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Preparation method of incomplete dehydrated magnesium chloride snow-melting agent

A technology of magnesium chloride and snow melting agent, applied in magnesium chloride, chemical instruments and methods, magnesium halide and other directions, can solve the problems of polluting the ecological environment of the salt lake, restricting the sustainable development of the salt lake potash fertilizer industry, complicated preparation process, etc. The effect of promoting sustainable development and low preparation cost

Inactive Publication Date: 2017-11-24
QINGHAI INST OF SALT LAKES OF CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Bischoferte contains six crystal waters, and the quality of crystal water is about 53% of the total mass, which makes the transportation cost of bischomite expensive; at the same time, if it is not airtightly packaged, it will absorb water in humid air Therefore, a large amount of bicholorite piled up in the salt lake area not only pollutes the ecological environment of the salt lake, but also restricts the sustainable development of the potash fertilizer industry in the salt lake
[0003] Existing deicing agents are generally calcium chloride deicing agents and organic and inorganic composite deicing agents, but calcium chloride deicing agents have the problems of high cost, complicated preparation process, and unsatisfactory snow melting effect, while organic and inorganic deicing agents Composite deicing agent also has the problem of high cost

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] This example provides a preparation method of an incompletely dehydrated magnesium chloride deicing agent. The incompletely dehydrated magnesium chloride deicing agent uses bischofite as a by-product of the salt lake as a raw material, and can make full use of this part of by-products, not only turning waste into treasure , save resources, and avoid pollution of the salt lake ecological environment, and provide guarantee for the sustainable development of the salt lake potash industry.

[0018] The preparation method of the incompletely dehydrated magnesium chloride deicing agent according to this embodiment includes the following steps: dehydrating the bischofite by-product of the salt lake in a fluidized equipment at 50°C to 70°C to obtain the first incompletely dehydrated Magnesium chloride deicing agent.

[0019] Specifically, the incompletely dehydrated magnesium chloride in the obtained first incompletely dehydrated magnesium chloride deicing agent has 4 to 6 crys...

Embodiment 2

[0026] In the description of Embodiment 2, the similarities with Embodiment 1 will not be repeated here, and only the differences with Embodiment 1 will be described. The difference between embodiment 2 and embodiment 1 is that in the process of preparing the incomplete dehydration magnesium chloride deicing agent in embodiment 2, the first incomplete dehydration magnesium chloride deicing agent obtained in embodiment 1 must continue to be fluidized Two-stage dehydration is carried out in the bed at 100°C to 130°C, thereby obtaining a second incompletely dehydrated magnesium chloride deicing agent; the incompletely dehydrated magnesium chloride in the second incompletely dehydrated magnesium chloride deicing agent has 3 to 4 crystal waters.

[0027] It is worth noting that, in the process of changing from the first incompletely dehydrated magnesium chloride deicing agent to the second incompletely dehydrated magnesium chloride deicing agent, the bed area of ​​the fluidized bed,...

Embodiment 3

[0030] In the description of Embodiment 3, the similarities with Embodiment 2 will not be repeated here, and only the differences with Embodiment 2 will be described. The difference between embodiment 3 and embodiment 2 is that in the process of preparing the incomplete dehydration magnesium chloride deicing agent in embodiment 3, the second incomplete dehydration magnesium chloride deicing agent obtained in embodiment 2 must be continued in fluidization Three stages of dehydration are carried out in the bed at 150°C to 180°C, thereby obtaining a third incompletely dehydrated magnesium chloride deicing agent; the incompletely dehydrated magnesium chloride in the third incompletely dehydrated magnesium chloride deicing agent has 2 to 3 crystal waters.

[0031] In this embodiment, in the process of changing from the second incompletely dehydrated magnesium chloride deicing agent to the third incompletely dehydrated magnesium chloride deicing agent, the bed area, feed amount, dehy...

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Abstract

The invention belongs to the technical field of comprehensive utilization of salt lake resources and particularly relates to a preparation method of an incomplete dehydrated magnesium chloride snow-melting agent. The preparation method comprises the following step: performing one-section dehydration on a byproduct bischofite of a salt lake in fluidization equipment at the temperature of 50-70 DEG C, so as to obtain a first incomplete dehydrated magnesium chloride snow-melting agent, wherein incomplete dehydrated magnesium chloride in the first incomplete dehydrated magnesium chloride snow-melting agent contains 4-6 crystal water molecules. According to the preparation method of the incomplete dehydrated magnesium chloride snow-melting agent, one-section dehydration is performed by utilizing the byproduct bischofite under strict temperature control to obtain the first incomplete dehydrated magnesium chloride snow-melting agent, so that a solving way of comprehensively utilizing the resources and turning waste into wealth is provided, the pollution to the ecological environment of the salt lake is reduced, and the sustainable development of the salt lake potash fertilizer industry is promoted; and besides, the preparation method provided by the invention also has the advantages of being low in preparation cost, simple in processes, good in snow-melting effect and the like.

Description

technical field [0001] The invention belongs to the technical field of comprehensive utilization of salt lake resources, and in particular relates to a preparation method of an incompletely dehydrated magnesium chloride deicing agent. Background technique [0002] Potassium fertilizer is widely used in agriculture as an important chemical fertilizer, but my country is a potassium-deficient country. More than 90% of the potassium fertilizer production in my country is produced in the Chaerhan Salt Lake area of ​​Qinghai. During the process of extracting potassium from the salt lake, there will be A large number of old brines, these old brines can be easily obtained bischofite with a purity of up to 98% through natural evaporation in salt pans, and ten tons of bischofite can be produced as a by-product for every ton of potash fertilizer produced. Bischoferte contains six crystal waters, and the quality of crystal water is about 53% of the total mass, which makes the transportat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01F5/30C05D11/00C09K3/18
CPCC01F5/30C05D1/00C09K3/18C05D5/00
Inventor 都永生孙庆国山发寿高东林李斌凯秦占杰魏海成袁秦
Owner QINGHAI INST OF SALT LAKES OF CHINESE ACAD OF SCI
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