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Method of temperature control and chromium preservation in rh decarburization process of ultra-low carbon high chromium steel

A decarburization process, high-chromium steel technology, applied in the field of steelmaking, can solve the problems of difficult temperature control of molten steel, difficult to achieve ultra-low carbon, high-chromium steel smelting, large loss of Cr alloy, etc., to reduce or LF heating power consumption and treatment time, improving RH treatment efficiency, and improving molten steel castability

Active Publication Date: 2020-01-31
ZHANGJIAGANG HONGCHANG STEEL PLATE CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, for most non-production stainless steel enterprises, the production is mainly based on the BOF→LF / RH→CC process route. It is difficult to achieve high-alloy and ultra-low-carbon smelting in RH vacuum furnaces. On the one hand, if Cr is controlled before deep decarburization In place, due to the high Cr content, severe oxidation of Cr is prone to occur in the deep decarburization stage of RH, and the loss of Cr alloy is large; It is difficult to control the temperature of molten steel. It is difficult to meet the smelting requirements by increasing the temperature of molten steel entering the RH station. The RH treatment process requires a large amount of aluminum and oxygen blowing to raise the temperature. If the RH entering station temperature is too high or the temperature compensation during the smelting process is too high, the refractory material will be damaged. In addition, due to the large amount of chromium alloy added, it brings serious carbon return problems, and it is difficult to realize the smelting of ultra-low carbon and high chromium steel
[0004] In view of the above problems, iron and steel enterprises that generally use the BOF→LF / RH→CC process route basically do not produce ultra-low carbon, high-chromium alloy steel or other high-alloy steel. Therefore, for C content less than 0.015%, Cr content greater than 5% ultra-low carbon high alloy steel rarely reported

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] 1) The temperature of molten steel in the RH station is 1615℃, Si content is 0.5%, Mn content is 1.5%, Cr content is 15%, and C content is 0.35%. After the ladle is in place, a three-stage pump is turned on to vacuum, and the vacuum chamber pressure drops below 100mbar. Start blowing oxygen, blowing 150-200Nm at a time 3 , The oxygen blowing is over, and then circulate for 2-5 minutes, then determine the oxygen, measure the temperature, take a sample to measure the carbon, determine the amount of oxygen blowing according to the carbon content, and repeat this operation until the C content drops below 0.1%.

[0030] 2) When the C content reaches below 0.1%, the four-stage vacuum pump is turned on, and when the pressure of the vacuum chamber is reduced to 5-20mbar, 100-150Nm of oxygen will be blown at one time 3 , The oxygen blowing is over, and then circulate for 2-5 minutes, then determine the oxygen, measure the temperature, take a sample to measure the carbon, determine th...

Embodiment 2

[0035] 1) The temperature of molten steel in the RH station is 1625℃, Si content is 0.05%, Mn content is 1.98%, Cr content is 5%, C content is 0.25%. After the ladle is in place, a three-stage pump is turned on to vacuum, and the vacuum chamber pressure drops below 100mbar. Start blowing oxygen, blowing 150-200Nm at a time 3 , The oxygen blowing is over, and then circulate for 2-5 minutes, then determine the oxygen, measure the temperature, take a sample to measure the carbon, determine the amount of oxygen blowing according to the carbon content, and repeat this operation until the C content drops below 0.1%.

[0036] 2) When the C content reaches below 0.1%, the four-stage vacuum pump is turned on, and when the pressure of the vacuum chamber is reduced to 5-20mbar, 100-150Nm of oxygen will be blown at one time 3 , The oxygen blowing is over, and then circulate for 2-5 minutes, then determine the oxygen, measure the temperature, take a sample to measure the carbon, determine the a...

Embodiment 3

[0041] 1) The temperature of molten steel in the RH station is 1605℃, Si content is 0.45%, Mn content is 0.51%, Cr content is 10%, C content is 0.11%. After the ladle is in place, a three-stage pump is turned on to vacuum, and the vacuum chamber pressure drops below 100mbar. Start blowing oxygen, blowing 150-200Nm at a time 3 , The oxygen blowing is over, and then circulate for 2-5 minutes, then determine the oxygen, measure the temperature, take a sample to measure the carbon, determine the amount of oxygen blowing according to the carbon content, and repeat this operation until the C content drops below 0.1%.

[0042] 2) When the C content reaches below 0.1%, the four-stage vacuum pump is turned on, and when the pressure of the vacuum chamber is reduced to 5-20mbar, 100-150Nm of oxygen will be blown at one time 3 , The oxygen blowing is over, and then circulate for 2-5 minutes, then determine the oxygen, measure the temperature, take a sample to measure the carbon, determine the ...

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PUM

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Abstract

The invention discloses a temperature-controlling chrome-protecting method for an ultra-low carbon high chrome steel RH decarbonization process. The temperature-controlling chrome-protecting method for the ultra-low carbon high chrome steel RH decarbonization process comprises the following steps of S1, setting the RH feeding molten steel temperature to be 1605 to 1625 DEG C, enabling molten steelto contain the following chemical components in percentage by mass: 0.05 percent to 0.5 percent of Si, 0.5 percent to 2.0 percent of Mn, 5 percent to 15 percent of Cr, and 0.1 percent to 0.35 percentof C, and vacuumizing after a steel ladle is put in place; blowing oxygen, decarbonizing, and the like. The temperature-controlling chrome-protecting method for the ultra-low carbon high chrome steelRH decarbonization process provided by the invention has the advantages that after RH oxygen blowing and decarbonizing are finished, the C content reaches to the target ingredient, the oxidation lossof the Si and the Mn in the molten steel is lower than 15 percent compared with RH feeding, and the content of the Cr element is reduced to be smaller than 0.5 percent.

Description

Technical field [0001] The invention relates to the technical field of steelmaking, in particular to a temperature control and chromium preservation method for ultra-low carbon high chromium steel RH decarburization process. Background technique [0002] When iron and steel enterprises organize the production of high-chromium alloy steel, they generally choose to adopt the stainless steel smelting process route, namely EAF+AOD or VOD method, mainly EAF+AOD. The process route is short and the investment cost is low. There are many steel enterprises specializing in the production of stainless steel. Use this process route. Another smelting method is EAF + converter (MRP, K-OBM or LD-OB) + VOD method. Due to the VOD, this process can more easily smelt ultra-low carbon and nitrogen stainless steel. [0003] Accordingly, when smelting high chromium steel with Cr content ≥5%, the smelting process of stainless steel can be used to organize production. However, for most non-production st...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21C7/00C21C7/068C21C7/072C21C7/06C21C7/10C22C38/02C22C38/04C22C38/18C22C38/38
CPCC21C7/0006C21C7/06C21C7/068C21C7/072C21C7/10C22C38/004C22C38/02C22C38/04C22C38/18C22C38/38
Inventor 赵家七邹长东黄永林麻晗皇祝平
Owner ZHANGJIAGANG HONGCHANG STEEL PLATE CO LTD
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