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Application of synergistic aza-graphene with manganese oxide to near infrared nitrogen removal

A near-infrared light, graphene technology, applied in the direction of oxidized water/sewage treatment, chemical instruments and methods, chemical/physical processes, etc.

Active Publication Date: 2017-05-31
江苏易驰新能源集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, TiO 2 It can only use ultraviolet light, which accounts for about 4% of solar energy, for TiO 2 Doping and developing Fe 2 o 3 、WO 3 、Bi 2 WO 6 Although some new catalysts have partially solved the problem of utilizing visible light, infrared light, which accounts for nearly 50% of solar energy, still needs to be developed and utilized.

Method used

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  • Application of synergistic aza-graphene with manganese oxide to near infrared nitrogen removal
  • Application of synergistic aza-graphene with manganese oxide to near infrared nitrogen removal

Examples

Experimental program
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Embodiment 1

[0038] (1)NG-α-MnO 2 Preparation: Weigh manganese chloride and potassium permanganate (the molar ratio is 3:2), and dissolve them in 20mL deionized water respectively, add 5% nitrogen-assorted graphite of manganese dioxide theoretical yield in the manganese chloride solution Alkene, sonicated for 1 hour, transferred to a three-necked flask, heated to 85°C in a water bath, and potassium permanganate was added dropwise, refluxed for 12 hours, then filtered and washed, and vacuum-dried at 70°C for 12 hours to obtain the aza Graphene-α-manganese dioxide nanocomposite photocatalyst.

[0039] (2) Photocatalysis experiment: Wrap the wall of a 100ml beaker with tin foil to prevent ultraviolet light and visible light from entering the reaction system, and cover the mouth of the beaker with a λ>780nm cut-off filter to ensure that only near-infrared light is present. The radiation enters the photoreactor, and a 300W UV-Vis lamp is placed above the reactor. Add a certain concentration o...

Embodiment 2

[0045] NG-β-MnO 2 Preparation: Weigh manganese chloride and potassium permanganate (the molar ratio is 3:2), dissolve them in 20mL deionized water respectively, then add 5% azagraphene of manganese dioxide theoretical yield in the manganese chloride solution, Ultrasound for 1 hour, add potassium permanganate solution, stir for 30 minutes, transfer to a 100ml reaction kettle, heat at 160°C for 12h, cool to room temperature, filter and wash, and dry at 70°C for 12h under vacuum to obtain the nitrogen Heterographene-β-manganese dioxide nanohybrid photocatalyst.

[0046] (2) Photocatalysis experiment: Wrap the wall of a 100ml beaker with tin foil to prevent ultraviolet light and visible light from entering the reaction system, and cover the mouth of the beaker with a λ>780nm cut-off filter to ensure that only near-infrared light is present. The radiation enters the photoreactor, and a 300W UV-Vis lamp is placed above the reactor. Add a certain concentration of ammonia nitrogen s...

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Abstract

The invention discloses application of synergistic aza-graphene with manganese oxide to near infrared nitrogen removal. The application includes degrading ammonia nitrogen to obtain N2 and H2O by the aid of composite aza-graphene materials with the manganese oxide under near infrared conditions. The composite aza-graphene materials with the manganese oxide are used as photocatalysts. The application has the advantages that the ammonia nitrogen is photocatalytically degraded by the aid of the composite aza-graphene materials with the manganese oxide, the composite aza-graphene materials have ammonia nitrogen molecular recognition and infrared photocatalytic degradation functions, accordingly, the ammonia nitrogen can be degraded to obtain the N2 and the H2O in near infrared light, and the ammonia nitrogen degradation rate still can be higher than 92% after the photocatalysts are repeatedly used for photocatalytically degrading ammonia nitrogen by 5-10 times.

Description

technical field [0001] The invention relates to a manganese oxide composite azagraphene material and its application in catalytic degradation of ammonia nitrogen by using near-infrared light. Background technique [0002] Using solar energy to solve environmental energy problems originated in 1972 when Fujishima used TiO 2 Photoelectrode electrolysis of water to produce hydrogen, followed by Carey in 1976 reported the use of TiO 2 Photocatalytic oxidation eliminates the toxicity of polychlorinated diphenols. Since then, the use of solar energy to degrade environmental pollutants has rapidly become a research hotspot. However, TiO 2 It can only use ultraviolet light, which accounts for about 4% of solar energy, for TiO 2 Doping and developing Fe 2 o 3 、WO 3 、 Bi 2 WO 6 Although some new catalysts such as X-rays have partially solved the problem of utilizing visible light, infrared light, which accounts for nearly 50% of solar energy, still needs to be developed and ut...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J27/24C02F1/72
CPCC02F1/725B01J27/24C02F2101/16B01J35/39
Inventor 刘守清朱晓雷
Owner 江苏易驰新能源集团有限公司
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