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A kind of preparation method of the colored rickshaw tread rubber of high-fill environment-friendly high-strength tire reclaimed rubber

A technology for reclaimed rubber and bicycle tires, which is applied in the field of preparation of colored bicycle tread rubber. It can solve the problems of narrow distribution of molecular chains, heavy equipment load, and large shrinkage of rubber materials, so as to achieve low vulcanization tendency and reduce power consumption. , The effect of accelerating the vulcanization speed

Active Publication Date: 2021-07-09
XUZHOU COLLEGE OF INDAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The tread rubber of rickshaw tires is generally made of natural rubber (NR), butadiene rubber (BR) and styrene-butadiene rubber (SBR). Generally, SBR accounts for about 30%, and the side group of the low-temperature emulsion poly-SBR molecular main chain introduces phenyl , and form vinyl side groups in the 1,2 structure of butadiene, with large steric hindrance, poor molecular chain flexibility, narrow relative molecular chain distribution, and lack of low-molecular-level plasticizing effect, so the processability is poor
The specific manifestations are poor wettability to the compounding agent during mixing, rapid temperature rise, and large equipment load; large shrinkage of the rubber during calendering; difficult operation during extrusion, large expansion rate of semi-finished products; poor self-adhesiveness during molding
The amount of rubber used in the tread of rickshaw tires is relatively large. If the rubber material heats up quickly and the mixing time is long, not only the rubber material is easy to burn, but also the power of the equipment is large and many other problems.
In addition, the amount of SBR in the tread rubber is too large, which makes the cost of the tire too high, which is not conducive to the development of enterprises and the use of consumers.

Method used

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  • A kind of preparation method of the colored rickshaw tread rubber of high-fill environment-friendly high-strength tire reclaimed rubber
  • A kind of preparation method of the colored rickshaw tread rubber of high-fill environment-friendly high-strength tire reclaimed rubber
  • A kind of preparation method of the colored rickshaw tread rubber of high-fill environment-friendly high-strength tire reclaimed rubber

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] The formula of a kind of colored rickshaw tread rubber that is highly filled with environmentally friendly and high-strength tire reclaimed rubber is as follows:

[0032] Various raw materials and their mass parts are:

[0033] Natural rubber (NR)…………60

[0034] Butadiene rubber (SBR)…………40

[0035] Environmentally friendly high-strength tire reclaimed rubber (TRR) ... 40

[0036] White carbon black………………45

[0037] Pine tar………………5.0

[0038] Vulcanizing agent S 8 …………… 2.5

[0039] Accelerator M……………2.0

[0040] Accelerator D……………1.0

[0041] Triethanolamine………2.0

[0042] Active agent ZnO………5.0

[0043] Active agent SA………3.0

[0044] Antiaging agent 2246………1.0

[0045] Paraffin…………1.0

[0046] Its preparation method, carry out as follows:

[0047] At room temperature, 14.5 Kg of NR and 9.6 Kg of BR were first plasticized using an open mill XK-450 (capacity of 50Kg), and then the NR and BR plasticized rubbers were combined and pressed, and 9.6 Kg of enviro...

Embodiment 2

[0050] The formula of a kind of colored rickshaw tread rubber that is highly filled with environmentally friendly and high-strength tire reclaimed rubber is as follows:

[0051] Various raw materials and their mass parts are:

[0052] Natural rubber (NR)…………60

[0053] Butadiene rubber (SBR)…………40

[0054] Environmental protection high strength tire reclaimed rubber (TRR) 55

[0055] White carbon black………………55

[0056] Pine tar………………5.0

[0057] Vulcanizing agent S 8 …………… 2.5

[0058] Accelerator M……………2.0

[0059] Accelerator D……………1.0

[0060] Triethanolamine………2.0

[0061] Active agent ZnO………5.0

[0062] Active agent SA………3.0

[0063] Antiaging agent 2246………1.0

[0064] Paraffin…………1.0

[0065] Its preparation method, carry out as follows:

[0066]Mix 25.4 Kg NR16.9 Kg BR with the internal mixer (filling capacity 140.63 Kg, filling factor 0.7), respectively, combine the NR and BR plasticized rubbers, and add 23.3 Kg of environmentally friendly high-strength ti...

Embodiment 3

[0069] The formula of a kind of colored rickshaw tread rubber that is highly filled with environmentally friendly and high-strength tire reclaimed rubber is as follows:

[0070] Various raw materials and their mass parts are:

[0071] Natural rubber (NR)…………60

[0072] Butadiene rubber (SBR)…………40

[0073] Environmentally friendly high-strength tire reclaimed rubber (TRR) ... 50

[0074] White carbon black………………40

[0075] Pine tar………………5.0

[0076] Vulcanizing agent S 8 …………… 2.5

[0077] Accelerator M……………2.0

[0078] Accelerator D……………1.0

[0079] Triethanolamine………2.0

[0080] Active agent ZnO………5.0

[0081] Active agent SA………3.0

[0082] Antiaging agent 2246 …………1.0

[0083] Paraffin…………1.0

[0084] Its preparation method, carry out as follows:

[0085] At room temperature, 18.4 Kg of NR and 12.2 Kg of BR were masticated separately with an open mill XK-550 (capacity of 65Kg), then the NR and BR plasticized rubbers were combined and pressed, and 15.3 Kg of env...

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Abstract

The invention discloses a preparation method of colored tire tread rubber highly filled with environmentally friendly and high-strength tire reclaimed rubber, wherein the amount of environmentally friendly and high-strength tire reclaimed rubber is 40-55 parts; the preparation method is as follows: firstly, an open mill or The internal mixer plasticizes NR and BR respectively, and then combines the plasticized rubbers of NR and BR for compaction, and adds reclaimed rubber to make the rubber material uniform; add vulcanization accelerator and triethanolamine to the above rubber materials and mix evenly, and then Add white carbon black, pine tar, and finally add sulfur, roll and triangular bag, until the various materials are evenly dispersed with each other, the plasticizing and mixing time is about 25-30min, and then perform performance testing according to GB / T1702-1997, pull The tensile strength is 16.54 MPa, and the elongation at break is 569.9%, which can better meet the needs of the mechanical properties of tire tread rubber; improve tire performance, reduce pollution, and reduce the cost of tires by 10‑30%.

Description

technical field [0001] The invention relates to a preparation method of a colored tire tread rubber highly filled with environmentally friendly and high-strength tire reclaimed rubber, and belongs to the field of tire manufacturing. Background technique [0002] The tread rubber of rickshaw tires is generally made of natural rubber (NR), butadiene rubber (BR) and styrene-butadiene rubber (SBR). Generally, SBR accounts for about 30%, and the side group of the low-temperature emulsion poly-SBR molecular main chain introduces phenyl , and form vinyl side groups in the butadiene 1,2 structure, which has large steric hindrance, poor molecular chain flexibility, narrow relative molecular chain distribution, and lack of low-molecular-level plasticizing effect, so the processability is poor. Specifically, during mixing, the wettability of the compounding agent is poor, the temperature rises quickly, and the load on the equipment is large; during calendering, the rubber material shri...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L7/00C08L9/00C08L17/00C08L91/06C08K13/02C08K3/36C08K3/22C08K3/06C08K5/17B60C1/00
CPCB60C1/0016C08K2003/2296C08L7/00C08L2205/035C08L9/00C08L17/00C08L91/06C08K13/02C08K3/36C08K3/22C08K3/06C08K5/17
Inventor 王艳秋祝木伟鲍桂楠翁国文臧亚南姚亮张小萍刘太闯靳玲
Owner XUZHOU COLLEGE OF INDAL TECH
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