerobic tank, there is a problem of high energy consumption

Method used

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  • Three-chamber electrodialysis hydrogen production fermentation reactor and hydrogen production method
  • Three-chamber electrodialysis hydrogen production fermentation reactor and hydrogen production method
  • Three-chamber electrodialysis hydrogen production fermentation reactor and hydrogen production method

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Embodiment 1: The method for producing hydrogen using the described three-chamber electrodialysis hydrogen production fermentation reactor comprises the following steps:

[0025] A. Make a three-chamber electrodialysis hydrogen production fermentation reactor. The reactor parameters are: the length, width and height of the anode chamber 3 and the cathode chamber 1 are 3cm, 4cm, and 5cm, that is, the volume is 60mL; The length, width and height are 6cm, 4cm, and 5cm, that is, the volume is 120mL; the dimensions of the cation exchange membrane 5 and the anion exchange membrane 4 are both 4cm×5cm, that is, 20cm 2 , The length, width and thickness of the graphite electrodes 6 and 7 are 5 cm, 4 cm and 0.2 cm.

[0026] B. Connect the gas collection chamber 15 in the fermentation chamber 2 with an external gas collection bag to collect the gas generated during the dark fermentation process.

[0027] C. Inoculate the activated sludge with a volume ratio of 10% in the fermentat...

Embodiment 2

[0031] Embodiment 2: The difference between this embodiment and Embodiment 1 is that in step C, inoculate activated sludge with a volume ratio of 10% and add substrate glucose and ammonia nitrogen to simulate high ammonia nitrogen organic wastewater, so that the concentration of glucose in the fermentation chamber is 10g / L, NH 4 + The concentration is 3000mg / L, and other operating and experimental parameters are the same.

[0032] see Figure 4A to Figure 4E , a in the figure is a traditional fermentation reactor, and b is a three-chamber electrodialysis hydrogen production fermentation reactor of the present invention.

[0033] As can be seen from the figure, compared with the traditional fermentation reactor under the same conditions, the hydrogen production in this embodiment was increased by 48%, and the concentration of volatile fatty acids in the fermentation chamber was reduced by 20%. 4 + The concentration was reduced by 59%, the concentration of volatile fatty aci...

Embodiment 3

[0035] Embodiment 3: Utilize the simulated fermentation liquid acetic acid to carry out the removal experiment.

[0036] The difference between this embodiment and Embodiment 1 is that in step C, acetic acid: 20 mmol / L is added to the fermentation chamber 2.

[0037] see Figure 5A to Figure 5B , as can be seen from the figure, the removal efficiency of acetic acid reached 95% after 96h. The enrichment concentration of acetic acid in the anode chamber can reach 25mmol / L.

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PUM

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Abstract

The invention discloses a three-chamber electrodialysis hydrogen production fermentation reactor and a hydrogen production method. The three-chamber electrodialysis hydrogen production fermentation reactor includes: an anode chamber, a fermentation chamber, a cathode chamber, a cathode electrode, an anode electrode, an anion exchange membrane and a cation exchange membrane. The fermentation reactor is characterized in that: the cathode chamber and the fermentation chamber are separated by the cation exchange membrane; the anode chamber and the fermentation chamber are separated by the anion exchange membrane; the cathode electrode and the anode electrode are respectively disposed in the cathode chamber and anode chamber; and the cathode electrode and the anode electrode are inert graphiteelectrodes, the electrode surface area is the same as the ion exchange membrane surface area, the cathode electrode and the anode electrode are externally connected to a direct current power supply negative pole and positive pole respectively, the upper part of the cathode chamber is equipped with a first discharge and drain port, and the lower part is equipped with a first water inlet. The reactor provided by the invention can achieve effective removal and enrichment of ammonia nitrogen in high ammonia nitrogen organic wastewater and volatile fatty acids produced during fermentation, and canbe widely applied to biology, energy, chemical industry and other fields.

Description

technical field [0001] The invention relates to a fermentation reactor, in particular to a three-chamber electrodialysis hydrogen production fermentation reactor and a hydrogen production method. Background technique [0002] The direct discharge of organic wastewater from agriculture and animal husbandry will cause serious environmental pollution due to the high content of COD and ammonia nitrogen, so it needs to be treated before discharge. The use of anaerobic fermentation hydrogen production technology to treat agricultural and animal husbandry organic wastewater can not only bring environmental benefits, but also bring added value because anaerobic fermentation hydrogen production technology can use microorganisms to digest organic matter to generate hydrogen. As a clean energy, hydrogen energy is known as the most potential energy in the 21st century. In the process of anaerobic fermentation hydrogen production, microorganisms can digest organic matter in wastewater t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C12M1/107C12M1/00C02F1/469C02F101/16C02F101/34
CPCC02F1/4693C02F2101/16C02F2101/34C12M21/04C12M23/42C12M33/04
Inventor 夏奡韦鹏飞廖强付乾黄云李俊朱恂
Owner CHONGQING UNIV
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