A lithium-ion battery negative electrode sheet containing conductive coating and preparation method thereof

A lithium-ion battery and conductive coating technology, which is applied to battery electrodes, secondary batteries, circuits, etc., can solve the problems of further improvement of adhesion, increase of electrode impedance, and insufficient specific surface area, so as to reduce electrochemical Response impedance, increase energy density, effect of small impedance

Active Publication Date: 2021-02-26
WANXIANG 123 CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are also some problems in the above-mentioned conductive coating: 1. Due to the addition of a layer of conductive coating, and the specific surface area of ​​the material in the conductive coating is not large enough, the impedance of the pole piece is increased; 2. Its adhesion to the current collector Still need to be further improved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035]A lithium ion battery negative electrode sheet containing a conductive coating layer includes a copper foil current collector, a conductive coating layer coated on the copper foil current collector, and a negative electrode active material layer coated on the conductive coating layer.

[0036]The negative active material layer is formed by curing the negative electrode slurry, and the negative electrode slurry includes the following parts by weight: 94.8 parts of graphite, 2 parts of conductive carbon black SP, 1.2 parts of sodium carboxymethyl cellulose, 2 parts Parts of styrene butadiene rubber, 140 parts of deionized water; the conductive coating is cured by conductive slurry, and the conductive slurry includes the following parts by weight: 70 parts of composite carbon source (particle size 40-600nm, Specific surface area 100-300m2 / g of carbon black aggregate 20 parts, tube diameter 0.4-5nm, tube length greater than 30um, specific surface area 300-500m220 parts / g of single-wa...

Embodiment 2

[0041]A lithium ion battery negative electrode sheet containing a conductive coating layer includes a copper foil current collector, a conductive coating layer coated on the copper foil current collector, and a negative electrode active material layer coated on the conductive coating layer.

[0042]The negative active material layer is formed by curing the negative electrode slurry. The negative electrode slurry includes the following materials in parts by weight: 94.5 parts of graphite, 2 parts of conductive carbon black SP, 1 part of sodium carboxymethyl cellulose, 2.5 parts by weight Parts of styrene butadiene rubber, 130 parts of deionized water; the conductive coating is cured by conductive slurry, and the conductive slurry includes the following parts by weight: 90 parts of composite carbon source (particle size 40-600nm, Specific surface area 100-300m2 / g of carbon black aggregate 30 parts, tube diameter 0.4-5nm, tube length greater than 30um, specific surface area 300-500m2 / g of...

Embodiment 3

[0047]A lithium ion battery negative electrode sheet containing a conductive coating layer includes a copper foil current collector, a conductive coating layer coated on the copper foil current collector, and a negative electrode active material layer coated on the conductive coating layer.

[0048]The negative electrode active material layer is formed by curing the negative electrode slurry, and the negative electrode slurry includes the following materials in parts by weight: 94.5 parts of graphite, 1.5 parts of conductive carbon black SP, 2 parts of sodium carboxymethyl cellulose, 2 parts Parts of styrene butadiene rubber, 1150 parts of deionized water; the conductive coating is cured by conductive slurry, and the conductive slurry includes the following parts by weight: 50 parts of composite carbon source (particle size 40-600nm, Specific surface area 100-300m2 / g of carbon black aggregate 20 parts, tube diameter 0.4-5nm, tube length greater than 30um, specific surface area 300-500m...

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Abstract

The invention relates to the field of lithium batteries, and discloses a lithium-ion battery negative plate containing a conductive coating and a preparation method thereof. The negative electrode sheet includes a copper foil current collector, a conductive coating, and a negative electrode active material layer. The negative electrode active material layer is formed by solidifying the negative electrode slurry. The negative electrode slurry includes the following materials: 93-95 parts of graphite, 1.5-2.5 parts of conductive Carbon black SP, 1-2 parts of sodium carboxymethyl cellulose, 2-3 parts of styrene-butadiene rubber, 130-150 parts of deionized water; the conductive coating is cured by conductive paste, which includes the following Materials: 10-95 parts of composite carbon source, 5-50 parts of binder, 5-40 parts of dispersant, 450-550 parts of organic solvent. In the present invention, a layer of special conductive paste is coated on the current collector, which has a large specific surface area and low impedance, which can greatly improve the adhesion of the pole piece, enhance the conductivity, reduce the amount of binder and conductive agent added, and improve The energy density of the battery.

Description

Technical field[0001]The invention relates to the field of lithium batteries, in particular to a lithium ion battery negative electrode sheet containing a conductive coating and a preparation method thereof.Background technique[0002]At present, the negative electrode sheet of a lithium ion battery generally includes a current collector and a negative electrode active material coated on the current collector. The current collector of the negative electrode mainly adopts copper foil light foil. Due to the smooth surface of the light foil, the negative electrode active material has a weak interface binding force with the current collector during coating, resulting in poor binding force of the negative electrode active material, which is likely to cause problems such as electrode dropout in the later process. Therefore, the amount of conductive agent added must not be increased, and in order to ensure the adhesion of the electrode, it is necessary to add more binder to the slurry of the...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/133H01M4/583H01M4/62H01M4/1393H01M10/0525
CPCH01M4/133H01M4/1393H01M4/583H01M4/621H01M4/625H01M10/0525Y02E60/10
Inventor 陆挺王涌吴晨琰
Owner WANXIANG 123 CO LTD
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