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High-strength high dampness and heat sea atmospheric environment resistant weathering resistant steel and preparing method

A marine atmosphere, high-strength technology, applied in the field of weathering steel, can solve problems such as applicability doubts

Active Publication Date: 2017-05-31
CENT IRON & STEEL RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there is still a lack of domestic and foreign research on the weathering steel used in high-humidity and hot marine atmospheric environments like the South China Sea. Although the 3Ni advanced weathering steel developed by Japan has been proved to have good corrosion resistance in its coastal exposure test, the South China Sea is in latitude. In addition, its applicability has been questioned due to the harsh high-humidity and heat marine environment. Therefore, it is imperative to independently develop weathering steel suitable for the high-humidity and heat marine and atmospheric environment of the South China Sea.

Method used

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  • High-strength high dampness and heat sea atmospheric environment resistant weathering resistant steel and preparing method

Examples

Experimental program
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Effect test

Embodiment 1

[0034] Embodiment 1 Contains Sn, Sn+Sb weathering steel's high-humidity and heat-resistant marine atmospheric corrosion

[0035] Sn and Sb elements are added to the traditional weathering steel Q450NQR1, and smelted in a 25kg vacuum induction furnace. After forging, the steel ingot is cut into 120mm×120mm×30mm squares. The rolling process is as follows: the temperature is raised to 1200°C with the furnace, and rolling is carried out after holding the heat for 1 hour. After multiple passes of rolling, a steel plate with a thickness of 6mm is obtained. The chemical composition of the test steel is shown in Table 2.

[0036] Chemical composition (wt%) of table 2 test steel

[0037]

[0038] According to the periodic infiltration corrosion test method of weathering steel for railways (TB / T2375-93) and the corrosion test method of steel bars in a chloride ion environment (YB / T4367-2014), the test parameters are set as follows: the wetting solution is 2% wtNaCl solution by mass ...

Embodiment 2

[0041] Example 2 Effects of Different Ni Contents on the Corrosion Resistance of Weathering Steels to High Humidity and Heat, Marine Atmosphere

[0042] Ni is one of the most effective corrosion-resistant elements, but due to the high cost of Ni, it is of great significance to select an appropriate Ni content to obtain weathering steel with good comprehensive performance and reasonable cost. On the basis of the composition of the Q450NQR1 weathering steel in Example 1 above, only the Ni content was changed to obtain weathering steels with different Ni contents. Then 5 kinds of Ni-containing weathering steels (respectively numbered 1#~5#) with Ni content in the range of 1%~5% were smelted in a 25kg vacuum induction furnace. The corrosion test method used is the same as in Example 1. Aiming at the effect of Ni on the corrosion resistance of weathering steel in high humidity and heat, the actual exposure test in the Xisha area of ​​the South China Sea was carried out, and the ex...

Embodiment 3

[0043] Example 3 Effect of Mo on weathering steel corrosion resistance to high humidity and heat in marine atmosphere

[0044] The influence of Mo element on the corrosion performance of weathering steel in high-humidity marine atmosphere was investigated. The laboratory 25kg vacuum induction furnace smelted Mo-containing weathering steel (1#) and Mo-free weathering steel (0#). Table 4 is the test steel chemical composition. The corrosion test method adopted is the same as in Example 1. Figure 4 It is a bar graph of the corrosion rate of the test steel. It can be seen that by adding 0.34% Mo element, the corrosion resistance of the test steel can be increased by about 10% in the high-humidity marine atmosphere environment.

[0045] Table 4 Chemical composition of Mo-containing and Mo-free test steels

[0046]

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Abstract

The invention relates to high-strength high dampness and heat sea atmospheric environment resistant weathering resistant steel and a preparing method, and belongs to the technical field of weathering resistant steel. The steel comprises, by weight, 0.01%-0.03% of C, 0.30%-0.50% of Si, 0.60%-0.80% of Mn, 0.90%-1.10% of Cu, 2.80%-3.20% of Ni, 0.20%-0.40% of Mo, 0.25%-0.35% of Sn, 0.05%-0.10% of Sb, not larger than 0.03% of Cr, not larger than 0.02% of Nb, not larger than 0.01% of P, not larger than 0.01% of S, 0.03%-0.05% of RE and the balance Fe. On the basis of a Cu-Ni-Mo alloy system, the Sn, the Sb, the Nb, the RE and other microalloy elements are added, and the Cr content in the weathering resistant steel is greatly reduced. A steel ingot meeting the composition design scope is smelted through a vacuum induction furnace, through the follow-up forging and hot rolling, the weathering resistant steel with the strength of extension larger than or equal to 750 MPa, the yield strength larger than or equal to 650 MPa and the ductility larger than or equal to 15% is finally obtained; the corrosion resistance is reduced by more than 30% compared with a Q450NQR1 traditional weathering resistant steel; and the high-strength high dampness and heat sea atmospheric environment resistant weathering resistant steel is prepared and has the excellent mechanical property.

Description

technical field [0001] The invention belongs to the technical field of weathering steel, and in particular relates to a high-strength, high-humidity and heat-resistant weathering steel for marine and atmospheric environments and a preparation method thereof. The weathering steel has mechanical properties satisfying tensile strength ≥ 750 MPa, yield strength ≥ 650 MPa, and elongation ≥ 15 %, and has excellent resistance to high humidity and heat marine atmospheric environment performance. Background technique [0002] The 21st century is the century of the ocean. The development of marine engineering equipment and the construction of marine engineering are important contents of promoting and implementing the national marine strategy. Since the beginning of the new century, my country's offshore engineering equipment manufacturing industry has made great progress, especially offshore oil and gas development equipment has a good development foundation, but the ensuing problem o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C38/02C22C38/04C22C38/16C22C38/08C22C38/12C22C33/04C21D8/00
CPCC21D8/00C22C33/04C22C38/002C22C38/005C22C38/008C22C38/02C22C38/04C22C38/08C22C38/12C22C38/16
Inventor 刘清友汪兵黄涛陈小平贾书君
Owner CENT IRON & STEEL RES INST
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