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Flame-retardant lithium battery electrolyte

An electrolyte, lithium battery technology, applied in secondary batteries, circuits, electrical components, etc., can solve the problems of battery failure, uneven passivation of lithium metal surface, dendrite phenomenon, etc., to increase safety and reduce the risk of spontaneous combustion Effect

Inactive Publication Date: 2018-03-23
杨彬
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The currently used electrolyte is mainly composed of organic solvents and lithium salts, and this electrolyte is prone to chemical reactions with lithium metal, resulting in uneven passivation of the lithium metal surface, resulting in dendrites during charging and discharging, making the battery invalid. Moreover, organic solvents are flammable and explosive, and there are potential safety hazards; and the life of conventional lithium batteries is generally 500 charge-discharge cycles, and the excellent ones can reach 600 charge-discharge cycles
As an important part of lithium batteries, electrolyte has a direct impact on the life of lithium batteries. Traditional lithium battery electrolytes have large internal resistance, poor stability, and are sensitive to temperature, especially in high-temperature environments. The stability of lithium battery electrolytes will decrease. A sharp decrease, there is a great security risk

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A flame-retardant lithium battery electrolyte, in parts by weight, comprising the following components: 21 parts by weight of dimethyl sulfoxide, 1 part by weight of tribromoethane, 25 parts by weight of dibromomethylfuran, 5 parts by weight of pyrrolidone, 15 parts by weight of potassium methylsulfonimide, 1 part by weight of lithium phosphate, 1 part by weight of sodium carboxymethylcellulose, 1 part by weight of sodium polyaspartate, and 1 part by weight of p-phenylenediamine oxalate.

[0019] Its preparation method comprises the following steps:

[0020] 1) Weigh the compounds of each component in proportion, and mix to obtain a mixed solution;

[0021] 2) The mixed solution in step 1) is further mixed uniformly under ultrasonic conditions to obtain the flame retardant lithium battery electrolyte of the present invention.

[0022] The ultrasonic frequency in the step 2) was 1200 Hz, and the ultrasonic time was 2 hours.

Embodiment 2

[0024] A flame retardant lithium battery electrolyte, in parts by weight, comprising the following components: 25 parts by weight of dimethyl sulfoxide, 5 parts by weight of tribromoethane, 31 parts by weight of dibromomethylfuran, 11 parts by weight of pyrrolidone, 21 parts by weight of potassium methylsulfonimide, 5 parts by weight of lithium phosphate, 5 parts by weight of sodium carboxymethylcellulose, 5 parts by weight of sodium polyaspartate, and 5 parts by weight of p-phenylenediamine oxalate.

[0025] Its preparation method comprises the following steps:

[0026] 1) Weigh the compounds of each component in proportion, and mix to obtain a mixed solution;

[0027] 2) The mixed solution in step 1) is further mixed uniformly under ultrasonic conditions to obtain the flame retardant lithium battery electrolyte of the present invention.

[0028] The ultrasonic frequency in the step 2) was 1200 Hz, and the ultrasonic time was 2 hours.

Embodiment 3

[0030] A flame-retardant lithium battery electrolyte, in parts by weight, comprising the following components: 22 parts by weight of dimethyl sulfoxide, 3 parts by weight of tribromoethane, 26 parts by weight of dibromomethylfuran, 8 parts by weight of pyrrolidone, 18 parts by weight of potassium methylsulfonimide, 2 parts by weight of lithium phosphate, 2 parts by weight of sodium carboxymethylcellulose, 2 parts by weight of sodium polyaspartate, and 1.5 parts by weight of p-phenylenediamine oxalate.

[0031] Its preparation method comprises the following steps:

[0032] 1) Weigh the compounds of each component in proportion, and mix to obtain a mixed solution;

[0033] 2) The mixed solution in step 1) is further mixed uniformly under ultrasonic conditions to obtain the flame retardant lithium battery electrolyte of the present invention.

[0034] The ultrasonic frequency in the step 2) was 1200 Hz, and the ultrasonic time was 2 hours.

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PUM

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Abstract

The invention relates to a flame-retardant lithium battery electrolyte. The flame-retardant lithium battery electrolyte comprises the following components in parts by weight: 21-25 parts of dimethyl sulfoxide, 1-5 parts of tribromoethane, 25-31 parts of dibromomethylfuran, 5-11 parts of pyrrolidone, 15-21 parts of potassium methylsulfonylimine, 1-5 parts of lithium phosphate, 1-5 parts of sodium carboxymethylcellulose, 1-5 parts of sodium polyaspartate and 1-5 parts of p-phenylenediamine oxalate. The invention provides the flame-retardant lithium battery electrolyte, so that the using capacityof a lithium battery can be higher than 80% of the theoretical capacity thereof.

Description

technical field [0001] The invention relates to the field of new energy, in particular to a flame retardant lithium battery electrolyte. Background technique [0002] In lithium-ion batteries, lithium metal and carbon materials can be used as anode materials, and when lithium metal is used as the anode material, it can provide large capacity and high output voltage. The electrolyte currently used is mainly composed of organic solvent and lithium salt, and this electrolyte is prone to chemical reaction with lithium metal, resulting in uneven passivation of the surface of lithium metal, so that dendrites appear during the charging and discharging process, and the battery fails. In addition, organic solvents are flammable and explosive, and there are potential safety hazards; and the life of conventional lithium batteries is generally 500 charge-discharge cycles, and the excellent ones can reach 600 charge-discharge cycles. As an important part of lithium batteries, electrolyt...

Claims

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Application Information

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IPC IPC(8): H01M10/0566H01M10/0567
CPCH01M10/0566H01M10/0567Y02E60/10
Inventor 杨彬
Owner 杨彬
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