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Ag(I) coordination compound with dichloromethane fluorescence enhancement effect, preparing method and application

A dichloromethane, fluorescence enhancement technology, applied in the direction of silver organic compounds, 1/11 organic compounds without C-metal bonds, fluorescence/phosphorescence, etc., can solve the problem that dichloromethane molecules cannot emit fluorescence and the molecules lack activity site, difficulty in interaction and other issues, to achieve the effect of easy mass production, simple method and mild reaction conditions

Active Publication Date: 2017-03-22
YANCHENG INST OF TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] Generally speaking, the fluorescence detection method requires the detected substance to have fluorescence characteristics, or have active sites that can interact with fluorescent substances, while dichloromethane molecules themselves cannot emit fluorescence, and the molecules themselves lack active interaction sites, which is different from general It is difficult for fluorescent detection materials to interact, so there is no relevant research report on the detection of dichloromethane by fluorescence technology

Method used

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  • Ag(I) coordination compound with dichloromethane fluorescence enhancement effect, preparing method and application
  • Ag(I) coordination compound with dichloromethane fluorescence enhancement effect, preparing method and application
  • Ag(I) coordination compound with dichloromethane fluorescence enhancement effect, preparing method and application

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preparation example Construction

[0034] The embodiment of the present invention also provides a preparation method of an Ag(I) complex having the fluorescence enhancement effect of dichloromethane. The Ag(I) complex uses silver nitrate as a metal salt and 5,12-diazatetra Acene is an organic ligand, which is prepared by the natural volatilization method of dichloromethane / methanol / acetonitrile three solvent components, and the preparation method of the Ag(I) complex specifically includes the following steps:

[0035] S1. Dissolve 5,12-diazatetracene in dichloromethane. The mass ratio of 5,12-diazatetracene to dichloromethane is preferably 1:1.2×10 3 -1.5×10 3 , to obtain the first solution, silver nitrate is dissolved in anhydrous methanol, the mass ratio of silver nitrate and anhydrous methanol is preferably 1:0.35×10 3 -0.44×10 3 , to obtain the second solution.

[0036] S2. Mix the first solution with the second solution to form a precipitate, and carefully add acetonitrile dropwise while stirring. The m...

Embodiment 1

[0041] This example provides an Ag(I) complex with dichloromethane fluorescence enhancement effect, which is prepared according to the following process:

[0042] Weigh 10 mg of DAT and dissolve it in 10 mL of dichloromethane (the mass ratio of DAT to dichloromethane is 1:1.325×10 3 ), to obtain the first solution, weigh 20mg of AgNO 3 Dissolve in 10 mL of anhydrous methanol (AgNO 3 The mass ratio to anhydrous methanol is 1:0.395×10 3 ) to obtain the second solution.

[0043] Mix the first solution and the second solution, a brownish-red precipitate is produced immediately, and carefully add 15 mL of acetonitrile dropwise under stirring (the mass ratio of DAT to acetonitrile is 1:1.185×10 3 ), the rate of addition of acetonitrile was 2 drops / second until the precipitate was completely dissolved to obtain a red clear solution.

[0044] The red clear solution was placed in a dark place and evaporated naturally at room temperature. After 4 days, dark red rod-shaped crystals w...

Embodiment 2

[0052] This example provides an Ag(I) complex with dichloromethane fluorescence enhancement effect, which is prepared according to the following process:

[0053] Weigh 10 mg of DAT and dissolve it in 9 mL of dichloromethane (the mass ratio of DAT to dichloromethane is 1:1.2×10 3 ), to obtain the first solution, weigh 20mg of AgNO 3 Dissolve in 8.86mL of anhydrous methanol (AgNO 3 The mass ratio to anhydrous methanol is 1:0.35×10 3 ) to obtain the second solution.

[0054] Mix the first solution and the second solution, a brownish-red precipitate is produced immediately, and carefully add 10 mL of acetonitrile dropwise under stirring (the mass ratio of DAT and acetonitrile is 1:0.79×10 3 ), the rate of addition of acetonitrile was 3 drops / second until the precipitate was completely dissolved to obtain a red clear solution.

[0055] Put the red clear solution in a dark place and let it evaporate naturally at room temperature. After 3 days, dark red rod-shaped crystals were ...

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Abstract

The invention discloses a Ag(I) coordination compound with the dichloromethane fluorescence enhancement effect, and relates to the field of fluorescence detection materials. The chemical formula of the Ag(I) coordination compound is [Ag2(DAT)2(NO3)2]n, wherein Ag and Cl in dichloromethane have the extra-high compatibility, a dichloromethane molecule can be actively adsorbed to the Ag(I) coordination compound, an original energy elimination channel is interdicted, and therefore the Ag(I) coordination compound has the dichloromethane fluorescence enhancement effect. According to the Ag(I) coordination compound, silver nitrate serves as metal salt, 5,12-di-aza-tetracene serves as an organic ligand, and the Ag(I) coordination compound is prepared with the natural volatilization method of three solvent components of the dichloromethane / methyl alcohol / acetonitrile; the method is simple, the reaction condition is wild, and large-batch production is easy. The invention also provides application of the Ag(I) coordination compound. The Ag(I) coordination compound serves as a fluorescence detection material, and is used for rapid and sensitive fluorescence detection of dichloromethane molecules free of fluorescence.

Description

technical field [0001] The invention relates to the field of fluorescence detection materials, and in particular to an Ag(I) complex having a dichloromethane fluorescence enhancement effect, a preparation method and an application. Background technique [0002] As an important chemical raw material and solvent, dichloromethane has important applications in many fields such as pharmaceuticals. Therefore, it is of great significance to develop a new technology that can quickly and accurately detect the residual amount of dichloromethane in corresponding products. Among the various new detection technologies that are popular at present, gas chromatography is the most widely used, and it has many defects and deficiencies. The main reason is that the operation process is complicated and cumbersome, which is not conducive to the rapid and convenient detection of products. The advantages are widely used. Fluorescence detection methods can be mainly divided into quenching type and ...

Claims

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Application Information

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IPC IPC(8): C07F1/10C09K11/06G01N21/64
CPCC07F1/005C09K11/06G01N21/6428
Inventor 解明华杨秀丽关荣锋宋涛易强强
Owner YANCHENG INST OF TECH
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