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A kind of preparation method of high energy density lithium-ion battery

A lithium-ion battery and high energy density technology, applied in the field of lithium-ion batteries, can solve the problems of low charging performance at low temperature, low battery storage performance at high temperature, low cycle performance at high temperature, and low battery energy density

Active Publication Date: 2021-04-02
安徽派能能源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Lithium-ion battery is a kind of secondary battery. It mainly relies on lithium ions to move between the positive and negative electrodes. With the development of lithium-ion battery technology, its application is becoming more and more extensive. However, the existing lithium-ion batteries Due to its unreasonable preparation method, there are usually the following defects. On the one hand, the high-temperature storage performance and high-temperature cycle performance of the battery are relatively low; on the other hand, the low-temperature charging performance is also very low; The defects of poor resistance and rate, the battery energy density is very low

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] The preparation method of the high energy density lithium ion battery of this embodiment includes the following steps:

[0018] A. Use low glass temperature acrylic modified chitosan derivative glue to make negative electrode pieces. The proportion of acrylic modified chitosan derivative glue is about 2%. During production, the negative electrode piece is made of 10μm copper foil. Obviously special production defects occur, such as wrinkles, breaks, etc.;

[0019] Among them, the glass transition temperature of the acrylic acid-modified chitosan derivative glue is -15°C, and the acrylic acid-modified chitosan derivative glue is preferably synthesized by acrylic acid modified by seaweed organisms, and the specific preparation method is as follows:

[0020] First dissolve the acrylic modified chitosan derivative glue in deionized water, then add graphite with a particle size of about 15 microns in the negative electrode, carbon black conductive agent, adjust the stirring,...

Embodiment 2

[0025] The preparation method of the high energy density lithium ion battery of the present invention comprises the following steps:

[0026] A. Use low glass temperature acrylic modified chitosan derivative glue to make the negative electrode piece, the proportion of acrylic modified chitosan derivative glue is about 3%, when making, the negative electrode piece is made of 8μm copper foil. Obviously special production defects occur, such as wrinkles, breaks, etc.;

[0027] Among them, the glass transition temperature of the acrylic acid-modified chitosan derivative glue is -20°C, and the acrylic acid-modified chitosan derivative glue is preferably synthesized by acrylic acid modified by seaweed organisms, and the specific preparation method is as follows:

[0028] First dissolve the acrylic modified chitosan derivative glue in deionized water, then add graphite with a particle size of about 15 microns in the negative electrode, carbon black conductive agent, adjust the stirri...

Embodiment 3

[0033] The preparation method of the high energy density lithium ion battery of the present invention comprises the following steps:

[0034] A. Use low glass temperature acrylic modified chitosan derivative glue to make negative electrode pieces. The proportion of acrylic modified chitosan derivative glue is about 2%-5%. During production, the negative electrode piece is made of 6μm copper foil. There is no obvious special production defects in the production process, such as wrinkles, breaks, etc.;

[0035] Among them, the glass transition temperature of the acrylic acid-modified chitosan derivative glue is 25°C, and the acrylic acid-modified chitosan derivative glue is preferably synthesized by acrylic acid modified by seaweed organisms, and the specific preparation method is as follows:

[0036] First dissolve the acrylic modified chitosan derivative glue in deionized water, then add graphite with a particle size of about 15 microns in the negative electrode, carbon black ...

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Abstract

The invention discloses a method for preparing a high energy density lithium ion battery. It includes the following steps: A. Use low glass temperature acrylic modified chitosan derivative glue to make the negative electrode sheet; B. Use a wet separator and pre-coat acrylic glue, C. At a temperature of 70-90°C and a pressure of 0.2 Under the environment of -0.5MPa, pressurize the battery for 20-60 minutes to make the battery; D. Inject the battery with liquid. After the battery is filled with liquid, it is aged at a temperature of 45-55℃ and aged for 70-75 hours. The time allows the electrolyte and acrylic glue to fully combine. After adopting the above method, various parameters are reasonably controlled during the process of making the battery to ensure uniform pressure on the upper, lower, left and right sides of the battery. After pressing, the battery has a hardness similar to that of a solid electrolyte lithium-ion battery, thus greatly improving the high-temperature storage performance and high-temperature cycle performance of the battery. , Low-temperature charging performance, the energy density of its lithium iron battery is increased to about 170wh / kg, without the defects of high internal resistance and poor rate of general solid electrolytes.

Description

Technical field [0001] The invention relates to a method for preparing a high-energy-density lithium-ion battery and belongs to the technical field of lithium-ion batteries. Background technique [0002] Lithium-ion battery is a secondary battery that mainly relies on the movement of lithium ions between the positive and negative electrodes. With the development of lithium-ion battery technology, its applications are becoming more and more widespread. However, existing lithium-ion batteries Because its preparation method is not reasonable, it usually has the following defects. On the one hand, the high-temperature storage performance and high-temperature cycle performance of the battery are relatively low. On the other hand, the low-temperature charging performance is also very low. On the other hand, there is also the high internal content of the solid electrolyte. Due to the defects of poor resistance and rate, the battery energy density is very low. Contents of the inve...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M10/0525H01M10/058
CPCH01M10/0525H01M10/058Y02E60/10Y02P70/50
Inventor 杨庆亨
Owner 安徽派能能源科技有限公司
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