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Green solvent system for preparing perovskite layer of perovskite solar cell and mixed solution

A solar cell and mixed solution technology, which is applied in electric solid devices, circuits, photovoltaic power generation, etc., can solve the problems of not conforming to the concept of green process development, unfavorable perovskite solar cells, and not many perovskite solar cells, etc. The effect of adapting to market demand, simple preparation process, and easy industrialized large-scale production

Active Publication Date: 2018-08-10
GUANGDONG UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] But so far, there are not many studies on the industrialization and application of perovskite solar cells. Taking the preparation process of perovskite layer as an example, the solvents required for its preparation often use solvents such as DMF and DMSO, which have higher boiling points and Low volatility usually requires high and long-term temperature annealing, accompanied by solvent vapor annealing and other difficult-to-control processing processes, which is not conducive to the use of high-throughput roll-to-roll printing technology to prepare perovskite solar cells. Industrialization promotion
More importantly, the above-mentioned solvents still have low toxicity, which is harmful to environmental protection and does not conform to the development concept of today's green technology.

Method used

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  • Green solvent system for preparing perovskite layer of perovskite solar cell and mixed solution
  • Green solvent system for preparing perovskite layer of perovskite solar cell and mixed solution
  • Green solvent system for preparing perovskite layer of perovskite solar cell and mixed solution

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preparation example Construction

[0048] The invention provides a method for preparing a perovskite layer of a perovskite solar cell, comprising the following steps:

[0049] 1) Under a protective atmosphere, spin-coat the mixed solution described in any one of the above technical solutions on the anode buffer layer to obtain a perovskite layer.

[0050] The present invention is not particularly limited to the selection of the anode buffer layer, and the conventional anode buffer layer or hole transport layer of a perovskite solar cell well known to those skilled in the art can be used. Those skilled in the art can according to the actual application situation, Product requirements and quality requirements are selected and adjusted. The anode buffer layer of the present invention, that is, the hole transport layer, preferably includes a spiro-OMeTAD layer, a PEDOT:PSS layer, a PTAA layer or a NiOx layer, and more preferably preferably includes a spiro-OMeTAD layer. layer, PEDOT:PSS layer or NiOx layer, most pr...

Embodiment 1

[0061] The novel green solvent system used in perovskite solar cells in this embodiment is composed of two solvents, dimethyl carbonate and N-methylpyrrolidone, with volume ratios of 3:7, 1:9 and 0.5:9.5, respectively.

[0062] The solubility test and film-forming property test of perovskite are carried out on the new green solvent system of this embodiment; the ultraviolet absorption spectrum test, SEM test and photovoltaic characteristic test are carried out on the perovskite film and device prepared by the new green solvent system, as follows :

[0063] 1. Carry out the solubility test of perovskite to the novel green solvent system of the present embodiment,

[0064] see figure 1 , figure 1 It is a photograph of the appearance of the mixed solvent system provided in Example 1 of the present invention after mixing with the perovskite raw material. Among them, the picture on the left is direct to MAI white powder and PbI 2 Dimethyl carbonate solvent is added to the yello...

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Abstract

The invention provides a solvent system for preparing a perovskite layer of a perovskite solar cell. The system comprises dimethyl carbonate and another solvent; and the other solvent comprises one ormultiple selected from N-methyl 2 pyrrolidone, gamma-butanolide, isopropanol and acetone. The dimethyl carbonate is used in cooperation with the other solvent of N-methyl 2 pyrrolidone and the like,the solvent system is green and degradable, and the environment can be protected. The perovskite solar cell prepared by the solvent system can regulate the morphology of the perovskite layer effectively under the condition of short-time thermal annealing or event without thermal annealing, the problem that technology is hard to control accurately during annealing by solvent steam, and requirementsfor high-flux coil-to-coil printing in future can be met. The preparation technology is simple, conditions are mild, and the system and solution have significance in the commercialized progress of the perovskite solar cell.

Description

technical field [0001] The invention belongs to the technical field of perovskite solar cells, and relates to a green solvent system and a mixed solution for preparing a perovskite layer of a perovskite solar cell, in particular to a solvent for preparing a perovskite layer of a perovskite solar cell A system and a mixed solution, a method for preparing a perovskite layer of a perovskite solar cell, and the perovskite solar cell. Background technique [0002] In recent years, in order to solve the increasingly severe energy and environmental problems, people have turned their attention to the development and utilization of new energy. Among various new energy technologies, photovoltaic power generation is undoubtedly one of the most promising directions. Although traditional silicon-based solar cells have achieved industrialization and have a relatively mature market, their cost performance cannot compete with traditional energy sources, and the pollution and energy consump...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L51/42H01L51/46H01L51/48
CPCH10K71/12H10K71/40H10K85/30H10K30/15Y02E10/549
Inventor 谭婉怡闵永刚
Owner GUANGDONG UNIV OF TECH
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