Resin composition for forming cured film, cured film, electrically conductive member, and method for preventing migration
A technology of resin composition and cured film, applied to conductive layers, coatings and other directions on insulating carriers, can solve the problems of inapplicable film substrate coating, lack of flexibility, cracks, etc., to inhibit the migration of metals, Excellent flexibility and the effect of maintaining light transmittance
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[0116] [Preparation method of composition]
[0117] The method for preparing the composition of the present invention is not particularly limited. As an example, the method which melt|dissolves (A) component in (C) solvent, mixes (B) component by predetermined ratio in this solution, and makes a uniform solution is mentioned. Moreover, the manufacturing method of adding (D)-(H) component and other components further as needed in the appropriate stage of this manufacturing method, and mixing is mentioned.
[0118] At the time of preparation of the composition of this invention, the solution of (A) component obtained by the polymerization reaction in a solvent can be used as it is. In this case, (B) component etc. are put into the solution of this (A) component as mentioned above, and it sets as a uniform solution. In addition, in order to adjust the concentration, (C) solvent may be further added.
[0119] The composition in the solution state prepared in this way is prefera...
Embodiment
[0132] Hereinafter, the present invention will be described in more detail with reference to synthesis examples, examples, and comparative examples, but the present invention is not limited to the following examples. It should be noted that the weight average molecular weight (Mw) of the copolymer obtained in the synthesis example was measured using a Showa Denko Co., Ltd. GPC device (Shodex GPC-101) (columns: Shodex (registered trademark) KF8031 and KF8041 (Showa Denko Co., Ltd. ) production)) and measure under the conditions that tetrahydrofuran, an eluting solvent, flows through the column at a flow rate of 1 mL / min (column temperature: 40° C.) to elute. In addition, Mw is represented by the polystyrene conversion value.
[0133] In addition, the reagents and apparatuses used in the following synthesis examples, examples, and comparative examples are as follows.
[0134] ・DEGMEA (diethylene glycol monoethyl ether acetate), MMA (methyl methacrylate), MAA (methacrylic acid),...
Synthetic example 1
[0144] 532.0 g of DEGMEA was placed in a 1,000 mL four-necked flask, and 280.0 g of MMA, 30.1 g of MAA, 36.5 g of ST, and A mixed solution of MAIB 8.1g. After dripping, it was made to react at 70 degreeC for 20 hours, and resin solution P1 was obtained. It should be noted that the molar ratio of the monomer units in the resin ((meth)acrylate polymer) contained in the resin solution is MMA unit: MAA unit: ST unit=80:10:10, and its Mw is about 50000.
[0145] [2] Production of resin composition for forming a cured film, production of a cured film and its evaluation
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