Lithium ion battery and cathode material thereof
A technology for lithium-ion batteries and negative electrode materials, which is applied in battery electrodes, negative electrodes, secondary batteries, etc., can solve the problems of unbalanced kinetic performance and cycle storage performance, and achieve good application prospects, good mass production, and low cost. cheap effect
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Embodiment 1
[0036] Adopt the following steps to prepare lithium-ion battery negative electrode material and battery:
[0037] Select artificial graphite modified by mechanical fusion (the degree of graphitization is 90%, the D50 particle size is 12 μm, and the specific surface area is 2.0m 2 / g), add the phenolic resin solution that mass fraction is 15%, stir for 2 hours, the stirrer frequency is 30Hz, the mixed solution is dried by the spray drying tower, the spray drying temperature is 550 ℃, and the working time is 2 hours, and the obtained particle diameter is 13μm, specific surface area 1.5m 2 / g of coated artificial graphite particles. Amorphous carbon chooses hard carbon, its degree of graphitization is 65%, D50 particle size is 7μm, specific surface area is 1.5m 2 / g. The coated artificial graphite and hard carbon are mixed according to the mass ratio of 90:10 to obtain the negative electrode material of lithium ion battery, and then the negative electrode material of lithium i...
Embodiment 2
[0039] Select natural graphite modified by mechanical fusion (the degree of graphitization is 96%, the D50 particle size is 13 μm, and the specific surface area is 2.5m 2 / g), add the phenolic resin solution, the mass fraction of the phenolic resin solution is 20%, stir for 3 hours, the stirrer frequency is 25Hz, the mixed solution is dried by the spray drying tower, the spray drying temperature is 450 ℃, and the working time is 3 hours, A particle size of 14 μm and a specific surface area of 1.7 m 2 / g of coated natural graphite particles. The choice of amorphous carbon is the same as in Example 1, and the above-mentioned coated natural graphite and hard carbon are mixed according to the mass ratio of 70:30. All the other are with embodiment 1.
Embodiment 3
[0041] Select artificial graphite modified by mechanical fusion (the degree of graphitization is 90%, the D50 particle size is 15 μm, and the specific surface area is 3m 2 / g), add the phenolic resin solution that mass fraction is 15%, stir for 2 hours, the stirrer frequency is 30Hz, the mixed solution is dried by the spray drying tower, the spray drying temperature is 550 ℃, and the working time is 2 hours, and the obtained particle diameter is 16μm, specific surface area is 2m 2 / g of coated artificial graphite particles. The degree of graphitization of amorphous carbon is 80%, the D50 particle size is 15μm, and the specific surface area is 1.0m 2 / g of hard carbon, the above-mentioned coated artificial graphite and hard carbon are mixed in a mass ratio of 50:50. All the other are with embodiment 1.
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