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Preparation method and application of copper metal organic framework compound

An organic framework and compound technology, applied in the field of preparation of copper metal organic framework compounds, can solve the problems of high production cost of carbon nanotubes, unsatisfactory adsorption effect, difficult regeneration of activated carbon, etc., and achieves high yield, simple preparation method, high The effect of porosity

Active Publication Date: 2018-08-21
GUANGDONG MEDICAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, there are a variety of materials that can be used as adsorbents, such as activated carbon, carbon nanotubes, ion exchange resins, metal oxides, etc., but the production cost of carbon nanotubes is high, and it is difficult to apply on a large scale; activated carbon is difficult to regenerate and reuse; metal oxides The specific surface area of ​​materials such as ion exchange resin and ion exchange resin is small, and the adsorption effect is not ideal

Method used

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  • Preparation method and application of copper metal organic framework compound
  • Preparation method and application of copper metal organic framework compound
  • Preparation method and application of copper metal organic framework compound

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A preparation method of a copper metal organic framework compound, comprising the following steps:

[0033] 1) Mix 2.7g of copper nitrate and 0.9g of 2,5-bis(3',5'-dicarboxyphenyl)-benzoic acid, add 166mL of water and N,N-dimethylformamide mixed solution and stir 3min, then add 11mL of fluoboric acid and stir for 8min to obtain a mixed solution A, wherein the volume ratio of water and N,N-dimethylformamide is 1:1;

[0034] 2) Place the glass bottle sealed with the mixed solution A obtained in step 1) at a temperature of 85°C for 12 hours to obtain crystal B;

[0035] 3) Wash the crystal B obtained in step 2) with ethanol three times, then place the cleaned crystal B in ethanol for 1 day, and replace the ethanol every 12 hours during this period, and finally place the soaked crystal B Dry in an oven at 90° C. for 12 hours to obtain the copper metal organic framework compound.

Embodiment 2

[0037] A preparation method of a copper metal organic framework compound, comprising the following steps:

[0038] 1) Mix 2.7g of copper nitrate and 0.9g of 2,5-bis(3',5'-dicarboxyphenyl)-benzoic acid, add 186mL of water and N,N-dimethylformamide mixed solution and stir 8min, then add 14.3mL fluoboric acid and stir for 3min to obtain mixed solution A, wherein the volume ratio of water and N,N-dimethylformamide is 1:1;

[0039] 2) Place the glass bottle sealed with the mixed solution A obtained in step 1) at a temperature of 95°C for 8 hours to obtain crystal B;

[0040] 3) Wash the crystal B obtained from step 2) with ethanol three times, then place the cleaned crystal B in ethanol for 3 days, and replace the ethanol every 12 hours during this period, and finally place the soaked crystal B Dry in an oven at a temperature of 110° C. for 8 hours to obtain a copper metal organic framework compound.

Embodiment 3

[0042]A preparation method of a copper metal organic framework compound, comprising the following steps:

[0043] 1) Mix 2.7g of copper nitrate and 0.9g of 2,5-bis(3',5'-dicarboxyphenyl)-benzoic acid, add 180mL of water and N,N-dimethylformamide mixed solution and stir 5min, then add 18mL of fluoboric acid and stir for 5min to obtain a mixed solution A, wherein the volume ratio of water and N,N-dimethylformamide is 1:1;

[0044] 2) Place the glass bottle sealed with the mixed solution A obtained in step 1) at a temperature of 90°C for 10 hours to obtain crystal B;

[0045] 3) Wash the crystal B obtained from step 2) with ethanol three times, then place the cleaned crystal B in ethanol for 2 days, and replace the ethanol every 12 hours during this period, and finally place the soaked crystal B Dry in an oven at 100°C for 10 hours to obtain the copper metal organic framework compound.

[0046] In conclusion, the preparation method of copper metal organic framework compound is ...

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Abstract

The invention discloses a preparation method and application of a copper metal organic framework compound. The preparation method comprises the steps of: 1) mixing copper nitrate with 2, 5-bis(3', 5'-dicarboxyphenyl)-benzoic acid, then adding a solvent and performing stirring, then adding fluoroboric acid and performing stirring to obtain a mixed solution A; 2) placing a glass bottle with the sealed mixed solution A obtained in step 1) at 85DEG C-95DEG C for reaction for 8-12h to obtain a crystal B; 3) cleaning the crystal B obtained in step 2) with ethanol three times, then soaking the crystal B in ethanol, and finally drying the crystal in an oven, thus obtaining the copper metal organic framework compound. The preparation method provided by the invention is simple and high in yield. Thecompound prepared by the method provided by the invention has good stability to water and good adsorption ability to drug pollutants, and also has certain desorption ability and recycling ability, and therefore has potential application in adsorption of drug residue in environmental water.

Description

technical field [0001] The invention relates to the technical field of pharmaceutical pollutant adsorbents, in particular to a preparation method and application of a copper metal organic framework compound. Background technique [0002] With the advancement of society and the development of the pharmaceutical industry, in recent decades, more and more water systems have detected residues of various drugs, drug metabolites and pharmaceutical excipients. Drugs mainly include antibiotics, hormones, anti-inflammatory drugs, etc., while pharmaceutical excipients mainly include solubilizers, co-solvents, emulsifiers, colorants, adhesives, etc. These drugs, drug metabolites and pharmaceutical excipients have complex structures and diverse components, and they degrade slowly under natural conditions. At the same time, with the continuous production and use of people, more and more drugs, drug metabolites and pharmaceutical excipients are discharged into the water body. Persistent...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/22B01J20/28B01J20/30C02F1/28C02F101/34C02F101/36C02F101/38
CPCB01J20/226B01J20/28054C02F1/285C02F2101/34C02F2101/36C02F2101/38C02F2101/40
Inventor 刘建强罗志董范舒然张肇升刘伟聪许楚婕李宝红郑明彬沈鑫韩瑶瑶
Owner GUANGDONG MEDICAL UNIV
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