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Zirconium silicate-mullite composite wear-resisting castable and preparation method thereof

A technology of mullite and zirconium silicate, which is applied in the field of refractory materials, can solve problems such as insufficient vibrator vibration, structural damage, and shortened service life of coal injection pipes, achieve good high temperature volume stability, increase load softening temperature, and compensate for tissue Effects of Structural Defects

Active Publication Date: 2017-11-14
长兴兴鹰新型耐火建材有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Cement rotary kiln kiln mouth, cement kiln coal injection pipe and other parts have heavy alkaline atmosphere components, strong clinker and hot flue gas scouring effect, large ambient temperature difference, high refractoriness and other special working conditions, the index requirements for refractory performance are compared High, conventional products generally use corundum mullite refractory castables, and the existing problems are: the thermal expansion coefficient of corundum is relatively large, the thermal shock stability is not good, corundum is transformed from α-phase corundum in the alkaline atmosphere of cement kiln It is β-phase corundum, which causes volume expansion and is easy to cause structural damage, which greatly shortens the life of the coal injection pipe and cannot meet the needs of the market.
[0003] The traditional construction method of castables is vibration construction. This method has the advantages of short production cycle, good integrity, and good uniformity, but there are also some shortcomings. Segregation, and when the vibrating rod is pulled out, it is easy to leave a cavity, and the excessive noise of the vibrator will affect the construction environment

Method used

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  • Zirconium silicate-mullite composite wear-resisting castable and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A zirconium silicate-mullite composite wear-resistant castable, including the following components and parts by weight: 10 parts of 5-8mm mullite, 5 parts of 3-5mm mullite, and 5 parts of 1-3mm mullite , 6 parts of 3-5mm andalusite particles, 5.1 parts of andalusite-sillimanite composite mineral powder with a particle size of less than 0.075mm, and ZrO with a particle size of less than 1μm 2 5 parts, silicon micropowder with particle size less than 1 μm 3 parts, Al with particle size less than 1.2 μm 2 o 3 3 parts of micro powder, 3 parts of calcium aluminate cement, 0.15 parts of sodium hexametaphosphate, 0.08 parts of leveling agent, 0.5 parts of heat-resistant steel fiber, and 0.2 part of explosion-proof fiber.

[0022] Prepare the castable according to the following steps: Pour the raw materials of the above castable into the stirring device, stir and mix at room temperature, add 4% water and stir evenly, pour into the mold, maintain for 48 hours with the mold, an...

Embodiment 2

[0024] A zirconium silicate-mullite composite wear-resistant castable, including the following components and parts by weight: 9 parts of 5-8mm mullite, 8 parts of 3-5mm mullite, 4 parts of 1-3mm mullite , 7 parts of andalusite particles of 3-5mm, 6 parts of andalusite-sillimanite composite mineral powder with a particle size of less than 0.075mm, and ZrO with a particle size of less than 1μm 2 5 parts, silicon powder with particle size less than 1 μm 4 parts, Al with particle size less than 1.2 μm 2 o 3 4 parts of micro powder, 4 parts of calcium aluminate cement, 0.16 parts of sodium hexametaphosphate, 0.09 parts of leveling agent, 0.7 parts of heat-resistant steel fiber, and 0.2 part of explosion-proof fiber.

[0025] Prepare the castable according to the following steps: Pour the raw materials of the above castable into the stirring device, stir and mix at room temperature, add 4% water and stir evenly, pour into the mold, cure with the mold for 48 hours, and dry after d...

Embodiment 3

[0027] A zirconium silicate-mullite composite wear-resistant castable, comprising the following components and parts by weight: 8 parts of 5-8mm mullite, 8 parts of 3-5mm mullite, 6 parts of 1-3mm mullite , 8 parts of 3-5mm andalusite particles, 7.2 parts of andalusite-sillimanite composite mineral powder with a particle size of less than 0.075mm, and ZrO with a particle size of less than 1μm 2 6 parts, microsilica powder with particle size less than 1 μm 5 parts, Al with particle size less than 1.2 μm 2 o 3 4 parts of micro powder, 5 parts of calcium aluminate cement, 0.17 parts of sodium hexametaphosphate, 0.10 parts of leveling agent, 1.0 parts of heat-resistant steel fiber, and 0.2 parts of explosion-proof fiber.

[0028] Prepare the castable according to the following steps: pour the raw materials of the above castable into the stirring device, stir and mix at room temperature, add 4% water and stir evenly, pour into the mold, maintain for 48 hours with the mold, and dr...

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Abstract

The invention discloses zirconium silicate-mullite composite wear-resisting castable and a preparation method thereof. The castable is prepared from the following components in parts by mass: 18 to 24 parts of mullite with the size of 1mm to 8mm, 5 to 10 parts of andalusite particles with the size of 3mm to 5mm, 5 to 10 parts of compound ore powder with the grain diameter less than 0.075mm, 5 to 8 parts of ZrO2 with the grain diameter less than 1mum, 3 to 8 parts of silicon micro-powder with the grain diameter less than 1mum, 3 to 5 parts of Al2O3 micro-powder with the grain diameter less than 1.2mum, 3 to 7 parts of calcium aluminate cement, 0.15 to 0.2 part of sodium hexametaphosphate, 0.08 to 0.12 part of a flatting agent, 0.5 to 1.6 parts of heat-resisting steel fibers and 0.2 part of explosion-proof fibers. The zirconium silicate-mullite composite wear-resisting castable disclosed by the invention has the characteristics of high strength, high temperature resistance, good thermal shock resistance, wearing resistance and uneasiness of being cracked; in the aspect of the preparation method, a traditional construction manner is changed and a self flow mode is adopted; the problems of castable segregation and the like, which are possibly caused by vibration construction, are avoided; the zirconium silicate-mullite composite wear-resisting castable is applicable to abnormal-shape parts which are not easy to vibrate, such as coal injection pipes and kiln openings.

Description

technical field [0001] The invention relates to the technical field of refractory materials, in particular to a zirconium silicate-mullite composite wear-resistant castable and a preparation method thereof. Background technique [0002] Cement rotary kiln kiln mouth, cement kiln coal injection pipe and other parts have heavy alkaline atmosphere components, strong clinker and hot flue gas scouring effect, large ambient temperature difference, high refractoriness and other special working conditions, the index requirements for refractory performance are compared High, conventional products generally use corundum mullite refractory castables, and the existing problems are: the thermal expansion coefficient of corundum is relatively large, the thermal shock stability is not good, corundum is transformed from α-phase corundum in the alkaline atmosphere of cement kiln It is β-phase corundum, which causes volume expansion and is easy to cause structural damage, which greatly shorte...

Claims

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Application Information

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IPC IPC(8): C04B35/66
Inventor 许高山国强王强
Owner 长兴兴鹰新型耐火建材有限公司
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