Method for preparing formaldehyde-free fiberboard using dialdehyde cellulose
A technology of dialdehyde cellulose and fiberboard, which is used in applications, household components, flat products, etc., can solve the problems of limited application and high production cost, and achieve the effects of moderate price, good physical properties and saving synthesis time.
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Embodiment 1
[0021] Formaldehyde-free fiberboard is synthesized from corn stover and dialdehyde cellulose as raw materials.
[0022] (1) Preparation of dialdehyde cellulose
[0023] Weigh 2g of absolutely dry bleached softwood pulp cellulose into a 250mL three-necked round bottom flask, add 100mLH 2 O, place the reactor in a constant temperature oil bath, then add 2.37g sodium periodate (analytical purity), and add 0.3mol / L HCl solution to adjust the pH to 2. In order to avoid the decomposition of sodium periodate, the reaction Enter nitrogen as a protective gas and perform shading treatment, and react for 5 hours at a temperature of 45°C. After the reaction is over, 110 mL of 0.1 mol / L ethylene glycol solution is added to react the excess sodium periodate. Vacuum filtration and drying to obtain dialdehyde cellulose.
[0024] (2) Straw pellets
[0025] A mechanical crushing method is used to crush the corn stalks to 75 micron size straw particles.
[0026] (3) Preparation of formaldehyde-free fib...
Embodiment 2
[0030] Formaldehyde-free fiberboard is synthesized from corn stover and dialdehyde cellulose as raw materials.
[0031] (1) Preparation of dialdehyde cellulose
[0032] Weigh 2g of absolutely dry bleached softwood pulp cellulose into a 250mL three-necked round bottom flask, add 100mLH 2 O, place the reactor in a constant temperature oil bath, then add 2.37g sodium periodate (analytical purity), and add 0.3mol / L HCl solution to adjust the pH to 2. In order to avoid the decomposition of sodium periodate, the reaction Enter nitrogen as a protective gas and perform shading treatment, and react for 5 hours at a temperature of 45°C. After the reaction is over, 110 mL of 0.1 mol / L ethylene glycol solution is added to react the excess sodium periodate. Vacuum filtration, drying to obtain dialdehyde cellulose.
[0033] (2) Straw pellets
[0034] A mechanical crushing method is used to crush the corn stalks to 75 micron size straw particles.
[0035] (3) Preparation of formaldehyde-free fiberb...
Embodiment 3
[0039] Formaldehyde-free fiberboard is synthesized from corn stover and dialdehyde cellulose as raw materials.
[0040] (1) Preparation of dialdehyde cellulose
[0041] Weigh 2g of absolutely dry bleached softwood pulp cellulose into a 250mL three-necked round bottom flask, add 100mLH 2 O, place the reactor in a constant temperature oil bath, then add 2.37g sodium periodate (analytical purity), and add 0.3mol / L HCl solution to adjust the pH to 2. In order to avoid the decomposition of sodium periodate, the reaction Enter nitrogen as a protective gas and perform shading treatment, and react for 5 hours at a temperature of 45°C. After the reaction is over, 110 mL of 0.1 mol / L ethylene glycol solution is added to react the excess sodium periodate. After vacuum filtration and drying, the dialdehyde cellulose is obtained.
[0042] (2) Straw pellets
[0043] A mechanical crushing method is used to crush the corn stalks to 70 micron size straw particles.
[0044] (3) Preparation of formalde...
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