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Ferrotitanium alloy hydrogen storage material used for fuel cell car and preparing method

A technology of titanium-iron alloy and hydrogen storage material, which is applied in metal processing equipment, transportation and packaging, etc., can solve the problems of poor activation and stability of titanium-iron hydrogen storage alloy, poor resistance to gaseous impurity poisoning, difficult alloy surface activation, etc. Improved activation and stability, long service life and low cost

Inactive Publication Date: 2018-11-30
CHENDU NEW KELI CHEM SCI CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] It can be seen that in the metal hydrogen storage materials in the prior art, rare earth metals and transition metals are expensive and have low reserves, and when iron-titanium alloy materials are used, because the use environment is relatively rough and the content of impurity gases is relatively large, it is easy to The surface of the alloy is oxidized and the activation is difficult. At the same time, the anti-poisoning performance of gaseous impurities is poor, and the activation and stability of titanium-iron hydrogen storage alloy are poor, which seriously affects the service life and other problems.

Method used

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  • Ferrotitanium alloy hydrogen storage material used for fuel cell car and preparing method

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] a. Using tetraethyl orthosilicate as a solvent, slowly add a saturated aqueous solution containing iron trichloride and titanium tetrachloride dropwise, while adding a reducing agent, a pore-forming agent and a flocculant for stirring, and using citric acid to adjust the pH value to 4 , standing and aging after complete reaction to obtain a gel-like material;

[0031] b. Uniformly mixing the gel-like material prepared in step a with doped metal powder, performing low-temperature heat treatment under the mixed gas source of argon / hydrogen, and then performing subsequent molding to obtain a titanium-iron alloy hydrogen storage material.

[0032]In step a, the reducing agent is lithium aluminum hydride, the pore forming agent is sodium bicarbonate, and the flocculant is aluminum sulfate; in step b, the doped metal powder is manganese powder;

[0033] In step a, 56 parts by weight of ethyl orthosilicate, 18 parts by weight of iron salt, 18 parts by weight of titanium salt, ...

Embodiment 2

[0036] a. Using tetraethyl orthosilicate as a solvent, slowly add a saturated aqueous solution containing iron trichloride and titanium tetrachloride dropwise, while adding a reducing agent, a pore-forming agent and a flocculant for stirring, and using citric acid to adjust the pH value to 4 , standing and aging after complete reaction to obtain a gel-like material;

[0037] b. Uniformly mixing the gel-like material prepared in step a with doped metal powder, performing low-temperature heat treatment under the mixed gas source of argon / hydrogen, and then performing subsequent molding to obtain a titanium-iron alloy hydrogen storage material.

[0038] In step a, the reducing agent is stannous chloride, the pore forming agent is potassium bicarbonate, and the flocculant is aluminum chloride; in step b, the doped metal powder is magnesium powder;

[0039] In step a, 65 parts by weight of ethyl orthosilicate, 15 parts by weight of iron salt, 15 parts by weight of titanium salt, 3 ...

Embodiment 3

[0042] a. Using tetraethyl orthosilicate as a solvent, slowly add a saturated aqueous solution containing iron trichloride and titanium tetrachloride dropwise, while adding a reducing agent, a pore-forming agent and a flocculant for stirring, and using citric acid to adjust the pH value to 4 , standing and aging after complete reaction to obtain a gel-like material;

[0043] b. Uniformly mixing the gel-like material prepared in step a with doped metal powder, performing low-temperature heat treatment under the mixed gas source of argon / hydrogen, and then performing subsequent molding to obtain a titanium-iron alloy hydrogen storage material.

[0044] In step a, the reducing agent is potassium borohydride, the pore-forming agent is ammonium bicarbonate, and the flocculant is ferric sulfate; in step b, the doped metal powder is manganese powder;

[0045] In step a, 50 parts by weight of ethyl orthosilicate, 20 parts by weight of iron salt, 20 parts by weight of titanium salt, 5 ...

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Abstract

The invention discloses a ferrotitanium alloy hydrogen storage material used for a fuel cell car and a preparing method. The ferrotitanium alloy hydrogen storage material is prepared through the following steps that a, a water solution containing iron salt and titanium salt, a reducing agent, a pore-forming agent and a flocculating agent are added into ethyl orthosilicate, after the stirring reaction, standing and aging are carried out, and a gelatinous material is made; b, the gelatinous material and doped metal powder are mixed for carrying out low-temperature heat treatment, and through subsequent forming, the ferrotitanium alloy hydrogen storage material is obtained. The method has following beneficial effects that silicon dioxide evenly wraps the ferrotitanium alloy surface, the activity and the stability of an alloy material can be obviously improved, the material is large in hydrogen storage amount, the service life is long, the whole preparing process is simple, the cost is low, and the ferrotitanium alloy hydrogen storage material used for the fuel cell car has the wide application prospect.

Description

technical field [0001] The invention relates to the field of fuel cells, in particular to the preparation of hydrogen storage materials, in particular to a ferro-titanium alloy hydrogen storage material for fuel cell vehicles and a preparation method. Background technique [0002] Hydrogen vehicles use hydrogen as the main energy for moving vehicles, using fuel cells and electric motors to replace general engines, that is, hydrogen fuel cells. The principle is to input hydrogen into the fuel cell, and the electrons of the hydrogen atoms are blocked by the proton exchange membrane, and then conduct from the negative electrode to the positive electrode through an external circuit, and become electric energy to drive the motor; however, the protons can be combined with oxygen through the proton exchange membrane to form pure water mist and discharged. Hydrogen can be produced in large quantities from electrolysis of water and coal gasification, and does not require major modifi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22F9/24B22F1/02B22F3/11B22F1/00
CPCB22F3/11B22F9/24B22F1/142B22F1/16
Inventor 陈庆廖健淞
Owner CHENDU NEW KELI CHEM SCI CO LTD
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