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Epoxy resin and organic silicon composite pouring sealant and preparation method thereof

An epoxy resin and silicone technology, applied in the field of potting glue, can solve the problems of complicated operation, poor dimensional stability, and many bubbles, etc., and achieve the effects of simple and easy preparation method, moderate curing conditions, and convenient and easy operation.

Active Publication Date: 2018-04-06
上海稳优实业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, there are three main types of potting materials that are widely used, which are epoxy resin, polyurethane and silicone materials. Room temperature curing epoxy resin potting adhesives are widely used in electronic components due to their good mechanical properties and adhesion. However, unmodified epoxy resin has high rigidity, poor toughness under high and low temperature impact, easy cracking of the adhesive layer, and poor dimensional stability caused by thermal expansion and contraction under high and low temperature; silicone materials It has excellent high and low temperature resistance, weather resistance and electrical insulation, but it has the defects of low thermal conductivity, poor flame retardancy and poor bonding performance; polyurethane materials have the best waterproof, acid resistance, flexibility and impact resistance. It is better, but when it is used as an electronic packaging glue, there are more air bubbles, and it needs to be vacuumed and filled, and the operation is more complicated

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] An epoxy resin silicone composite potting glue, composed of component A and component B in a weight ratio of 1:1;

[0031] The A component includes the following raw materials in parts by weight: 45 parts of bisphenol A epoxy resin, 10 parts of alumina-coated graphene, 5 parts of epoxy siloxane coupling agent, and 5 parts of dibenzyl phosphate;

[0032] The B component includes the following raw materials in parts by weight: 45 parts of amino silicone oil, 5 parts of aminosilane coupling agent, 10 parts of alumina-coated graphene;

[0033] The preparation method of the alumina-coated graphene comprises the following steps: adding 1000 g of distilled water and 10 g of emulsifier sodium dodecylbenzenesulfonate to 100 g of graphene treated at 280 ° C, and adding dilute hydrochloric acid to adjust the pH of the suspension Value to neutral, and ultrasonic dispersion. After heating to 200°C, slowly add 500 g of aluminum chloride solution with a mass fraction of 10% into the ...

Embodiment 2

[0041] An epoxy resin silicone composite potting glue, composed of A component and B component with a weight ratio of 1:1.2;

[0042] The A component includes the following raw materials in parts by weight: 48 parts of o-cresol novolac epoxy resin, 13 parts of alumina-coated graphene, 7 parts of epoxy siloxane coupling agent, and 7 parts of dibenzyl phosphate;

[0043] The B component includes the following raw materials in parts by weight: 48 parts of amino silicone oil, 7 parts of aminosilane coupling agent, and 13 parts of alumina-coated graphene;

[0044] The preparation method of alumina-coated graphene comprises the following steps: adding 1000 g of distilled water and 20 g of emulsifier polyoxypropylene polyvinyl glyceryl ether to 100 g of graphene treated at 290 ° C, and adding dilute hydrochloric acid to adjust the pH value of the suspension To neutral, and ultrasonic dispersion. After heating to 220°C, slowly add 600g of aluminum chloride solution with a mass fracti...

Embodiment 3

[0052] An epoxy resin silicone composite potting glue, composed of component A and component B in a weight ratio of 1:1.7;

[0053] The A component includes the following raw materials in parts by weight: 55 parts of epoxy resin, 17 parts of alumina-coated graphene, 7 parts of epoxy siloxane coupling agent, and 8 parts of dibenzyl phosphate;

[0054] The B component includes the following raw materials in parts by weight: 55 parts of amino silicone oil, 7 parts of aminosilane coupling agent, and 16 parts of alumina-coated graphene;

[0055] The preparation method of alumina-coated graphene comprises the following steps: adding 1000 g of distilled water and 22 g of emulsifier nonylphenol polyoxyethylene ether to 100 g of graphene treated at 285 ° C, adding dilute hydrochloric acid to adjust the pH value of the suspension To neutral, and ultrasonic dispersion. After heating to 240° C., slowly add 700 g of aluminum chloride solution with a mass fraction of 16% into the suspensio...

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PUM

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Abstract

The invention discloses an epoxy resin and organic silicon composite pouring sealant and a preparation method thereof. The epoxy resin and organic silicon composite pouring sealant is composed of a component A and a component B which are in the weight ratio of 1:(1-2); the component A comprises the following raw materials in parts by weight: 45-65 parts of epoxy resin, 10-20 parts of aluminum oxide coated graphene, 5-8 parts of epoxysiloxane coupling agent and 5-10 parts of dibenzyl phosphate; and the component B comprises the following raw materials in parts by weight: 45-65 parts of amino silicon oil, 5-8 parts of aminosilane coupling agent and 10-20 parts of aluminum oxide coated graphene. The epoxy resin and organic silicon composite pouring sealant disclosed by the invention overcomesthe defects of a traditional pouring sealant, has excellent mechanical property, insulation property, sealing property, waterproofness, thermal conductivity, flame retardance, chemical stability andbonding property and is simple and easy to realize pouring-sealing operation.

Description

technical field [0001] The invention relates to the technical field of potting glue, in particular to an epoxy resin and silicone composite potting glue and a preparation method thereof. Background technique [0002] With the development of economy and society, electronic materials and electronic products have sprung up like mushrooms. In order to cooperate with the development of electronic materials and electronic products, people have proposed new methods for the potting adhesive used for bonding, potting and packaging of electronic components. Requirements, not only require it to have excellent mechanical properties, perfect appearance, insulation, sealing, waterproof, but also require it to have good thermal conductivity, flame retardancy, chemical stability, and require its filling operation to be convenient. [0003] At present, there are three main types of potting materials that are widely used, which are epoxy resin, polyurethane and silicone materials. Room temper...

Claims

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Application Information

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IPC IPC(8): C09J163/00C09J183/10C09J163/04C09J11/04C09J11/06C08G77/44
CPCC08G77/26C08K2003/2227C08L2201/02C08L2201/08C08L2203/206C08L2312/00C09J11/04C09J11/06C09J183/08C08L63/00C08K13/06C08K9/10C08K3/042C08K3/22C08K5/5435C08K5/544C08K5/521C08L63/04
Inventor 李丽娟
Owner 上海稳优实业有限公司
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